USE OF SILICON-CONTAINING PRECURSOR COMPOUNDS OF AN ORGANIC ACID AS A CATALYST FOR CROSS-LINKING FILLED AND UNFILLED POLYMER COMPOUNDS
    1.
    发明申请
    USE OF SILICON-CONTAINING PRECURSOR COMPOUNDS OF AN ORGANIC ACID AS A CATALYST FOR CROSS-LINKING FILLED AND UNFILLED POLYMER COMPOUNDS 审中-公开
    有机酸前体化合物作为催化剂用于交联填充和填充的聚合物化合物的使用

    公开(公告)号:US20110144277A1

    公开(公告)日:2011-06-16

    申请号:US13058290

    申请日:2009-07-09

    IPC分类号: B01J31/02 C08F8/00 B32B1/08

    CPC分类号: C08K5/5425 Y10T428/139

    摘要: The invention relates to the use of a silicon-containing precursor compound of an organic acid, particularly an olefinic silicon-containing precursor compound of an organic acid and/or of a tetracarboxyl silane, for the production of unfilled and/or filled polymer compounds, polymers, or filled plastics, such as granules or finished products, made from thermoplastic base polymers and/or monomers and/or prepolymers of the thermoplastic base polymers. A finished product is an item, such as a molded body, particularly a cable, hose, or pipe. The invention further relates to a master batch comprising the silicon-containing precursor compound.

    摘要翻译: 本发明涉及有机酸的含硅前体化合物,特别是有机酸和/或四羧基硅烷的烯属含硅前体化合物在制备未填充和/或填充的聚合物化合物中的用途, 聚合物或填充塑料,例如由热塑性基础聚合物和/或单体和/或热塑性基础聚合物的预聚物制成的颗粒或成品。 成品是成型体,特别是电缆,软管或管子。 本发明还涉及包含含硅前体化合物的母料。

    High-viscosity aqueous emulsions of functional alkoxysilanes, condensed oligomers thereof, organopolysiloxanes, their preparation and use for surface treatment of inorganic materials
    4.
    发明授权
    High-viscosity aqueous emulsions of functional alkoxysilanes, condensed oligomers thereof, organopolysiloxanes, their preparation and use for surface treatment of inorganic materials 有权
    功能性烷氧基硅烷的高粘度水性乳液,其缩合低聚物,有机聚硅氧烷,其制备和无机材料表面处理用途

    公开(公告)号:US07781520B2

    公开(公告)日:2010-08-24

    申请号:US11814127

    申请日:2005-12-08

    IPC分类号: B32B3/00 C08L83/06

    摘要: High-viscosity aqueous emulsions of functional alkoxysilanes, condensed oligomers thereof, organopolysiloxanes, their preparation and use for the surface treatment of inorganic materials High-viscosity aqueous oil-in-water emulsion which comprises from 50 to 90% by weight, based on the total weight of the emulsion, of functional alkoxysilanes and/or condensed oligomers thereof and/or organoalkoxysiloxanes, at least one emulsifier and water and has a pH of from 5 to 9 and a mean droplet size of the disperse phase of less than 5 μm, wherein the width of the droplet size distribution, expressed as the span (see formula (I)), is >1.5, preferably from 3 to 8. The preparation of the emulsions having the desired droplet size distribution is carried out in apparatuses having at least one pressure stage at a pressure of from 2 to 15 MPa. The emulsion can be used for hydrophobicizing porous mineral building materials. D ⁢ ⁢ 90 - D ⁢ ⁢ 10 D ⁢ ⁢ 50 ( I )

    摘要翻译: 功能性烷氧基硅烷的高粘度水性乳液,其缩合低聚物,有机聚硅氧烷,其制备和用于无机材料表面处理的用途高粘度水性水包油乳液,其含量为50-90%重量 乳液,功能性烷氧基硅烷和/或其缩合低聚物和/或有机烷氧基硅氧烷的重量,至少一种乳化剂和水,并且具有5至9的pH和分散相的平均液滴尺寸小于5μm,其中 液滴尺寸分布的宽度(以公式(I)表示)为> 1.5,优选为3至8.具有所需液滴尺寸分布的乳液的制备在具有至少一个 压力为2〜15MPa的压力。 该乳液可用于疏水化多孔矿物建筑材料。 D ud 90-Dé10 D um 50(I)

