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    Hydrogenated block copolymer and polypropylene resin composition containing the same
    5.
    发明授权
    Hydrogenated block copolymer and polypropylene resin composition containing the same 有权
    氢化嵌段共聚物和含有它们的聚丙烯树脂组合物

    公开(公告)号：US06310138B1

    公开(公告)日：2001-10-30

    申请号：US09485130

    申请日：2000-04-05

    申请人： Jun Yonezawa ,  Kiyoo Kato

    发明人： Jun Yonezawa ,  Kiyoo Kato

    IPC分类号： C08L5302

    CPC分类号： C08F8/04 ,  C08F297/04 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L53/00 ,  C08L53/02 ,  C08L53/025 ,  C08L2205/035 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04

    摘要： A hydrogenated block copolymer comprising: two polymer blocks A mainly comprising vinylaromatic hydrocarbon compound monomer units; and one hydrogenated polymer block B mainly comprising butadiene monomer units, in which at least 90% of olefinically unsaturated double bonds contained in a polymer block mainly comprising butadiene monomer units before hydrogenation have been hydrogenated, wherein a bonding vinylaromatic hydrocarbon compound content in the hydrogenated block copolymer is higher than 13 wt % but lower than 25 wt %, a 1,2-bond content in the unhydrogenated polymer block mainly comprising butadiene monomer units is higher than 40 mol % but lower than 60 mol %, and the copolymer has a quantity of heat of crystal fusion (&Dgr;H) smaller than 0.05 J/g, an order-disorder transition temperature of 200° C. or higher, and a melt flow rate (MFR) value, as determined in accordance with JIS K7210 under the conditions of a temperature of 230° C. and a load of 2.16 kg, of from not smaller than 0.1 g/10 min to smaller than 30 g/10 min. By incorporating the copolymer into a polypropylene resin, a composition which is suitable for giving a molded article having an excellent balance among impact resistance, brittle temperature, rigidity, heat distortion resistance, and tensile elongation at break, can be obtained.

    摘要翻译： 一种氢化嵌段共聚物，包括：主要包含乙烯基芳族烃化合物单体单元的两个聚合物嵌段A; 和主要包含丁二烯单体单元的一个氢化聚合物嵌段B，其中主要包含氢化之前的丁二烯单体单元的聚合物嵌段中包含的至少90％的烯属不饱和双键已被氢化，其中在氢化嵌段中键合的乙烯基芳族烃化合物含量 共聚物高于13重量％但低于25重量％，主要包含丁二烯单体单元的未氢化聚合物嵌段中的1,2-键含量高于40摩尔％但低于60摩尔％，共聚物的量 的结晶熔融热（DELTAH）小于0.05J / g，无序转变温度为200℃以上，熔体流动速率（MFR）值根据JIS K7210在条件下测定 温度为230℃，负荷为2.16kg，为0.1g / 10分钟以上，小于30g / 10分钟。 通过将共聚物结合到聚丙烯树脂中，可以获得适合于赋予耐冲击性，脆性温度，刚性，耐热变形性和断裂拉伸伸长率之间优异平衡的成型体的组合物。

    Hydrogenated block copolymer and composition of the same
    6.
    发明授权
    Hydrogenated block copolymer and composition of the same 失效
    氢化嵌段共聚物及其组成

    公开(公告)号：US06239218B1

    公开(公告)日：2001-05-29

    申请号：US09057404

    申请日：1998-04-09

    申请人： Jun Yonezawa ,  Kiyoo Kato ,  Eiji Sasaya ,  Takashi Sato

    发明人： Jun Yonezawa ,  Kiyoo Kato ,  Eiji Sasaya ,  Takashi Sato

    IPC分类号： C08L5302

    CPC分类号： C08L53/00 ,  C08F297/04 ,  C08L23/10 ,  C08L53/005 ,  C08L53/025 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2308/00 ,  G03F7/0002 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

    摘要： A hydrogenated block copolymer comprising: at least two polymer blocks A mainly comprising vinylaromatic hydrocarbon compound monomer units; and at least two polymer blocks B mainly comprising hydrogenated conjugated diene compound monomer units, in which at least 90% of the olefinically unsaturated double bonds contained in the unhydrogenated polymer block mainly comprising the conjugated diene compound monomer units is hydrogenated, wherein at least one of the terminal blocks is a polymer block B, the proportion of the terminal polymer block B in the hydrogenated block copolymer being 0.1% by weight or higher and lower than 9.1% by weight, and wherein the content of the vinylaromatic hydrocarbon compound units in the hydrogenated block copolymer is 12% by weight or higher and lower than 25% by weight. Also disclosed are a resin composition containing the hydrogenated block copolymer, and a molded article of the resin composition.

    摘要翻译： 一种氢化嵌段共聚物，其包含：至少两个主要包含乙烯基芳族烃化合物单体单元的聚合物嵌段A; 以及主要包含氢化共轭二烯化合物单体单元的至少两个聚合物嵌段B，其中主要包含共轭二烯化合物单体单元的未氢化聚合物嵌段中包含的至少90％的烯属不饱和双键被氢化，其中至少一个 端基是聚合物嵌段B，氢化嵌段共聚物中的末端聚合物嵌段B的比例为0.1重量％以上且低于9.1重量％，其中氢化的乙烯基芳烃化合物单元的含量 嵌段共聚物为12重量％以上且低于25重量％。 还公开了含有氢化嵌段共聚物的树脂组合物和树脂组合物的模塑制品。

    Hydrogenated block copolymer
    8.
    发明授权
    Hydrogenated block copolymer 有权
    氢化嵌段共聚物

