公开(公告)号：US20070213576A1

公开(公告)日：2007-09-13

申请号：US11373360

申请日：2006-03-10

Applicant: Stephen Brown ,  Georges Mathys

Inventor： Stephen Brown ,  Georges Mathys

IPC: C07C2/02

CPC classification number: C07C2/12

Abstract: The invention relates to the use of isobutene-containing olefin feedstock in oligomerization reactions, particularly in the production of octenes as feedstock for the manufacture of plasticizer alcohols, the process comprising contacting a feed comprising isobutene with a molecular sieve at a temperature in excess of 240° C. to produce a product low in triple-branched octenes.

Abstract translation: 本发明涉及在低聚反应中使用含异丁烯的烯烃原料，特别是在制备辛烯作为制备增塑剂醇的原料时，该方法包括使包含异丁烯的进料与分子筛在超过240℃的温度下接触 以产生三支支化烯烃低的产物。

公开(公告)号：US20050182282A1

公开(公告)日：2005-08-18

申请号：US11064370

申请日：2005-02-22

Applicant: Luc Martens ,  John Godsmark ,  Marcel Janssen ,  Georges Mathys ,  Raphael Caers ,  Hubertus Beckers ,  J. Shutt ,  Eddy Van Driessche

Inventor： Luc Martens ,  John Godsmark ,  Marcel Janssen ,  Georges Mathys ,  Raphael Caers ,  Hubertus Beckers ,  J. Shutt ,  Eddy Van Driessche

IPC: C07B61/00 ,  C07C1/20 ,  C07C2/10 ,  C07C2/12 ,  C07C2/18 ,  C07C11/02 ,  C07C11/107 ,  C07C29/16 ,  C08F2/00 ,  C08F10/00 ,  C07C1/00 ,  C07C2/00

CPC classification number: C07C29/16 ,  C07C1/20 ,  C07C2/10 ,  C07C2/12 ,  C07C2/18 ,  C07C11/02 ,  C07C2523/755 ,  C07C2527/173 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/60 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  Y02P30/42 ,  C07C31/12

Abstract: A method of making a higher olefin product from a C4+ fraction separated from the hydrocarbon product produced by an oxygenate to olefin reaction unit. The C4+ fraction primarily contains butenes which may be directed to a higher olefin reaction unit without removing isobutenes, butanes, and/or butadiene. The C4+ fraction is particularly well suited for the production of higher olefins because of its high olefin content, low branching number, and low contaminent levels. The invention is also directed to an olefin product composition that is produced by contacting the C4+ fraction with an oligomerization catalyst. The olefin composition is characterized by a relatively high octene content, and octene with a branching number less than 1.4.

Abstract translation: 从由含氧化合物产生的烃产物与烯烃反应单元分离的C 4 H 4 O + +馏分制备较高级烯烃产物的方法。 C 4 S 4+ + / - >级分主要包含可以引导到较高级烯烃反应单元而不除去异丁烯，丁烷和/或丁二烯的丁烯。 由于其高烯烃含量，低分支数和低污染物水平，C 4 S 4 O + + / O 2馏分特别适用于生产高级烯烃。 本发明还涉及一种烯烃产物组合物，该烯烃产物组合物是通过使低分子化催化剂与C 4+ 4+ 烯烃组合物的特征在于具有相对较高的辛烯含量和分支数小于1.4的辛烯。

公开(公告)号：US20050143616A1

公开(公告)日：2005-06-30

申请号：US10509165

申请日：2003-03-28

Applicant: Stephen Beadle ,  Georges Mathys ,  Cesar Cheng-Guajardo

Inventor： Stephen Beadle ,  Georges Mathys ,  Cesar Cheng-Guajardo

IPC: C07B37/02 ,  C07C2/12 ,  C07C29/16 ,  C07C303/06 ,  C07C309/31 ,  C07C2/02

CPC classification number: C07C303/06 ,  C07B37/02 ,  C07C2/12 ,  C07C11/02 ,  C07C309/31

Abstract: A process for preparing a substantially linear olefinic hydrocarbon mixture is described in which a lower olefin feed comprising one or more C3 to C6 lower olefins is contacted in the presence of water and under olefin oligomerization conditions with a catalyst comprising surface-deactivated ZSM-23.