    TIN-FREE COMPOSITION FOR CROSSLINKING THERMOPLASTIC POLYOLEFINS
    5.
    发明申请
    TIN-FREE COMPOSITION FOR CROSSLINKING THERMOPLASTIC POLYOLEFINS 审中-公开
    用于交联热塑性聚烯烃的无铅组合物

    公开(公告)号:US20160200852A1

    公开(公告)日:2016-07-14

    申请号:US14913236

    申请日:2014-07-29

    IPC分类号: C08F255/02

    摘要: The invention relates to a composition for use in a Monosil process for the crosslinking of thermoplastic polyolefins which comprises(i) from 5 to 60% by weight content of caprylic acid (H3C(CH2)6COOH), (ii) content of at least one monounsaturated organofunctional alkoxysilane of the general formula I A-SiR2x(OR1)3-x  (I), where R1 is mutually independently a linear or branched hydrocarbon moiety having from 1 to 4 C atoms, R2 is methyl and x is 0 or 1 and A is a monovalent olefin group of the formula (R3)2C═C(R3)-Mk-, where k is 0 or 1, in which groups R3 are identical or different and R3 is a hydrogen atom or a methyl group and the group M is a group from this list: —CH2—, —(CH2)2—, —(CH2)3— and C(O)O—(CH2)3—, (iii) content of at least one free-radical generator and (iv) optionally content of at least one other component, where the entirety of all components (i) to (iv) gives 100% by weight. The present invention further relates to production processes and to mouldings or, respectively, products obtained therefrom, based on thermoplastic polyolefins, where a composition of the invention is reacted together with at least one thermoplastic polyolefin in a Monosil process. The invention further relates to the use of a composition of the invention in the Monosil process for the crosslinking of thermoplastic polyolefins during the production of products moulded by means of extrusion, based on thermoplastic polyolefins.

    摘要翻译: 本发明涉及用于交联热塑性聚烯烃的Monosil方法的组合物,其包含(i)5至60重量%的辛酸(H3C(CH2)6COOH)含量,(ii)至少一种 通式I A-SiR 2 x(OR 1)3-x(I)的单不饱和有机官能烷氧基硅烷,其中R 1相互独立地为具有1至4个C原子的直链或支链烃部分,R 2为甲基且x为0或1, A是式(R3)2C = C(R3)-Mk-的一价烯烃基,其中k是0或1,其中基团R3相同或不同,R3是氢原子或甲基,基团 M是该列表中的基团:-CH 2 - , - (CH 2)2 - , - (CH 2)3 - 和C(O)O-(CH 2)3 - ,(iii)至少一种自由基发生剂 和(iv)至少一种其它组分的任选含量,其中所有组分(i)至(iv)的全部量为100重量%。 本发明进一步涉及制备方法,以及基于热塑性聚烯烃从其获得的成型品或其制品,其中本发明的组合物与Monosil方法中的至少一种热塑性聚烯烃一起反应。 本发明还涉及本发明的组合物在Monosil方法中用于在通过基于热塑性聚烯烃的挤出成型的产品生产期间交联热塑性聚烯烃。

    TIN-FREE CATALYST-CONTAINING COMPOSITION FOR A MONOSIL PROCESS WITH OPTIMIZED PROCESS PROPERTIES
    6.
    发明申请
    TIN-FREE CATALYST-CONTAINING COMPOSITION FOR A MONOSIL PROCESS WITH OPTIMIZED PROCESS PROPERTIES 审中-公开
    具有优化工艺特性的单层工艺的无含催化剂的组合物

