公开(公告)号：US20050119442A1

公开(公告)日：2005-06-02

申请号：US10500059

申请日：2002-12-17

申请人： Klause Dziwok ,  Inge Kramer ,  Norbert Schall ,  Helmut Coutelle ,  Sabine Huth ,  Alan Steinmetz ,  Thadeus Schauer ,  Heinz Greisiger ,  Mark Entenmann

发明人： Klause Dziwok ,  Inge Kramer ,  Norbert Schall ,  Helmut Coutelle ,  Sabine Huth ,  Alan Steinmetz ,  Thadeus Schauer ,  Heinz Greisiger ,  Mark Entenmann

IPC分类号： C08G12/42 ,  C09B67/46 ,  C09D7/45 ,  C09D17/00 ,  C09D133/06 ,  C09D161/20 ,  C08G2/00 ,  C08G73/06

CPC分类号： C08G12/424 ,  C08G12/42 ,  C09B67/0085 ,  C09D7/45 ,  C09D17/001

摘要： A description is given of water-soluble aminoplast ether copolymers of the following structural type: where Z is an aminoplast unit based on a glycoluril which is unsubstituted or substituted by a reactive OR group (where R is an alkyl, alkylene, alkyl ether or alkyl ester group, preferably a lower alkyl group, e.g., a methyl or ethyl group); B is the radical of an essentially water-insoluble polymer selected from poly-n-butyl acrylate, poly-n-butyl methacrylate, polyethyl acrylate, polytetrahydrofuran, polyethyl methacrylate, polymethyl acrylate, polymethyl methacrylate, a predominantly aliphatic polycarbonate or a predominantly aromatic polycarbonate, and more preferably from a poly-n-butyl methacrylate or a predominantly aliphatic or aromatic polycarbonate having at least two functional groups which are able to react with the OR function of the aminoplast unit, preferably having a hydroxyl function; R1 is the radical of a hydrophilic organic compound containing at least one functional group which is able to react with the OR function of the aminoplast unit to form an ether bond, preferably having a hydroxyl function, and a is at least 1. A description is additionally given of a process for preparing the above aminoplast ether copolymers and also of their use as dispersants and stabilizers.

摘要翻译： 给出以下结构类型的水溶性氨基塑料醚共聚物的描述：其中Z是基于甘脲的氨基塑料单元，其未被取代或被反应性OR基团取代（其中R是烷基，亚烷基，烷基醚或烷基 酯基，优选低级烷基，例如甲基或乙基）; B是基本上不溶于水的聚合物的基团，其选自聚丙烯酸正丁酯，聚甲基丙烯酸正丁酯，聚丙烯酸乙酯，聚四氢呋喃，聚甲基丙烯酸乙酯，聚丙烯酸甲酯，聚甲基丙烯酸甲酯，主要是脂族聚碳酸酯或主要是芳族聚碳酸酯 ，更优选由具有至少两个能够与氨基塑料单元的OR功能反应的至少两个官能团的优选具有羟基官能团的聚甲基丙烯酸甲酯或主要是脂族或芳族聚碳酸酯; R1是含有至少一个官能团的基团，其能够与氨基塑料单元的OR功能反应形成醚键，优选具有羟基官能团，并且a至少为1.描述为 另外给出了制备上述氨基塑料醚共聚物的方法，以及它们作为分散剂和稳定剂的用途。

公开(公告)号：US5948156A

公开(公告)日：1999-09-07

申请号：US903708

申请日：1997-07-31

申请人： Helmut Coutelle ,  Klaus Dziwok

发明人： Helmut Coutelle ,  Klaus Dziwok

IPC分类号： C04B14/10 ,  C04B40/00

CPC分类号： C04B40/0042 ,  C04B14/10 ,  C04B14/104 ,  C04B2103/30 ,  Y10S106/04

摘要： A supplementing agent for mineral binder systems is disclosed, especially for the construction industry, containing at least 1 finely divided, swellable layer silicate and possible at least 1 other additive, the proportion of the swellable layer silicate being more than 60 wt. % and the swelling volume of the layer silicate being around 5-50 ml, in terms of a suspension of 2 g layer silicate in 100 ml water.

