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    PRETREATED EPOXIDATION CATALYST AND A PROCESS FOR PRODUCING AN OLEFIN THEREWITH
    1.
    发明申请
    PRETREATED EPOXIDATION CATALYST AND A PROCESS FOR PRODUCING AN OLEFIN THEREWITH 有权
    预氧化环氧化催化剂及其制备方法

    公开(公告)号：US20140243538A1

    公开(公告)日：2014-08-28

    申请号：US14252149

    申请日：2014-04-14

    申请人： Hannah L. Crampton

    发明人： Hannah L. Crampton

    IPC分类号： C07D303/08

    CPC分类号： C07D303/08 ,  B01J29/89 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/06 ,  B01J38/52 ,  C07D301/12 ,  Y02P20/584

    摘要： A pretreated titanium silicalite with MFI structure (TS-1) catalyst which has been pretreated with methanol, and then optionally filtered and optionally air-dried to form a pretreated activated TS-1 catalyst. The activated TS-1 may be used in an epoxidation reaction with no additional methanol added and has equivalent activity to TS-1 used with large excesses of methanol. By removing the need for additional methanol during the reaction, the losses of epichlorohydrin from solvolysis are minimized significantly.

    摘要翻译： 具有MFI结构（TS-1）催化剂的预处理的钛硅沸石，其已经用甲醇预处理，然后任选地过滤并任选地空气干燥以形成预处理的活化的TS-1催化剂。 活化的TS-1可以在环氧化反应中使用，没有添加额外的甲醇，并且与使用大量过量的甲醇的TS-1具有同等的活性。 通过在反应期间除去对另外的甲醇的需要，溶剂分解的表氯醇的损失被显着地最小化。

    PROCESS FOR PRODUCING PROPYLENE OXIDE USING A PRETREATED EPOXIDATION CATALYST
    3.
    发明申请
    PROCESS FOR PRODUCING PROPYLENE OXIDE USING A PRETREATED EPOXIDATION CATALYST 失效
    使用预氧化环氧化催化剂生产丙烯氧化物的方法

    公开(公告)号：US20130018196A1

    公开(公告)日：2013-01-17

    申请号：US13637072

    申请日：2011-03-22

    申请人： Hannah L. Crampton

    发明人： Hannah L. Crampton

    IPC分类号： C07D301/12 ,  C07D303/04

    CPC分类号： C07D303/04 ,  C07D301/12 ,  Y02P20/52 ,  Y02P20/582

    摘要： A process for preparing propylene oxide by epoxidizing propylene with an oxidant in the presence of a pretreated catalyst; wherein the catalyst comprises an activated titanium silicalite with MFI structure (TS-1) catalyst; and wherein the catalyst has been activated by pretreatment with methanol to form the pretreated catalyst. The pretreated TS-1 catalyst may be used in the epoxidizing propylene reaction with no additional methanol added; and the pretreated catalyst has equivalent activity to TS-1 catalyst used with large excesses of methanol.

    摘要翻译： 一种通过在预处理的催化剂存在下用氧化剂环氧化丙烯来制备环氧丙烷的方法; 其中所述催化剂包括具有MFI结构（TS-1）催化剂的活化钛硅沸石; 并且其中催化剂已经通过用甲醇预处理而活化，以形成预处理的催化剂。 预处理的TS-1催化剂可用于环氧化丙烯反应，不加入额外的甲醇; 并且预处理的催化剂对与大量过量的甲醇一起使用的TS-1催化剂具有等同的活性。

    PRETREATED EPOXIDATION CATALYST AND A PROCESS FOR PRODUCING AN OLEFIN THEREWITH
    4.
    发明申请
    PRETREATED EPOXIDATION CATALYST AND A PROCESS FOR PRODUCING AN OLEFIN THEREWITH 有权
    预氧化环氧化催化剂及其制备方法

    公开(公告)号：US20130012731A1

    公开(公告)日：2013-01-10

    申请号：US13636706

    申请日：2011-03-22

    申请人： Hannah L. Crampton

    发明人： Hannah L. Crampton

    IPC分类号： C07F7/28 ,  C07D303/02 ,  C07D303/08 ,  C07D301/03

    CPC分类号： C07D303/08 ,  B01J29/89 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/06 ,  B01J38/52 ,  C07D301/12 ,  Y02P20/584

    摘要： A pretreated titanium silicalite with MFI structure (TS-1) catalyst which has been pretreated with methanol, and then optionally filtered and optionally air-dried to form a pretreated activated TS-1 catalyst. The activated TS-1 may be used in an epoxidation reaction with no additional methanol added and has equivalent activity to TS-1 used with large excesses of methanol. By removing the need for additional methanol during the reaction, the losses of epichlorohydrin from solvolysis are minimized significantly.

