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公开(公告)号：US4407782A
公开(公告)日：1983-10-04
申请号：US299267
申请日：1981-09-03
Applicant: John H. Estes
Inventor： John H. Estes
CPC classification number: C01B39/22 , Y10S423/21
Abstract: A novel crystalline zeolite composition is prepared by conducting the hydrothermal crystallization and, preferably, a preliminary aging step, at high pressure, i.e. pressures in excess of 20,000 psig (ca 138 MPa) and preferably above about 40,000 psig (ca 276 MPa megaPascals). The crystalline zeolite, designated zeolite HP, has a higher aluminum content than zeolite X and a lattice constant of above 24.94 A up to 25.10 A.
Abstract translation: 通过在高压下，即超过20,000psig（约138MPa），优选高于约40,000psig（约276MPa兆帕）的压力下进行水热结晶，优选进行预熟化步骤来制备新的结晶沸石组合物。 称为沸石HP的结晶沸石具有比沸石X更高的铝含量和高达24.94A至高达25.10A的晶格常数。
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公开(公告)号：US4306962A
公开(公告)日：1981-12-22
申请号：US231819
申请日：1981-02-05
Applicant: John H. Estes
Inventor： John H. Estes
CPC classification number: C10G11/05 , B01J29/08 , C01B33/2815 , C01B39/22
Abstract: A novel crystalline zeolite composition is prepared by conducting the hydrothermal crystallization and, preferably, a preliminary aging step, at high pressure, i.e. pressures in excess of 20,000 psig (ca 138 MPa) and preferably above about 40,000 psig (ca 276 MPa megaPascals). The crystalline zeolite, designated zeolite HP, has a higher aluminum content than zeolite X and a lattice constant of above about 25.02 A.
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公开(公告)号：US4171329A
公开(公告)日：1979-10-16
申请号：US887392
申请日：1978-03-16
Applicant: Leon F. Koniz , John H. Estes
Inventor： Leon F. Koniz , John H. Estes
CPC classification number: B01J23/85 , C07C4/20 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/24 , C07C2523/74 , C07C2523/85
Abstract: Alkylaromatic charge hydrocarbons such as toluene are steam dealkylated in the presence of catalyst which typically contains oxides of nickel, chromium, and potassium on an activated high-purity alumina. It is a feature of this invention that the high-purity alumina is activated by calcining followed by addition thereto of alkaline earth metal such as calcium or magnesium. A test is disclosed according to which it may be determined which high-purity aluminas are suitable for use.
Abstract translation: 烷基芳族电荷烃如甲苯是在催化剂存在下蒸汽脱烷基化的，催化剂通常在活化的高纯度氧化铝上含有镍，铬和钾的氧化物。 本发明的一个特征是高纯度氧化铝通过煅烧而活化，然后加入碱土金属如钙或镁。 公开了可以确定哪种高纯度氧化铝适合使用的试验。
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公开(公告)号：US4160011A
公开(公告)日：1979-07-03
申请号：US865452
申请日：1977-12-29
Applicant: John H. Estes , Stanley Kravitz , Robert M. Suggitt
Inventor： John H. Estes , Stanley Kravitz , Robert M. Suggitt
CPC classification number: C01B33/2823 , C01B39/20 , Y10S423/21 , Y10S423/24
Abstract: An amorphous powder useful as a precursor for the preparation of crystalline aluminosilicates is prepared by forming a sodium aluminum silicate water mixture whose composition falls within specified ranges for forming sodium zeolite A. By dehydrating the mixture with a water miscible solvent prior to aging and crystal formation, an amorphous powder is recovered for future use. Upon subsequent treatment the amorphous powder can be converted to crystalline aluminosilicates including type 3A, 4A, 5A, X and Y.
