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1.发明授权Monoethylenically unsaturated compounds whose polymers are useful as photoinitiators 失效聚合物作为光敏剂有用的单一不饱和化合物
公开(公告)号：US5100987A
公开(公告)日：1992-03-31
申请号：US603092
申请日：1990-10-25
IPC分类号： C07C67/00 , C07C69/54 , C07C69/738 , C07C235/74 , C07C235/78 , C07C237/08 , C07C239/00 , C07C271/16 , C07C323/12 , C07C323/22 , C07C323/36 , C07D295/10 , C07D295/108 , C07F9/40 , C07F9/44 , C08F20/00 , C08F20/10 , C08F20/26 , C08F20/30 , C08F20/34 , C08F20/36 , C08F30/02
CPC分类号： C07D295/108 , C07F9/4056 , Y10S430/136 , Y10S522/904 , Y10S522/905
摘要： Monethylenically unsaturated compounds whose polymers are useful as polymeric photoinitiators are of formula Ar.sup.1 COC(R.sup.1)(R.sup.2)R.sup.3 where R.sup.1 is C.sub.1 -C.sub.10 alkyl or alkoxy, R.sup.2 is C.sub.1 -C.sub.10 alkyl, --X--O--R.sup.4 --OCOC(R.sup.5).dbd.CH.sub.2 (II) --X--NH--R.sup.6 --OCOC(R.sup.5).dbd.CH.sub.2 (III), or --CH.sub.2 [OCH.sub.2 CH(OH)CH.sub.2 ].sub.a OCOC(R.sup.5).dbd.CH.sub.2 (IIIA) or R.sup.1 and R.sup.2, together with the attached carbon, denote C.sub.4 -C.sub.8 cycloalkyl, R.sup.3 is a C.sub.6 -C.sub.20 aromatic group, OH, tert.amino, --OCOC(R.sup.5).dbd.CH.sub.2 (VI) or --OCH.sub.2 CH(OH)CH.sub.2 OCOC(R.sup.5).dbd.CH.sub.2 (VIA), R.sup.4 is C.sub.1 -C.sub.4 alkylene, which may be substituted by --OH or by C.sub.2 -C.sub.20 acyloxy, R.sup.5 is H or C.sub.1 -C.sub.4 alkyl, R.sup.6 is C.sub.1 to C.sub.4 alkylene, X is a group of formula R.sup.7 CO-- or ##STR1## where R.sup.7 is C.sub.1 -C.sub.4 alkylene, R.sup.8 is C.sub.1 to C.sub.4 alkyl, and is 0 or 1, Ar.sup.1 is a C.sub.6 -C.sub.20 aromatic group, with the provisos that (i) R.sup.2, R.sup.3 or Ar.sup.1 contains a group (VI), (ii) where R.sup.1 and R.sup.2 together with the attached carbon atom denote cycloalkyl, R.sup.3 is --OH, tert.amino or a group VI or VIA (iii) when R.sup.2 is a group II, a is 0, (iv) when R.sup.2 is a group III a is 1, (v) when R.sup.2 denotes a group IIIA, R.sup.3 denotes said monovalent aromatic group (vi) when R.sup.3 denotes a group VI, R.sup.1 and R.sup.2 together with the attached carbon denote C.sub.4 -C.sub.8 cycloalkyl, (vii) when Ar.sup.1 contains a group VI R.sup.1 is --CH.sub.3 and R.sup.3 is --OH, R.sup.2 is C.sub.2 -C.sub.10 alkyl, and (viii) when Ar.sup.1 contains a group VI, R.sup.1 and R.sup.2 are each alkyl and R.sup.3 is --OH, the group VI is linked to an aromatic C atom in Ar.sup.1 through a group --YR.sup.10 OR.sup.9 -- or --YR.sup.10 OCONHR.sup.6 --, Y being attached to an aromatic C atom, where Y is O or S, R.sup.9 is 2-hydroxypropylene or 2-(C.sub.2 -C.sub.20 acyloxy)propylene and R.sup.10 is C.sub.1 -C.sub.4 alkylene.