摘要翻译： 公开了用于矿物粘合剂体系的补充剂，特别是对于建筑工业，其含有至少1个细分散的可溶胀层状硅酸盐和可能的至少1种其它添加剂，可膨胀层硅酸盐的比例大于60wt。 ％，硅酸盐的溶胀体积为约5-50ml，以2g硅酸盐在100ml水中的悬浮液计。

公开(公告)号：US5582638A

公开(公告)日：1996-12-10

申请号：US410828

申请日：1995-03-27

申请人： Helmut Coutelle ,  Wolfgang Heininger ,  Wolfgang Buckl

发明人： Helmut Coutelle ,  Wolfgang Heininger ,  Wolfgang Buckl

IPC分类号： A61K8/26 ,  A61K8/55 ,  A61Q11/00 ,  A61Q19/00 ,  B01F17/14 ,  C09C1/28 ,  C09C1/42 ,  C09C3/08 ,  C09D7/00 ,  C08K9/04 ,  C09L3/08

CPC分类号： C09C1/28 ,  A61K8/26 ,  A61K8/55 ,  A61Q11/00 ,  A61Q19/00 ,  C09C1/42 ,  C09C3/08 ,  C09D7/002 ,  C01P2004/61 ,  C01P2006/22 ,  C08K3/34

摘要： A thickening agent which is based on at least one synthetic phyllosilicate which contains at least one additive from the group of organic phosphorus compounds comprising the following:a) phosphonic acids with formula ##STR1## b) phosphinic acids with formula ##STR2## c) thiophosphinic acids with formula ##STR3## d) diesters of phosphorous acid with formula HO--P(OR).sub.2 e) diesters of phosphoric acid with formula ##STR4## f) diphosphonic acid with formula ##STR5## in which R is an alkyl or hydroxyalkyl group with 1 to 22 C atoms or an aryl or hydroxyaryl group with 6 to 12 C atoms and R' is an alkylene group with 2 to 22 C atoms.

摘要翻译： 基于至少一种合成页硅酸盐的增稠剂，其含有至少一种由以下有机磷化合物组成的组合物的至少一种添加剂：a）具有下式的膦酸：b）具有下式的次膦酸c）硫代膦 具有式的酸d）具有式HO-P（OR）2e的亚磷酸二酯具有式“IMAGE”的磷酸二酯f）具有式“IMAGE”的二膦酸，其中R是烷基或羟烷基， 1至22个C原子或具有6至12个碳原子的芳基或羟基芳基，R'为具有2至22个C原子的亚烷基。

公开(公告)号：US5423911A

公开(公告)日：1995-06-13

申请号：US67287

申请日：1993-05-25

申请人： Helmut Coutelle ,  Joachim Hlavatsch ,  Friedrich Ruf ,  Hartmann Schott

发明人： Helmut Coutelle ,  Joachim Hlavatsch ,  Friedrich Ruf ,  Hartmann Schott

IPC分类号： C09C1/28 ,  B41M1/02 ,  B41M1/10 ,  B41M1/36 ,  C01B33/20 ,  C01B33/26 ,  C09C1/00 ,  C09C1/42 ,  C09D1/00 ,  C09D1/02 ,  C09D5/00 ,  C09D7/12 ,  D21H19/38 ,  D21H19/40 ,  D21H19/42 ,  C04B14/20

CPC分类号： D21H19/40 ,  C09C1/0081 ,  C09C1/42 ,  D21H19/42 ,  C01P2006/12 ,  C01P2006/22

摘要： A coating pigment for coating printing media, especially paper and cardboard, is made with at least one swellable layer silicate which can be fixed on the printing medium essentially without binders, where the amount of swellable layer silicate is at least 30 weight percent and the swelling volume of the coating pigment is 5 to 30 ml, based on suspension of 2 g coating pigment in 100 ml water. A water-based coating which contains such a coating pigment and a printing medium that is coated on one or both sides with the coating pigment or coating are also described. The deinkability of printed printing media coated with the coating pigment is improved.

