摘要:
The invention describes an improved process for preparing polyols by reacting a mono-epoxy compound such as propylene oxide with a hydroxyl-containing initiator compound such as glycerine in the presence of a catalyst, the improvement being that the catalyst is added in the form of a calcium, strontium or barium salt of an organic acid such as acetic acid.Polyols prepared by this process can be employed to prepare polyurethanes without removing the catalyst.
摘要:
Rapid-setting polyurethanes are prepared from organic aromatic polyisocyanates and polyols having an average functionality of 2-8 and an equivalent weight less than 500 by admixture thereof in the presence of a non-amine nitrogen-containing compound such as urea as a catalyst therefor.
摘要:
Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as trichlorobenzene.
摘要:
A method for gelling relatively high molecular weight polyoxyalkylene-containing materials having a block of at least about 10 weight percent of oxyethylene units by blending therewith a sufficient quantity of a relatively low molecular weight material having at least two hydroxyl groups per molecule containing urea dissolved therein.
摘要:
Compositions containing a relatively high molecular weight polyol and ethylene glycol which compositions are incompatible, i.e. separate into two distinct phases upon storage, are compatibilized by the admixture therewith of urea or a substituted urea.
摘要:
Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as triethyl phosphate.
摘要:
Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as a cyclic sulfone.
摘要:
Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an organic aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as an organic carbonate.
摘要:
Compositions which will rapidly set to produce solid, rigid polyurethanes without the use of a catalyst comprise an amine initiated polyether polyol such as triethanol amine, an aromatic polyisocyanate, such as toluene diisocyanate and a liquid modifier compound having a boiling point above about 150.degree. C such as dioctylphthalate.
摘要:
Mixtures comprising a low molecular weight diol, a liquid modifier compound having a boiling point above about 150.degree. C, such as a cyclic sulfone, a polyisocyanate having a functionality of at least about 2.5 and an organometallic catalyst instantly set, after a brief induction period, to a solid, dense, rigid polymeric product which can be demolded within a period of from less than 1 minute to about 5 minutes.