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    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants
    2.
    发明授权
    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants 失效
    多硫化烯烃组合物，它们的制备及其作为润滑剂添加剂的用途

    公开(公告)号：US5045221A

    公开(公告)日：1991-09-03

    申请号：US403968

    申请日：1989-09-07

    申请人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    发明人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    IPC分类号： C07C319/14 ,  C07C321/00 ,  C10M135/04 ,  C10N30/06 ,  C10N40/04 ,  C10N40/22

    CPC分类号： C10M135/04

    摘要： Polysulphurized olefin compositions used as additives for gear oils, cutting oils, and as sulphurizing agents in organic media are obtained by a process comprising:a stage (1) in which at least one compound chosen from among sulphur dichloride and monochloride is reacted with at least one aliphatic monpolefin with 2 to 12 carbon atoms, thus forming an adduct;a stage (2) in which sulphurized hydrogen and at least one mercaptan is reacted with ammonium or alkali metal hydroxide dissolved in at least one aliphatic monoalcohol with 1 to 4 carbon atoms, which is substantially anhydrous, so as to give an alcoholic solution;a stage (3) in which contacting takes place between the adduct obtained in stage (1) and the alcoholic solution obtained in stage (2);a stage (4), in which the resulting mixture is heated and then the aliphatic monoalcohol is eliminated by distillation, while adding water in a quantity adequate for maintaining in solution the reagents and the mineral products formed during the reaction; anda stage (5) in which elimination takes place of the aqueous phase and recovery takes place of the organic phase mainly constituted by the polysulphurized olefin composition.

    摘要翻译： 用于齿轮油，切削油和作为有机介质中的硫化剂的添加剂的多硫化烯烃组合物通过以下方法获得，该方法包括：其中至少一种选自二氯化硫和一氯化物的化合物至少与 一种具有2至12个碳原子的脂族单烯烃，从而形成加合物; 使硫化氢和至少一种硫醇与溶解在至少一种具有1-4个碳原子的脂族一元醇中的铵或碱金属氢氧化物反应的阶段（2），其基本上是无水的，以得到醇溶液; 在阶段（1）中获得的加合物和阶段（2）中获得的醇溶液之间发生接触的阶段（3）; 加热得到的混合物，然后通过蒸馏除去脂肪族一元醇的阶段（4），同时加入足以维持溶液中的水，反应物中形成的试剂和矿物产物; 以及主要由多硫化烯烃组合物构成的有机相进行水相脱除发生阶段（5）。

    (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils
    10.
    发明授权
    (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils 失效
    （聚）硫化羧酸化合物，它们的制备及其作为润滑油的石油添加剂的用途

    公开(公告)号：US5284592A

    公开(公告)日：1994-02-08

    申请号：US872196

    申请日：1992-04-22

    申请人： Ourida Aberkane ,  Maurice Born ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    发明人： Ourida Aberkane ,  Maurice Born ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    IPC分类号： C10M135/26 ,  C07C319/20 ,  C07C323/12 ,  C10M135/24 ,  C10N30/06

    CPC分类号： C10M135/24 ,  C07C323/12 ,  C10M2219/084

    摘要： Novel (poly)sulfurized carboxylic compounds, their preparation, and their use as additives to lubricating oils are disclosed. Such novel carboxylic compounds are more particularly esters of the general formula:[R.sup.3 --OC(O)--].sub.q R.sup.2 {--C(O)O--(CH.sub.2).sub.m --CH.sub.3-z [--(CH.sub.2).sub.n --S.sub.x --R.sup.1 ].sub.z }.sub.p (1)wherein R.sup.1 is a saturated or unsaturated monovalent aliphatic radical with 1 to 30 carbon atoms; the number x is equal to or greater than 1; z equals 1 or 2; when z equals 1, n is an integer from 0 to 5 and m an integer from 0 to 0.5, with m+n an integer from 1 to 10; when z equals 2, n is an integer from 1 to 5 and m an integer from 0 to 5, with m+n an integer from 1 to 10; R.sup.2 is a hydrocarbon radical with 1 to 31 carbon atoms and a valency of p+q; R.sup.3 is a hydrogen atom or an aliphatic radical with 1 to 30 carbon atoms; p is an integer from 1 to 4; and q is an integer from 0 to 3, with p+q being an integer from 1 to 4. They are obtained by esterifying carboxylic acid R.sup.2 (--COOH).sub.p+q with a (poly)sulfurized monoalcohol:[R.sup.1 --S.sub.x --(CH.sub.2).sub.n --].sub.z CH.sub.3-z --(CH.sub.2).sub.m --OHand possibly an alcohol R.sup.3 OH. They are used as anti-wear and extreme pressure additives in lubricating oils.

    摘要翻译： 公开了新型（多）硫化羧酸化合物，它们的制备及其作为润滑油添加剂的用途。 这样的新型羧酸化合物更特别是以下通式的酯：（R3-OC（O） - ）qR2（-C（O）O-（CH2）m-CH3-z（ - （CH2）n-Sx-R1） z）p（1）其中R1是具有1至30个碳原子的饱和或不饱和的一价脂族基; 数x等于或大于1; z等于1或2; 当z为1时，n为0〜5的整数，m为0〜0.5的整数，m + n为1〜10的整数。 当z为2时，n为1〜5的整数，m为0〜5的整数，m + n为1〜10的整数。 R2是具有1至31个碳原子并且p + q的化合价的烃基; R3是氢原子或具有1至30个碳原子的脂族基团; p是1至4的整数; 并且q为0〜3的整数，p + q为1〜4的整数。它们是通过用（多）硫化一元醇将羧酸R2（-COOH）p + q酯化得到的：（R1-Sx- （CH 2）n - ）z CH 3 -Z-（CH 2）m -OH以及可能的醇R 3 OH。 它们用作润滑油中的抗磨和极压添加剂。