摘要翻译： 用于涂布印刷介质，特别是纸和纸板的涂料颜料用至少一种可溶胀层状硅酸盐制成，其可以基本上不粘合剂固定在印刷介质上，其中可溶胀层状硅酸盐的量为至少30重量％ 基于2g涂料颜料在100ml水中的悬浮液，涂料颜料的体积为5至30ml。 还描述了含有这种涂料颜料的水性涂料和在一面或两面涂覆有涂料颜料或涂料的印刷介质。 改善了涂覆有涂料颜料的印刷印刷介质的脱墨性。

公开(公告)号：US07419540B2

公开(公告)日：2008-09-02

申请号：US10362305

申请日：2001-08-29

申请人： Markus Möller ,  Helmut Coutelle ,  Robert Warth ,  Wolfgang Heininger

发明人： Markus Möller ,  Helmut Coutelle ,  Robert Warth ,  Wolfgang Heininger

IPC分类号： C04B14/04

CPC分类号： A61K8/26 ,  A61Q19/00 ,  C01B33/40 ,  C02F1/281 ,  C04B14/04 ,  C04B14/10 ,  C04B14/206 ,  C10M113/10 ,  C10M2201/103 ,  C11D3/1253

摘要： A swellable layer silicate is described based on smectite or sepiolite/palygorskite for use in media containing di- or polyvalent cations that reduce swellability, characterized by a swelling volume of about 5 to 50 mL, measured by addition of 2 g layer silicate (air-dried) to 100 mL water, and by a fineness of maximum 5 wt. % >40 μm and maximum 20% >20 μm, as dry sieve residue.

摘要翻译： 基于蒙脱石或海泡石/坡缕石描述可溶胀层状硅酸盐，用于含有二价或多价阳离子的介质中，所述二价或多价阳离子可降低溶胀性，其特征在于溶胀体积为约5至50mL，通过加入2g层状硅酸盐（空气 - 干燥）至100mL水，细度最大为5wt。 ％> 40mum，最大20％> 20mum，作为干筛残渣。

公开(公告)号：US07335699B2

公开(公告)日：2008-02-26

申请号：US10500059

申请日：2002-12-17

申请人： Klaus Dziwok ,  Inge Krämer ,  Norbert Schall ,  Helmut Coutelle ,  Sabine Huth ,  Alan Steinmetz ,  Thadeus Schauer ,  Heinz Greisiger ,  Mark Entenmann

发明人： Klaus Dziwok ,  Inge Krämer ,  Norbert Schall ,  Helmut Coutelle ,  Sabine Huth ,  Alan Steinmetz ,  Thadeus Schauer ,  Heinz Greisiger ,  Mark Entenmann

IPC分类号： C08G73/06 ,  C08G12/42

CPC分类号： C08G12/424 ,  C08G12/42 ,  C09B67/0085 ,  C09D7/45 ,  C09D17/001

摘要： A description is given of water-soluble aminoplast ether copolymers of the following structural type: wherein Z is a glycoluril central unit, B is a radical of an essentially water-insoluble polymer and R1 is a radical of a hydrophilic organic compound. The ratio R1:B is selected within a range of about 1.5 to 4:1 and the overall mass of the water-soluble aminoplast ether copolymer is from about 2000 to 50 000 g/mol such that the copolymer is soluble in water and may be used as a dispersant for e.g. pigments in polar solvents, e.g. water.

摘要翻译： 给出以下结构类型的水溶性氨基塑料醚共聚物的描述：其中Z是甘脲中心单元，B是基本上不溶于水的聚合物的基团，R 1是亲水性有机化合物的基团。 比例R1：B选择在约1.5至4：1的范围内，并且水溶性氨基塑料醚共聚物的总质量为约2000至50 000g / mol，使得共聚物可溶于水，并且可以是 用作例如的分散剂 极性溶剂中的颜料，例如 水。