Abstract translation: 描述了制备基本上线性的烯烃混合物的方法，其中包含一种或多种C 3 -C 6低级烯烃的低级烯烃进料在水的存在下接触 并在烯烃低聚条件下使用含有表面失活的ZSM-23的催化剂。

公开(公告)号：US20050014630A1

公开(公告)日：2005-01-20

申请号：US10492705

申请日：2002-10-23

Applicant: Jihad Dakka ,  Hans Goris ,  Georges Mathys ,  Roger Eijkhoudt ,  Marc Puttemans ,  Stephen Brown

Inventor： Jihad Dakka ,  Hans Goris ,  Georges Mathys ,  Roger Eijkhoudt ,  Marc Puttemans ,  Stephen Brown

IPC: B01J29/70 ,  C01B39/46 ,  C07B61/00 ,  C07C2/12 ,  C07C11/02 ,  C07C29/141 ,  C07C31/125 ,  B01J29/04

CPC classification number: B01J29/7042 ,  B01J29/7026 ,  B01J29/80 ,  B01J37/20 ,  B01J2229/186 ,  B01J2229/34 ,  C07C2/12 ,  C07C2529/70

Abstract: Sulphur-containing olefinic feedstocks are oligomerized over zeolite catalysts.

Abstract translation: 含硫烯烃原料在沸石催化剂上低聚。

公开(公告)号：US20050020865A1

公开(公告)日：2005-01-27

申请号：US10492706

申请日：2002-10-23

Applicant: Jihad Dakka ,  Georges Mathys ,  Marc Puttemans

Inventor： Jihad Dakka ,  Georges Mathys ,  Marc Puttemans

IPC: B01J29/70 ,  C07B61/00 ,  C07C2/12 ,  C07C11/02 ,  C07C2/02

CPC classification number: C07C2/12 ,  B01J2229/186 ,  B01J2229/34 ,  C07C2529/70

Abstract: Limiting the sulphur level in olefin feedstocks to zeolite-catalysed oligomerization enhances selectivity to trimer and catalyst life and activity.

Abstract translation: 将烯烃原料中的硫含量限制在沸石催化的低聚物中，提高了对三聚体的选择性和催化剂寿命和活性。

公开(公告)号：US06770791B2

公开(公告)日：2004-08-03

申请号：US10426065

申请日：2003-04-29

Applicant: Georges Mathys ,  John Stephen Godsmark ,  Marcel Janssen ,  Luc Roger Martens ,  Hubertus Joseph Beckers ,  Eddy Theophile Andrea Van Driessche ,  Raphael Frans Ivo Caers ,  John Richard Shutt

Inventor： Georges Mathys ,  John Stephen Godsmark ,  Marcel Janssen ,  Luc Roger Martens ,  Hubertus Joseph Beckers ,  Eddy Theophile Andrea Van Driessche ,  Raphael Frans Ivo Caers ,  John Richard Shutt

IPC: C07C1207

CPC classification number: C07C11/02 ,  C07C1/20 ,  C07C2/10 ,  C07C2/12 ,  C07C2/18 ,  C07C2523/755 ,  C07C2527/173 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/60 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  C12C11/02

Abstract: Disclosed is an olefin containing stream from an oxygenate to olefin process, and a process for making olefin dimer and oligomer product from the olefin containing stream using a nickel based oligomerization catalyst. The dimer/oligomer product is optionally converted to hydroformylated product. The olefin containing stream that is used to make the higher olefin product has low levels of impurities including nitrogen, sulfur and/or chlorine.

Abstract translation: 公开了一种从含氧化合物到烯烃方法的含烯烃流，以及使用镍基低聚催化剂从含烯烃流中制备烯烃二聚体和低聚物产物的方法。 二聚体/低聚物产物任选转化为加氢甲酰化产物。 用于制备较高级烯烃产物的含烯烃流具有低含量的杂质，包括氮，硫和/或氯。

公开(公告)号：US5299374A

公开(公告)日：1994-04-05

申请号：US923455

申请日：1992-08-03

Applicant: Georges Mathys

Inventor： Georges Mathys

IPC: F41A19/10 ,  F41A19/35

CPC classification number: F41A19/10

Abstract: The invention concerns a multifunctional firearm control device comprising: (A) a trigger slidably-mounted on the casing of the firearm and able to occupy four positions, namely the first position, comprising a rest or uncocked position, the second comprising an armed position situated behind the first position, and a third position comprising the firing position situated behind the second position, and finally a fourth position comprising an opening position situated in front of the rest position; (B) a triggering device with meeting roller bearings and a percussion spring which, once freed, activates a cock, hammer or striking pin; (C) a firing plate including an armament ramp moved by the trigger activation, via a non-reversible movement after armament by means of a roller bearing, an armament lever of the percussion spring and a device for freeing the triggering device with meeting roller bearings; and (D) a control rod moved as the trigger moves into the opening position and, depending on the type of firearm, controlling the opening of the firearm or unlocking of the barrel or freeing of the magazine.