Abstract translation: 可用作制备结晶铝硅酸盐的前体的无定形粉末通过形成其组成落入用于形成钠沸石A的特定范围内的硅酸钠水混合物来制备。通过在老化和晶体形成之前用水混溶性溶剂脱水混合物 回收无定形粉末以供将来使用。 随后的处理可以将无定形粉末转化为包括3A，4A，5A，X和Y型晶体的硅铝酸盐。
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5.发明授权Hydroisomerization of normal paraffin with a catalyst of noble metal, alumina support and chlorine 失效正烷烃与贵金属，氧化铝载体和氯的催化剂加氢异构化
公开(公告)号：US4113789A
公开(公告)日：1978-09-12
申请号：US774099
申请日：1977-03-03
Applicant: Babu Y. Rao , John T. Nolan, Jr. , John H. Estes
Inventor： Babu Y. Rao , John T. Nolan, Jr. , John H. Estes
CPC classification number: B01J37/24 , B01J23/38 , B01J37/08 , C07C5/2791
Abstract: A process for the hydroisomerization of paraffinic hydrocarbons employing a catalyst composed of a noble metal, alumina and chlorine. The catalyst is prepared by treating a composite of noble metal and alumina with an aluminum compound such as an inorganic or organic salt of aluminum, preferably aluminum nitrate, calcining the treated composite and thereafter contacting the treated composite with a conventional chloride activating agent. By treating and calcining the composite with an aluminum salt, the amount of noble metal retained on the catalyst's surface during chloride activation is maximized enabling high conversions of normal paraffins to isoparaffins to be realized.
Abstract translation: 使用由贵金属，氧化铝和氯构成的催化剂对链烷烃进行加氢异构化的方法。 通过用铝化合物如铝的无机或有机盐，优选硝酸铝处理贵金属和氧化铝的复合物，煅烧所述经处理的复合材料，然后使经处理的复合材料与常规氯化物活化剂接触来制备催化剂。 通过用铝盐处理和煅烧复合材料，在氯化物活化期间保留在催化剂表面上的贵金属的量最大化，使得能够实现正链烷烃到异链烷烃的高转化率。
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Patent Agency Ranking
公开(公告)号：US4089811A
公开(公告)日：1978-05-16
申请号：US737304
申请日：1976-11-01
Applicant: Leon F. Koniz , John H. Estes
Inventor： Leon F. Koniz , John H. Estes
Abstract: Alumina, derived as by-product of the Zeigler-catalyzed higher alcohol process, is converted to beta alumina trihydrate and alpha alumina trihydrate in controlled proportions and thence to the catalytic transition aluminas.
Abstract translation: 作为Zeigler催化的高级醇工艺的副产物衍生的氧化铝以受控的比例转化成β氧化铝三水合物和α氧化铝三水合物，然后转化为催化转移氧化铝。
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公开(公告)号：US4033901A
公开(公告)日：1977-07-05
申请号：US656048
申请日：1976-02-06
Applicant: Ernest P. Buinicky , Joseph A. Durkin , John H. Estes
Inventor： Ernest P. Buinicky , Joseph A. Durkin , John H. Estes
CPC classification number: C07D301/19 , B01J23/00 , B01J23/30 , B01J37/0009
Abstract: Disclosed is a shaped catalyst composed of finely divided particles of binary or ternary boride compounds having the general formula M.sub.x B.sub.y or M.sub.x B.sub.y R.sub.2 wherein x is an integer from 1-5; y is an integer from 1-2; z is an integer from 1-4; B is boron; M is an element selected from the groups II-A, III-B, IV-B, V-B, VI-B, VII-B, VIII, III-A, IV-A, and V-A of the Periodic Table, the rare earths, and the actinides; R is an element different from M selected from the same group of elements in the Periodic Table as M; the particles being bonded by 1 to 10% by weight of finely divided particles of preoxidized aluminum, zinc, or magnesium. The preferred catalyst materials are those boron-containing substances which are substantially insoluble in the reaction mixture containing the organic hydroperoxides olefins and products and which are bonded by heat treated aluminum particles having an oxide coating constituting from 5 to 10 percent of the particles.Also disclosed is a method for the liquid phase epoxidation of an olefinic compound with an organic hydroperoxide at temperatures of about 90.degree. to 130.degree. C at a pressure sufficient to maintain the mixture substantially in liquid phase in the presence of a catalytically effective amount of the novel catalyst material.