    摘要翻译： 具有MFI结构（TS-1）催化剂的预处理的钛硅沸石，其已经用甲醇预处理，然后任选地过滤并任选地空气干燥以形成预处理的活化的TS-1催化剂。 活化的TS-1可以在环氧化反应中使用，没有添加额外的甲醇，并且与使用大量过量的甲醇的TS-1具有同等的活性。 通过在反应期间除去对另外的甲醇的需要，溶剂分解的表氯醇的损失被显着地最小化。

    PROCESS FOR PRODUCING PROPYLENE OXIDE
    5.
    发明申请
    PROCESS FOR PRODUCING PROPYLENE OXIDE 审中-公开
    生产丙烯氧化物的方法

    公开(公告)号：US20120130096A1

    公开(公告)日：2012-05-24

    申请号：US13388704

    申请日：2010-08-04

    申请人： Hannah L. Crampton ,  Philip J. Carlberg ,  David H. West ,  Bruce D. Hook ,  William W. Fan ,  Anna Forlin

    发明人： Hannah L. Crampton ,  Philip J. Carlberg ,  David H. West ,  Bruce D. Hook ,  William W. Fan ,  Anna Forlin

    IPC分类号： C07D301/12 ,  C09K3/00

    CPC分类号： C07D301/12 ,  Y02P20/52 ,  Y02P20/582

    摘要： A multiple liquid phase composition and process for preparing propylene oxide including a reaction mixture of: (a) propylene, (b) at least one peroxide compound, (c) at least one catalyst, such as a titanium silicalite-1 (TS-I) catalyst, and (d) and a predetermined amount of a solvent mixture; wherein the solvent mixture comprises at least (i) at least one alcohol, such as methanol, and (ii) at least one non-reactive co-solvent; wherein the solvents are mixed at a predetermined concentration; wherein the non-reactive co-solvent has a different boiling point than propylene oxide; and wherein the resulting propylene oxide product partitions into a high affinity solvent during the reaction. The process of the present invention advantageously produces a waste stream with little or no significant amount of sodium chloride (NaCl).

    摘要翻译： 一种多液相组合物和制备环氧丙烷的方法，包括以下反应混合物：（a）丙烯，（b）至少一种过氧化物，（c）至少一种催化剂，例如钛硅沸石-1（TS-1 ）催化剂，和（d）和预定量的溶剂混合物; 其中所述溶剂混合物包含至少（i）至少一种醇，例如甲醇，和（ii）至少一种非反应性助溶剂; 其中所述溶剂以预定浓度混合; 其中所述非反应性助溶剂具有不同于环氧丙烷的沸点; 并且其中所得环氧丙烷产物在反应期间分成高亲和力溶剂。 本发明的方法有利地产生具有很少或没有显着量的氯化钠（NaCl）的废物流。

    Process for producing an oxirane
    6.
    发明授权
    Process for producing an oxirane 有权
    生产环氧乙烷的方法

    公开(公告)号：US08697895B2

    公开(公告)日：2014-04-15

    申请号：US13388723

    申请日：2010-08-04

    申请人： Hannah L. Crampton ,  Philip J. Carlberg ,  David H. West ,  Bruce D. Hook ,  William W. Fan ,  Anna Forlin

    发明人： Hannah L. Crampton ,  Philip J. Carlberg ,  David H. West ,  Bruce D. Hook ,  William W. Fan ,  Anna Forlin

    IPC分类号： C07D301/12

    CPC分类号： C07D301/12 ,  Y02P20/52

    摘要： A multiple liquid phase composition and process for preparing an oxirane product, such as epichlorohydrin, including a reaction mixture of: (a) at least one olefin, wherein the olefin is selected from one of (i) an aliphatic olefin or substituted aliphatic olefin, with the proviso that the aliphatic olefin is not propylene, (ii) a cycloaliphatic olefin, (iii) an aromatic olefin, (iv) a cycloaromatic olefin, and (v) mixtures thereof; (b) at least one peroxide compound, (c) at least one catalyst, and (d) and a solvent mixture; wherein the solvent mixture comprises at least (i) at least one alcohol or a combination of alcohols, and (ii) at least one non-reactive co-solvent; wherein the solvents are mixed at a predetermined concentration; wherein the non-reactive co-solvent has a different boiling point than the oxirane product; and wherein the oxirane product partitions into a high affinity solvent during the reaction. The process of the present invention advantageously produces a waste stream with no significant amount of sodium chloride (NaCl). In one embodiment, the present invention includes a process for preparing epichlorohydrin from allyl chloride and hydrogen peroxide including reacting (a) an allyl chloride with (b) hydrogen peroxide, in the presence of (c) a titanium silicalite-1 (TS-1) catalyst and (d) in the presence of a predetermined amount of a mixed solvent system; wherein the mixed solvent system includes at least (i) methanol and (ii) at least one non-reactive co-solvent.

