摘要:
A process is described for preparing N-substituted 3-hydroxypyrazoles of the formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or heteroaryl andR.sup.2, R.sup.3 are hydrogen, cyano, halogen and unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or heteroaryl,by oxidizing a corresponding pyrazolidin-3-one.
摘要:
Preparation of O-substituted hydroxylammonium salts of the formula IH.sub.2 NOR x HX Iwhere R is a C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl radical, each of which may be halogen-substituted, and X is chlorine or bromine, by reacting in an integrated process, without isolation of intermediatesa) acetone with hydroxylammonium sulfate and sodium hydroxide solution to give acetone oxime;b) treating the solution of acetone oxime thus obtained with sodium hydroxide solution and completely removing water,c) reacting the suspension of the acetone oxime Na salt thus obtained with alkylating agents at from 0.5 to 15 bar and at up to 140.degree. C. to give acetone oxime ethers; andd) cleaving the acetone oxime ethers with acids HX to give the products I,a homogeneous, nonpolar aprotic solvent being used in all process steps a) to d).
摘要翻译:式I的O-取代羟铵盐的制备H 2 NOR x HXI其中R是C1-C6烷基或C2-C6-烯基,其各自可以被卤素取代,X是氯或溴,通过在 一体化方法,不分离中间体a)丙酮与硫酸羟铵和氢氧化钠溶液得到丙酮肟; b)用氢氧化钠溶液处理由此获得的丙酮肟溶液并完全除去水,c)使得到的丙酮肟钠盐与烷基化剂的悬浮液在0.5至15巴和至多140℃下反应至 给予丙酮肟醚; 和d)用酸HX裂解丙酮肟醚以产生产物I,所有方法步骤a)至d)中使用均匀的非极性非质子溶剂。
摘要:
The invention relates to a method and arrangement for controlling the fuel metered to an engine and especially to a diesel engine. The engine includes a fuel pump drive by a shaft for which injection start and injection end is fixed by a corresponding control of the electromagnetically actuated valve. The drive pulses for pump-delivery start and pump-delivery end are generated in dependence upon the analog signal of an angle sensor.
摘要:
The invention is directed to an apparatus and a method for controlling the operating characteristic quantities of an internal combustion engine, with a characteristic set up with operating quantities of the internal combustion engine for pre-control of engine variables influencing the operating characteristic quantities, and with a control arrangement, responsive to at least one engine variable, for correctively influencing the characteristic values. The values stored in the characteristic field and selected in dependence on operating characteristic quantities of the internal combustion engine are modified via the control arrangement to correctively influence the characteristic values. In addition, the characteristic values lying within the defined region of the characteristic value modified are also changed in dependence on the modification of this particular characteristic value. The fact that the modification of a characteristic region in dependence on the modification of its respective characteristic value is weighted, permits a rapid and accurate adaptation of the characteristic to the actual operating conditions of the internal combustion engine. The invention is advantageously suitable for use in various control systems contolling air-fuel metering, ignition point, charge-air pressure, exhaust-gas recirculation of idle speed, for example.
摘要:
The invention is directed to an apparatus for controlling the operating characteristic quantities of an internal combustion engine. The apparatus includes a characteristic field for pre-controlling engine variables influencing the operating characteristic quantities. The characteristic field is made up of the operating characteristic quantities. The apparatus further includes a control arrangement for controlling to maximum power output of the engine. The control arrangement is superposed on the pre-control and includes means for determining corrective values from the control loop in a predetermined operating range of the engine. The corrective values are applied to influence all of the pre-control values of the characteristic field over all operating ranges. With the apparatus of the invention, it is possible in a simple manner to consider changes in the surrounding factors that influence the engine. Two embodiments are described wherein the control is achieved by means of an optimizer and the engine is controlled to maximum power in either the part-load range or the full-load range of the engine. The apparatus of the invention can be used, for example, in air-fuel mixture metering, charging air control, control of exhaust gas return or also idle control.
摘要:
The ignition timing, or ignition instant, is determined by generating electric voltages representative of various operating parameters of the internal combustion engine, and modifying these voltages in a function generator to derive ignition control signals. An entirely electronic, or servo-operated adjustment system is responsive to the modified voltages to control the ignition system for proper timing of the ignition spark; in accordance with the present invention, the control system forms part of a closed control loop. In accordance with a feature of the invention, the engine itself forms part of the control loop, in that the effect on an operation parameter of the engine, for example composition of exhaust gases, is evaluated and fed back as an input control quantity to modify the ignition timing.
摘要:
The invention is directed to a method and an arrangement for controlling the fuel injection in a high-pressure fuel pump. Magnetic valves determine the fuel quantity to be injected into the engine. The magnetic valve is controlled during the pumping phase of the pumping element in such a manner that first a preinjection and then a main injection is carried out. In specific operating conditions, the control apparatus determines the duration of the drive pulses for the magnetic valve at which a preinjection just takes place. With the duration of the drive pulses as a basis, the control apparatus forms compensating signals for the drive pulses which effect preinjection and stores the same.
摘要:
A method for determining adjustment values for a fuel supply device which supplies a fuel mixture to a fuel-burning engine for optimum performance by additionally influencing the preset adjustment values of the fuel supply device itself from values supplied by a storage means containing an engine performance log of adjustment values whereby said performance adjustment values are continuously changed and replaced by values which reflect instantaneous operating engine characteristics. Each replaced value forms the basis for computing a new value upon a change in engine operating characteristics. The apparatus disclosed comprises a fuel supply device, such as a carburetor, which has its adjustment values preset due to its construction, a storage means containing engine performance adjustment values for correcting the preset values of the supply device in response to engine operating characteristics, and a second storage means connected to the fuel supply device and to the first storage means wherein the performance values from said first storage means are continuously adjusted from the engine operating characteristics and stored for use by the fuel supply device for optimum engine operating performance.
摘要:
To prevent application of excessive spark energy in an ignition system designed for proper firing voltages even under low-battery voltage conditions, upon rise of the battery voltage to normal or excessive values, a voltage sensing circuit, including a threshold stage, is connected to the secondary of the ignition coil to sense the secondary voltage, the threshold stage providing an output when the voltage is exceeded and blocking continued supply of power to the ignition coil of the system to thereby limit the ignition voltage.