Abstract:
A method for preparing polyolefin from alpha-olefin with high productivity using an internal circulating fluidized bed polymerization reactor is disclosed. The method for gas-phase polymerization of alpha-olefin comprising the steps of: supplying circulation gas including one or more alpha-olefins and inert gas into a polymerization reactor; polymerizing the alpha-olefin to polyolefin in two separated polymerization areas in the polymerization reactor; and discharging produced polyolefin from the polymerization reactor. The polymerization reactor is divided into the two polymerization areas by a draft tube, and an inside of the draft tube forms a riser where growing polyolefin polymers move up in fast fluidization, and an outside of the draft tube forms an annulus where the polyolefin polymers passing the riser move down by gravity, and the polyolefin polymers passing the annulus are introduced to a lower part of the riser again, so that the polyolefin polymers are polymerized during circulating between the riser and the annulus.
Abstract:
A multinuclear transition metal compound which has two or more catalytic active sites, and is useful in preparing the olefin polymer and copolymer, is disclosed. The multinuclear transition metal compound for olefin polymerization includes two or more metals, and at least one ligand having a cyclopentadienyl moiety, which connects the two or more metals. The preferable multinuclear transition metal catalyst for olefin polymerization includes the first transition metal, the first η ligand having a cyclopentadienyl moiety, which is coordinated to the first transition metal, and the second transition metal to which the second η ligand having a cyclopentadienyl moiety is coordinated, wherein the second transition metal is bonded to the first η-ligand via a sigma (σ) bond.
Abstract:
The present invention relates to supported metallocene catalysts and to new processes for preparing them and olefin polymerization therewith. Specifically, this invention relates to supported catalyst benefiting from the penetration and homogeneous distribution of catalyst components containing one or more metallocenes and activators within porous support particles. A new process for preparing the catalyst of the invention provides for a supported metallocene catalyst, wherein one or more metallocenes and activator, a solvent capable of dissolving them and a porous support are mutually contacted to form a slurry and a sonic wave or vibrating wave in the frequency range of 1-10,000 kHz is applied to the slurry and the solvent is removed and the resultants are dried. The catalyst are useful for olefin polymerization in a slurry and gas phase polymerization process.
Abstract:
There are disclosed new metallocene compounds and catalysts for olefin polymerization. The metallocene compound is a complex of transition metal and cyclopentadienyl-type ligands substituted with silacycloalkyl group. The metallocene catalyst comprises the above metallocene compound and at least one activator such as aluminoxanes, aromatic boron compounds substituted with fluoride, and modified clays. The metallocene catalyst can be used for polymerization of olefin in liquid phase, slurry phase or gas phase process.
Abstract:
A method for preparing polyolefin from alpha-olefin with high productivity using an internal circulating fluidized bed polymerization reactor is disclosed. The method for gas-phase polymerization of alpha-olefin comprising the steps of: supplying circulation gas including one or more alpha-olefins and inert gas into a polymerization reactor; polymerizing the alpha-olefin to polyolefin in two separated polymerization areas in the polymerization reactor; and discharging produced polyolefin from the polymerization reactor. The polymerization reactor is divided into the two polymerization areas by a draft tube, and an inside of the draft tube forms a riser where growing polyolefin polymers move up in fast fluidization, and an outside of the draft tube forms an annulus where the polyolefin polymers passing the riser move down by gravity, and the polyolefin polymers passing the annulus are introduced to a lower part of the riser again, so that the polyolefin polymers are polymerized during circulating between the riser and the annulus.
Abstract:
The present application discloses a method for preventing or retarding degeneration of intervertebral disc at an intervertebral disc defect site, which includes injecting a mammalian connective tissue cell into the intervertebral disc defect site.
Abstract:
In an apparatus for manufacturing semiconductor devices, a container is disposable on a load port and is adapted to accommodate one or more wafers. A transfer robot is installed at a frame and the frame is located between the load port and processing equipment. The transfer robot moves the one or more wafers between the processing equipment and the container. A gas supplying part blows a more desirable gas, e.g., a nitrogen gas or an inert gas, into the container through opening holes formed through a wall of the container. The more desirable gas flows (due to a pressure gradient) from the container to the frame to substantially (if not completely) prevent a less desirable gas (e.g., contaminated air) in the frame from entering the container as the one or more wafers are moved between the container and the processing chamber.
Abstract:
Provided is an apparatus for fabricating a semiconductor device using plasma, whereby a semiconductor device fabricating process using plasma provides significantly greater uniformity. The apparatus includes a process chamber, a first electrode through which a radio frequency (RF) power is supplied into the process chamber, a second electrode having a semiconductor substrate placed thereon, wherein the second electrode is disposed in the process chamber to face the first electrode and generates plasma used in fabricating a semiconductor device on the semiconductor substrate using the RF power, and a confinement ring assembly disposed between the first electrode and the second electrode, including a first confinement ring that moves in the vertical direction and a second confinement ring that surrounds the first confinement ring and moves in the vertical direction.
Abstract:
A molded case circuit breaker having a contact on mechanism which can perform a trip operation and automatically rotates the handle to the on position or a position toward the on position if the handle is manipulated to move to the off (or reset) position in a state that the contacts are melt-adhered to each other, the contact on mechanism, including: a contact on plate which is vertically movable by being guided according to the operation of the switching mechanism, a trip bar that drives the restricting unit to a releasing position, a lever connected to the handle and that provides a pivot point of the handle, a lever pin fixed to the lever, for driving the restricting unit to the releasing position by pressing the trip bar, and thereby operating the switching mechanism to the trip position, and a trip spring providing an elastic driving force for enabling the switching mechanism to operate to the trip position when the restricting unit is moved to the releasing position.