    摘要翻译： 一种多液相组合物和用于制备环氧乙烷产物如表氯醇的方法，包括：（a）至少一种烯烃的反应混合物，其中烯烃选自（i）脂族烯烃或取代的脂族烯烃， 条件是脂族烯烃不是丙烯，（ii）脂环族烯烃，（iii）芳族烯烃，（iv）环芳烃烯烃和（v）它们的混合物; （b）至少一种过氧化物化合物，（c）至少一种催化剂和（d）和溶剂混合物; 其中所述溶剂混合物包含至少（i）至少一种醇或醇的组合，和（ii）至少一种非反应性助溶剂; 其中所述溶剂以预定浓度混合; 其中所述非反应性助溶剂具有与环氧乙烷产物不同的沸点; 并且其中环氧乙烷产物在反应期间分成高亲和力溶剂。 本发明的方法有利地产生没有显着量氯化钠（NaCl）的废物流。 在一个实施方案中，本发明包括由烯丙基氯和过氧化氢制备环氧氯丙烷的方法，包括在（c）钛硅沸石-1（TS-1）存在下，使（a）烯丙基氯与（b）过氧化氢反应 ）催化剂和（d）在预定量的混合溶剂体系的存在下; 其中所述混合溶剂系统至少包括（i）甲醇和（ii）至少一种非反应性助溶剂。

    Process and system for producing an oxirane
    7.
    发明授权
    Process and system for producing an oxirane 有权
    生产环氧乙烷的方法和系统

    公开(公告)号：US08927744B2

    公开(公告)日：2015-01-06

    申请号：US14355865

    申请日：2012-11-02

    申请人： Cesar E. Meza ,  Philip J. Carlberg ,  Hannah L. Crampton

    发明人： Cesar E. Meza ,  Philip J. Carlberg ,  Hannah L. Crampton

    IPC分类号： C07D301/12

    CPC分类号： C07D301/12 ,  Y02P20/582

    摘要： Embodiments of the present disclosure provide processes and systems for the epoxidation of an olefin using a fixed bed reactor. The fixed bed reactor is maintained at a temperature from 0 to 40 degrees Celsius. The processes and systems regulate a superficial liquid velocity of a non-homogeneous reaction mixture and recycled portion of effluent of the fixed bed reactor.

    摘要翻译： 本公开的实施方案提供了使用固定床反应器进行烯烃环氧化的方法和系统。 固定床反应器保持在0至40摄氏度的温度。 方法和系统调节固定床反应器的非均匀反应混合物和再循环部分流出物的表面液体速度。

    Process for producing propylene oxide using a pretreated epoxidation catalyst
    9.
    发明授权
    Process for producing propylene oxide using a pretreated epoxidation catalyst 失效
    使用预处理的环氧化催化剂生产环氧丙烷的方法

    公开(公告)号：US08703983B2

    公开(公告)日：2014-04-22

    申请号：US13637072

    申请日：2011-03-22

    申请人： Hannah L. Crampton

    发明人： Hannah L. Crampton

    IPC分类号： C07D303/00

    CPC分类号： C07D303/04 ,  C07D301/12 ,  Y02P20/52 ,  Y02P20/582

    摘要： A process for preparing propylene oxide by epoxidizing propylene with an oxidant in the presence of a pretreated catalyst; wherein the catalyst comprises an activated titanium silicalite with MFI structure (TS-1) catalyst; and wherein the catalyst has been activated by pretreatment with methanol to form the pretreated catalyst. The pretreated TS-1 catalyst may be used in the epoxidizing propylene reaction with no additional methanol added; and the pretreated catalyst has equivalent activity to TS-1 catalyst used with large excesses of methanol.

    摘要翻译： 一种通过在预处理的催化剂存在下用氧化剂环氧化丙烯来制备环氧丙烷的方法; 其中所述催化剂包括具有MFI结构（TS-1）催化剂的活化钛硅沸石; 并且其中催化剂已经通过用甲醇预处理而活化，以形成预处理的催化剂。 预处理的TS-1催化剂可用于环氧化丙烯反应，不加入额外的甲醇; 并且预处理的催化剂对与大量过量的甲醇一起使用的TS-1催化剂具有等同的活性。