Abstract:
The present invention relates to a method for the absorption of liquids, which comprises the step bringing the liquid into contact with at least one sorbent comprising a porous metal-organic framework, the framework taking up the liquid and comprising at least one at least bidentate organic compound having a coordinate bond to at least one metal ion.
Abstract:
Process for preparing 1,1,4,4-tetraalkoxybut-2-ene derivatives of the general formula (I), where the radicals R1 and R2 are each, independently of one another, hydrogen, C1-C6-alkyl, C6-C12-aryl, such as phenyl, or C5-C12-cycloalkyl or R1 and R2 together with the double bond to which they are bound form a C6-C12-aryl radical, such as phenyl, a phenyl radical substituted by one or more C1-C6-alkyl groups, halogen atoms or alkoxy groups or a monounsaturated or polyunsaturated C5-C12-cycloalkyl radical, R3, R4 are each, independently of one another, hydrogen, methyl, trifluoromethyl or nitrile, which comprises electrochemically oxidizing 1,4-dialkoxy-1,3-butadiene of the formula II where the radicals R1, R3 and R4 have the same meanings as in the formula I, in the presence of a C1-C6-alkyl alcohol.
Abstract:
The present invention relates to suspensions for odor reduction comprising a porous metal-organic framework material in a liquid, and also atomizer and methods for odor reduction using the suspensions. The invention likewise relates to the use of the suspensions for odor reduction.
Abstract:
The present invention relates to a method for separating off odor substances from gases, comprising gas with at least one filter comprising a porous metal-organic framework material, the framework material comprising at least one, at least bidentate, organic compound which is bound by coordination to at least one metal ion.
Abstract:
Process for preparing primary amines having a cyclopropyl unit and a primary amino group bound to an aliphatic or cycloaliphatic carbon atom (amine A) by cathodically reducing oximes having a cyclopropyl unit or oxime derivatives in which the hydrogen atom in the oxime group has been replaced by an alkyl or acyl group (oxime O) at a temperature of from 50 to 100° C. in an essentially anhydrous electrolyte solution in a divided electrolysis cell.
Abstract:
The invention relates to a method for producing a uniform flow through an electrolyte space of an electrolysis cell, in which a maximum deviation of less than 1% to 25% from the average flow rate is achieved by suitable design measures. The invention also relates to an electrolysis cell with at least two electrolyte spaces, in each of which at least one electrode is arranged and each of which has an inlet region and an outlet region, the flow cross section being reduced in the inlet and/or outlet region so as to produce an additional pressure reduction
Abstract:
The present invention relates to a gauze catalyst based on titanium or vanadium zeolites and inert gauze fabrics which is suitable for accelerating oxidation reactions such as epoxidation of olefins, hydrogen peroxide production or hydroxylamine synthesis.
Abstract:
A process is disclosed for preparing phthalides by cathodic reduction of phthalic acid or phthalic acid derivatives, in which the carboxylic acid units may be substituted by units which can be derived by a condensation reaction from carboxylic acid units and in which one or several hydrogen atoms of the o-phenylene unit of the phthalic acid may be substituted by inert radicals. This process is characterised in that the reduction is carried out in an organic solvent which contains less than 50 wt % water and in a non-divided electrolytic cell.
Abstract:
Process for preparing primary amines having a cyclopropyl unit and a primary amino group bound to an aliphatic or cycloaliphatic carbon atom (amine A) by cathodically reducing oximes having a cyclopropyl unit or oxime derivatives in which the hydrogen atom in the oxime group has been replaced by an alkyl or acyl group (oxime O) at a temperature of from 50 to 100° C. in an essentially anhydrous electrolyte solution in a divided electrolysis cell.
Abstract:
A process for the preparation of 2,5-dihydrofuran derivatives substituted in the 3- or 4-position, which in the 2- or in the 5-position or at both positions each carry a C1- to C6-alkoxy radical (DHF-alkoxy derivatives 1), or 1,1,4,4-tetraalkoxy-but-2-ene derivatives substituted in the 3- or 4-position, from 2-butene-1 ,4-diol derivatives of the general formula (I) in which the radicals R1 and R2 independently of one another are hydrogen, C1- to C6-alkyl, C6- to C12-aryl or C5- to C12-cycloalkylene orR1 and R2, together with the double bond to which they are bonded, form a C6- to C12-aryl radical or a mono- or polyunsaturated C5- to C12-cycloalkyl radical,orfrom their mixture with 2,5-dihydrofuran derivatives substituted in the 3- position or 4-position, which in the 2- or in the 5-position carry a C1- to C6-alkoxy radical, by electro-chemical oxidation in the presence of a C1- to C6-monoalkyl alcohol.