Abstract translation: 本发明涉及一种多功能火器控制装置，包括：（A）触发器，其可滑动地安装在枪支的壳体上，并且能够占据四个位置，即第一位置，包括休息或未锁定位置，第二位置包括位于 在第一位置之后，以及包括位于第二位置后面的击发位置的第三位置，最后包括位于静止位置前方的打开位置的第四位置; （B）具有会议辊轴承和冲击弹簧的触发装置，一旦释放，激活旋塞，锤子或撞击销; （C）包括通过触发器启动而移动的武装斜坡的击发板，通过滚子轴承在武器之后的不可逆运动，冲击弹簧的装备杆以及用于释放具有会议滚子轴承的触发装置的装置 ; 和（D）当触发器移动到打开位置时移动的控制杆，并且根据枪支的类型来控制枪支的打开或者解除枪管的释放或释放刀库。

公开(公告)号：US07582226B2

公开(公告)日：2009-09-01

申请号：US10869245

申请日：2004-06-16

Applicant: Eddy Van Driessche ,  Georges Mathys ,  Richard H. Schlosberg ,  Christian Francois ,  Chris De Roover

Inventor： Eddy Van Driessche ,  Georges Mathys ,  Richard H. Schlosberg ,  Christian Francois ,  Chris De Roover

IPC: C09K5/00

CPC classification number: C09D11/033 ,  C09D7/20

Abstract: Herein are fluid compositions and methods of making such compositions, wherein the compositions comprise C1 to C4 esters of a mixture of C3–C6 branched carboxylic acids and C3–C6 linear carboxylic acids.

Abstract translation: 本文是制备这种组合物的流体组合物和方法，其中组合物包含C 3 -C 6支链羧酸和C 3 -C 6直链羧酸的混合物的C1至C4酯。

公开(公告)号：US20080039669A1

公开(公告)日：2008-02-14

申请号：US11596168

申请日：2005-05-26

Applicant: Stephen Brown ,  John Godsmark ,  Georges Mathys

Inventor： Stephen Brown ,  John Godsmark ,  Georges Mathys

IPC: C07C2/12

CPC classification number: B01J29/7042 ,  B01J29/06 ,  B01J29/7026 ,  B01J29/703 ,  B01J29/7046 ,  B01J37/0009 ,  B01J2229/42 ,  C07C2/12 ,  C07C2529/70 ,  C07C2529/80 ,  C10G50/00 ,  C07C11/02

Abstract: In a process for oligomerizing an olefinic hydrocarbon feedstock comprising at least 65 wt % olefins and/or sulfur-containing molecules, the feedstock is contacted under oligomerization conditions with (a) a first unidimensional 10-ring molecular sieve catalyst and (b) a second multidimensional crystalline molecular sieve catalyst. The first and second catalysts may be contained in separate reactors or as separate beds in a single reactor.

Abstract translation: 在包含至少65重量％的烯烃和/或含硫分子的烯烃原料低聚的方法中，原料在低聚条件下与（a）第一单维10环分子筛催化剂接触，（b）第二 多维结晶分子筛催化剂。 第一和第二催化剂可以包含在单独的反应器中或作为单个反应器中的分离床。

公开(公告)号：US20070191661A1

公开(公告)日：2007-08-16

申请号：US11500004

申请日：2006-08-07

Applicant: Stephen Brown ,  Georges Mathys ,  Paul Hamilton

Inventor： Stephen Brown ,  Georges Mathys ,  Paul Hamilton

IPC: C07C2/02

CPC classification number: C07C2/12 ,  C07C2529/70 ,  C10G50/00 ,  C10G2300/1092 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2400/22

Abstract: The invention is directed to a method of selectively oligomerizing olefin monomers by controlling feedstock composition and reaction conditions. Reaction conditions are chosen to include at least one of: (a) dimer recycle; (b) staged injection of monomer; and (c) utilization of a two catalyst system.

Abstract translation: 本发明涉及通过控制原料组成和反应条件来选择性低聚烯烃单体的方法。 选择反应条件以包括以下至少一种：（a）二聚体再循环; （b）分期注射单体; 和（c）利用两个催化剂体系。