    公开(公告)号：US06458891B1

    公开(公告)日：2002-10-01

    申请号：US09554314

    申请日：2000-05-12

    申请人： Jun Yonezawa ,  Eiji Sasaya

    发明人： Jun Yonezawa ,  Eiji Sasaya

    IPC分类号： C08F29704

    CPC分类号： C08L25/04 ,  C08F8/04 ,  C08L23/10 ,  C08L23/12 ,  C08L25/06 ,  C08L53/025 ,  C08L71/12 ,  C08L71/123 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08F297/04 ,  C08L2666/24 ,  C08L2666/22 ,  C08L2666/02 ,  C08L2666/04

    摘要： A hydrogenated block copolymer has at least two polymer blocks A each having an aromatic vinyl hydrocarbon compound monomer unit and at least two hydrogenated polymer blocks B each having a hydrogenated butadiene monomer unit. At least 90% of olefinically unsaturated double bonds in the polymer blocks mainly having a butadiene monomer unit before hydrogenation have been hydrogenated. At least one of the locks at the terminal of the hydrogenated block copolymer is the polymer block B. The proportion of the terminal polymer blocks B in the hydrogenated block copolymer is 0.1 wt % to 9.1 wt %. The proportion of the aromatic vinyl hydrocarbon compound in the hydrogenated block copolymer is 25 wt % to 80 wt %. The 1,2-bond content of the polymer blocks having a butadiene monomer unit before hydrogenation averages 60 mol % to 99 mol %. The resulting resin composition improves the balance among the appearance of its molded article, tensile elongation at break and moldability.

    摘要翻译： 氢化嵌段共聚物具有至少两个具有芳族乙烯基烃化合物单体单元和至少两个具有氢化丁二烯单体单元的氢化聚合物嵌段B的聚合物嵌段A. 在氢化之前，主要具有丁二烯单体单元的聚合物嵌段中的至少90％的烯属不饱和双键已被氢化。 氢化嵌段共聚物末端的至少一个锁是聚合物嵌段B.氢化嵌段共聚物中末端聚合物嵌段B的比例为0.1重量％至9.1重量％。 氢化嵌段共聚物中芳香族乙烯基烃化合物的比例为25重量％〜80重量％。 在氢化前具有丁二烯单体单元的聚合物嵌段的1,2-键含量平均为60mol％至99mol％。 所得到的树脂组合物改善了其模制品的外观，断裂拉伸伸长率和成型性之间的平衡。

    Hydrogenated block copolymer
    9.
    发明授权
    Hydrogenated block copolymer 有权
    氢化嵌段共聚物

    公开(公告)号：US06455635B1

    公开(公告)日：2002-09-24

    申请号：US09554310

    申请日：2000-05-12

    申请人： Jun Yonezawa ,  Shinichi Sekikawa ,  Hiromi Nakafutami ,  Takashi Sato

    发明人： Jun Yonezawa ,  Shinichi Sekikawa ,  Hiromi Nakafutami ,  Takashi Sato

    IPC分类号： C08F29700

    CPC分类号： C08L23/10 ,  C08F297/04 ,  C08L53/00 ,  C08L53/02 ,  C08L53/025 ,  C08L2666/24 ,  C08L2666/04

    摘要： A hydrogenated block copolymer which comprises at least two polymer blocks A each mainly comprising an aromatic vinyl hydrocarbon compound monomer unit and at least two hydrogenated polymer blocks B each mainly comprising a butadiene monomer unit, at least 90% of the olefinically unsaturated double bonds in said polymer block mainly comprising a butadiene monomer unit before hydrogenation having been hydrogenated, wherein at least one of the block at the terminal of the hydrogenated block copolymer is the polymer block B, wherein the proportion of the terminal polymer blocks B in the hydrogenated block copolymer is at least 0.1 wt % but less than 9.1 wt %, wherein the proportion of the aromatic vinyl hydrocarbon compound in the hydrogenated block copolymer exceeds 10 wt % but less than 25 wt %, wherein the 1,2-bond content of the polymer blocks mainly comprising a butadiene monomer unit before hydrogenation is, on average, at least 62 mole % but less than 99 mol %, and wherein the difference &Dgr;Tc (Tc1−Tc2) between the crystallization initiating temperature (Tc1) of the isotactic homopolypropylene and the crystallization initiating temperature (Tc2) of a mixture thereof with the hydrogenated block copolymer is at least 1.5° C.

    摘要翻译： 一种氢化嵌段共聚物，其包含至少两个主要包含芳族乙烯基烃化合物单体单元的聚合物嵌段A和至少两个主要包含丁二烯单体单元的氢化聚合物嵌段B，所述氢化聚合物嵌段B中所述的至少90％的所述烯属不饱和双键 氢化前主要包含丁二烯单体单元的聚合物嵌段被氢化，其中氢化嵌段共聚物末端的至少一个嵌段是聚合物嵌段B，其中氢化嵌段共聚物中末端聚合物嵌段B的比例为 至少0.1重量％但小于9.1重量％，其中氢化嵌段共聚物中芳族乙烯基烃化合物的比例超过10重量％但小于25重量％，其中聚合物的1,2-键含量主要 氢化前的丁二烯单体单元平均为至少62摩尔％但小于99摩尔％，其中， 全同立构均聚丙烯的结晶起始温度（Tc1）与其与氢化嵌段共聚物的混合物的结晶起始温度（Tc2）之间的差值DELTATc（Tc1-Tc2）为至少1.5℃