公开(公告)号：US20070161745A1

公开(公告)日：2007-07-12

申请号：US10548696

申请日：2004-03-07

申请人： Helmut Coutelle ,  Klaus Dziwok

发明人： Helmut Coutelle ,  Klaus Dziwok

IPC分类号： C08G67/02

CPC分类号： C11D17/003 ,  A61K2800/594 ,  C09D7/44 ,  C09D11/03 ,  C11D17/0026

摘要： An associative thickener preparation having a viscosity in aqueous solution of less than 25 000 mPa·s is described, comprising (a) a combination of at least one associative thickener (A) having a structural viscosity and at least one Newtonian associative thickener (B); and/or (b) a combination of at least one associative thickener (A) having a structural viscosity, at least one Newtonian associative thickener (B) and at least one thinner (C); and/or (c) a combination of at least one associative thickener (A) having a structural viscosity, at least one Newtonian associative thickener (B) and at least one wetting agent; and/or (d) a combination of at least one associative thickener (A) having a structural viscosity, at least one Newtonian associative thickener (B) and at least one solvent; and/or (e) a combination of at least one associative thickener (A) having a structural viscosity, at least one Newtonian associative thickener (B), at least one solvent and at least one wetting agent; and/or (f) a combination of at least one thickener (A) having a structural viscosity and at least one thinner (C); and/or (g) a combination of at least one Newtonian thickener (B) and at least one thinner (C).

摘要翻译： 描述了在水溶液中粘度小于25000mPa.s的缔合增稠剂制剂，其包含（a）至少一种具有结构粘度的缔合增稠剂（A）和至少一种牛顿缔合增稠剂（B）的组合， ; 和/或（b）具有结构粘度的至少一种缔合增稠剂（A），至少一种牛顿缔合增稠剂（B）和至少一种稀释剂（C）的组合; 和/或（c）具有结构粘度的至少一种缔合增稠剂（A），至少一种牛顿缔合增稠剂（B）和至少一种润湿剂的组合; 和/或（d）具有结构粘度的至少一种缔合增稠剂（A），至少一种牛顿缔合增稠剂（B）和至少一种溶剂的组合; 和/或（e）具有结构粘度的至少一种缔合增稠剂（A），至少一种牛顿缔合增稠剂（B），至少一种溶剂和至少一种润湿剂的组合; 和/或（f）具有结构粘度的至少一种增稠剂（A）和至少一种稀释剂（C）的组合; 和/或（g）至少一种牛顿增稠剂（B）和至少一种稀释剂（C）的组合。

公开(公告)号：US06929860B2

公开(公告)日：2005-08-16

申请号：US10343647

申请日：2001-08-02

申请人： Alan Lawrence Steinmetz ,  Norbert Schall ,  Klaus Dziwok ,  Helmut Coutelle ,  Wolfgang Simon ,  Stefan Dick ,  Inge Krämer ,  Hubert Schiessling

发明人： Alan Lawrence Steinmetz ,  Norbert Schall ,  Klaus Dziwok ,  Helmut Coutelle ,  Wolfgang Simon ,  Stefan Dick ,  Inge Krämer ,  Hubert Schiessling

IPC分类号： C08K9/04 ,  C08G12/42 ,  C08G12/46 ,  C08K9/08 ,  C08L101/04 ,  B32B5/16

CPC分类号： C08K9/08 ,  C08G12/42 ,  Y10T428/2991 ,  Y10T428/2998

摘要： Surface-modified fillers are described characterized by the fact that the fillers represent reactive inorganic fillers and the modifying agent represents an amphiphilic aminoplastic-ether polymer or copolymer of the structural type in which: Z denotes the same or different aminoplastic central units based on melamine-formaldehyde or urea-formaldehyde derivatives; n=10 to 500; R denotes the group —[O—CH2—CH2]mO—S in which m=5 to 500 and S represents a substituted or unsubstituted alkyl, aryl, alkaryl or aralkyl group.

摘要翻译： 描述表面改性填料的特征在于填料代表活性无机填料，改性剂代表结构类型的两亲性氨基塑料醚聚合物或共聚物，其中：Z表示基于三聚氰胺的相同或不同的氨基塑料中心单元， 甲醛或脲甲醛衍生物; n = 10〜500; R表示其中m = 5至500且S表示取代或取代的基团 - [O-CH 2 CH 2 CH 2 OS] 未取代的烷基，芳基，烷芳基或芳烷基。