    公开(公告)号:US20160200843A1

    公开(公告)日:2016-07-14

    申请号:US14912710

    申请日:2014-07-29

    IPC分类号: C08F210/02 B29C47/00

    摘要: The invention relates to a composition for use in a Monosil process for the crosslinking of thermoplastic polyolefins which comprises (i) from 5 to 60% by weight content of 2-ethyl hexanoic acid [H3C(CH2)3CH(C2H5)COOH], (ii) content of at least one monounsaturated organofunctional alkoxysilane of the general formula I A-SiR2x(OR1)3-x   (I), where R1 is mutually independently a linear or branched hydrocarbon moiety having from 1 to 4 C atoms, R2 is methyl and x is 0 or 1 and A is a monovalent olefin group of the formula (R3)2C=C(R3)-Mk-, where k is 0 or 1, in which groups R3 are identical or different and R3 is a hydrogen atom or a methyl group and the group M is a group from the following list: —CH2—, —(CH2)2—, —(CH2)3— and —C(O)O—(CH2)3—, (iii) content of at least one free-radical generator and (iv) optionally content of at least one other component, where the entirety of all components (i) to (iv) gives 100% by weight. The present invention further relates to a production process, and also to mouldings or products obtainable thereby based on thermoplastic polyolefins, where a composition of the invention is reacted together with at least one thermoplastic polyolefin in a Monosil process. The invention further relates to the use of a composition of the invention in the Monosil process for the crosslinking of thermoplastic polyolefins during the production of products moulded by means of extrusion, based on thermoplastic polyolefins.

    摘要翻译: 本发明涉及一种用于交联热塑性聚烯烃的Monosil方法的组合物,其包含(i)5-60重量%的2-乙基己酸[H3C(CH2)3CH(C2H5)COOH],( ii)至少一种通式I A-SiR 2 x(OR 1)3-x(I)的单不饱和有机官能烷氧基硅烷的含量,其中R 1相互独立地为具有1至4个C原子的直链或支链烃部分,R2为甲基 并且x为0或1,A为式(R3)2C = C(R3)-Mk-的单价烯烃基,其中k为0或1,其中基团R3相同或不同,R3为氢原子 或-CH 2 - , - (CH 2)2 - , - (CH 2)3 - 和-C(O)O-(CH 2)3 - ,(iii) 至少一种自由基发生剂的含量和(iv)任选的至少一种其它组分的含量,其中所有组分(i)至(iv)的全部为100重量%。 本发明还涉及一种制备方法,还涉及基于热塑性聚烯烃可得到的成型品或产品,其中本发明的组合物与Monosil方法中的至少一种热塑性聚烯烃一起反应。 本发明还涉及本发明的组合物在Monosil方法中用于在通过基于热塑性聚烯烃的挤出成型的产品生产期间交联热塑性聚烯烃。

    SILANOL CONDENSATION CATALYSTS FOR THE CROSS-LINKING OF FILLED AND UNFILLED POLYMER COMPOUNDS
    8.
    发明申请
    SILANOL CONDENSATION CATALYSTS FOR THE CROSS-LINKING OF FILLED AND UNFILLED POLYMER COMPOUNDS 审中-公开
    用于填充和未充分聚合物化合物交联的硅烷醇缩合催化剂

    公开(公告)号:US20130253144A1

    公开(公告)日:2013-09-26

    申请号:US13903594

    申请日:2013-05-28

    IPC分类号: C08F110/02

    摘要: The invention relates to a composition of an organofunctional silane compound, particularly of a mono-unsaturated silane compound, and of an organic acid or a precursor compound which releases said organic acid, and to a method for the production of polymer compounds such as granulates and/or finished products from thermoplastic base polymers and/or monomers and/or prepolymers of the thermoplastic base polymer utilizing the composition, the organic acid, or the precursor compound which releases said organic acid. The invention also relates to the produced polymers, filled plastics such as, for example, granulates, finished products, molded bodies and/or articles such as pipes or cables. In addition, the invention relates to a kit containing the composition.

    摘要翻译: 本发明涉及有机官能硅烷化合物,特别是单不饱和硅烷化合物的组合物,有机酸或前体化合物的释放所述有机酸的组合物,以及制备高分子化合物如颗粒和 /或使用所述组合物,有机酸或释放所述有机酸的前体化合物的热塑性基础聚合物和/或热塑性基础聚合物的单体和/或预聚物的成品。 本发明还涉及生产的聚合物,填充塑料,例如颗粒,成品,成型体和/或诸如管道或电缆的物品。 此外,本发明涉及含有该组合物的试剂盒。