Abstract translation: 公开了一种成形催化剂，其由具有通式M x B y或M x B y R 2的二元或三元硼化物的细碎颗粒组成，其中x为1-5的整数; y是1-2的整数; z是1-4的整数; B是硼; M是选自元素周期表II-A，III-B，IV-B，VB，VI-B，VII-B，VIII，III-A，IV-A和VA中的元素，稀土 ，和锕系元素; R是与M相同的元素周期表中选择的不同于M的元素; 颗粒通过预氧化的铝，锌或镁的细碎颗粒1-10％重量的比例粘合。 优选的催化剂材料是在含有有机氢过氧化物烯烃和产物的反应混合物中基本上不溶的含硼物质，它们通过具有构成颗粒的5-10％的氧化物涂层的热处理的铝颗粒结合。
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公开(公告)号：US4289740A
公开(公告)日：1981-09-15
申请号：US92162
申请日：1979-11-07
Applicant: John H. Estes
Inventor： John H. Estes
CPC classification number: C01B39/22
Abstract: A novel crystalline zeolite composition is prepared by conducting the hydrothermal crystallization and, preferably, a preliminary aging step, at high pressure, i.e. pressures in excess of 20,000 psig (ca 138 MPa) and preferably above about 40,000 psig (ca 276 MPa megaPascals). The crystalline zeolite, designated zeolite HP, has a higher aluminum content than zeolite X and a lattice constant of above about 25.02 A.
Abstract translation: 通过在高压下，即超过20,000psig（约138MPa），优选高于约40,000psig（约276MPa兆帕）的压力下进行水热结晶，优选进行预熟化步骤来制备新的结晶沸石组合物。 称为沸石HP的结晶沸石具有比沸石X更高的铝含量和高于约25.02A的晶格常数。
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公开(公告)号：US4223731A
公开(公告)日：1980-09-23
申请号：US963617
申请日：1978-11-24
Applicant: John H. Estes , Ernest P. Buinicky
Inventor： John H. Estes , Ernest P. Buinicky
Abstract: An enhanced oil recovery method comprising injecting an aqueous solution of ammonium salts selected from the group consisting of ammonium sulfite, ammonium bisulfite, and mixtures thereof into a petroleum-bearing earth formation, heating said injected aqueous solution to a temperature in the range of about 120.degree.-300.degree. F., or higher in the presence of said petroleum-bearing earth formation, flowing said heated aqueous solution through said petroleum bearing earth formation to drive petroleum to a recovery well, and producing increased amounts of petroleum from said earth formation through said recovery well.
Abstract translation: 一种增强的油回收方法，包括将选自亚硫酸铵，亚硫酸氢铵及其混合物的铵盐水溶液注入含石油的地层中，将所述注入的水溶液加热至约120℃ 在所述含石油的地层的存在下，在-300°F或更高的温度下，使所述加热的水溶液流过所述含石油的地层，以驱动石油回收井，并从所述地层中产生增加量的石油，通过 说恢复好。
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公开(公告)号：US4138444A
公开(公告)日：1979-02-06
申请号：US848186
申请日：1977-11-03
Applicant: Sheldon Herbstman , Edward L. Cole , John H. Estes
Inventor： Sheldon Herbstman , Edward L. Cole , John H. Estes
CPC classification number: C07C2/76 , C07C9/16 , C07C2521/04 , C07C2523/32 , C07C2523/40 , C07C2523/74
Abstract: Isobutane is self-alkylated to an alkylate composition having high octane components including trimethylpentanes in the presence of a solid catalyst and a minor amount of a C.sub.5 and higher olefin. The self-alkylation process utilizes a chlorided alumina catalyst having from about 4 to 15 weight percent chlorine. The olefins of choice employed in the isobutane self-alkylation reaction are isoolefins having 6 or 7 carbons. The isobutane may be derived from the isomerization of n-butane and the isomerization process may be integrated with the self-alkylation process.
Abstract translation: 在固体催化剂和少量C5和更高级烯烃的存在下，异丁烷被自烷基化成具有高辛烷值组分（包括三甲基戊烷）的烷基化物组合物。 自烷基化方法利用具有约4至15重量％氯的氯化氧化铝催化剂。 在异丁烷自烷基化反应中使用的烯烃是具有6或7个碳原子的异烯烃。 异丁烷可以衍生自正丁烷的异构化，并且异构化过程可与自烷基化方法结合。
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