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公开(公告)号：US4977293A
公开(公告)日：1990-12-11
申请号：US465513
申请日：1990-01-16
IPC分类号： C07C67/00 , C07C69/54 , C07C69/738 , C07C235/74 , C07C235/78 , C07C237/08 , C07C239/00 , C07C271/16 , C07C323/12 , C07C323/22 , C07C323/36 , C07D295/10 , C07D295/108 , C07F9/40 , C07F9/44 , C08F20/00 , C08F20/10 , C08F20/26 , C08F20/30 , C08F20/34 , C08F20/36 , C08F30/02
CPC分类号： C07D295/108 , C07F9/4056 , Y10S430/136 , Y10S522/904 , Y10S522/905
摘要： Monoethylenically unsaturated compounds whose polymers are useful as polymeric photoinitiators are of formula Ar.sup.1 COC(R.sup.1)(R.sup.2)R.sup.3 where R.sup.1 is (C.sub.1 -C.sub.10 alkyl or alkoxy, R.sup.2 is C.sub.1 -C.sub.10 alkyl, --X--O--R.sup.4 -OCOC(R.sup.5).dbd.CH.sub.2 (II) --X--NH--R.sup.6 --OCOC(R.sup.5).dbd.CH.sub.2 (III), or --CH.sub.2 [OCH.sub.2 CH(OH)CH.sub.2 ].sub.a OCOC(R.sup.5).dbd.CH.sub.2 (IIIA) or R.sup.1 and R.sup.2, together with the attached carbon, denote C.sub.4 -C.sub.8 cycloalkyl, R.sup.3 is a C.sub.6 -C.sub.20 aromatic group, OH tert. amino,--OCOC(R.sup.5).dbd.CH.sub.2 (VI) or --OCH.sub.2 CH(OH)CH.sub.2 OCOC(R.sup.5).dbd.CH.sub.2 (VIA), R.sup.4 is C.sub.1 14 C.sub.4 alkylene, which may be substituted by --OH or by C.sub.2 -C.sub.20 acyloxy, R.sup.5 is H or C.sub.1 -C.sub.4 alkyl, R.sup.6 is C.sub.1 to C.sub.4 alkylene, X is a group of formula R.sup.7 CO-- or ##STR1## where R.sup.7 is C.sub.1 -C.sub.4 alkylene, R.sup.8 is C.sub.1 to C.sub.4 alkyl, and is 0 or 1, Ar.sup.1 is a C.sub.6 -C.sub.20 aromatic group, with the provisos that (i) R.sup.2, R.sup.3 or Ar.sup.1 contains a group (VI), (ii) where R.sup.1 and R.sup.2 together with the attached carbon atom denote cycloalkyl, R.sup.3 is --OH, tert.amino or a group VI or VIA (iii) when R.sup.2 is a group II, a is 0, (iv) when R.sup.2 is a group III a is 1, (v) when R.sup.2 denotes a group IIIA, R.sup.3 denotes said monovalent aromatic group (vi) when R.sup.3 denotes a group VI, R.sup.1 and R.sup.2 together with the attached carbon denote C.sub.4 -C.sub.8 cycloalkyl, (vii) when Ar.sup.1 contains a group VI R.sup.1 is --CH.sub.3 and R.sup.3 is --OH, R.sup.2 is C.sub.2 -C.sub.10 alkyl, and (viii) when Ar.sup.1 contains a group VI, R.sup.1 and R.sup.2 are each alkyl and R.sup.3 is --OH, the group VI is linked to an aromatic C atom in Ar.sup.1 through a group --YR.sup.10 OR.sup.9 -- or --YR.sup.10 OCONHR.sup.6 --, Y being attached to an aromatic C atom, where Y is O or S, R.sup.9 is 2-hydroxypropylene or 2-(C.sub.2 -C.sub.20 acyloxy)-propylene and R.sup.10 is C.sub.1 -C.sub.4 alkylene.
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公开(公告)号：US06855748B1
公开(公告)日：2005-02-15
申请号：US10088564
申请日：2000-09-07
申请人： Kevin B Hatton
发明人： Kevin B Hatton
IPC分类号： C09K3/10 , C08F2/50 , C08G59/20 , C08G65/18 , C08L71/02 , C09D5/00 , C09D163/00 , C09D171/00 , C09J163/00 , C09J171/00 , C08F2/46
摘要： The present invention relates to UV-curable compositions, the process for preparing the compositions and to the use of the curable compositions. The compositions contain: a) at least one oxetane compound; b) at least one polyfunctional cycloaliphatic epoxy compound; c) at least one multifunctional hydroxy compound; and d) at least one curing agent.
摘要翻译： 本发明涉及UV可固化组合物，制备组合物的方法和可固化组合物的用途。 组合物含有：a）至少一种氧杂环丁烷化合物; b）至少一种多官能环脂族环氧化合物; c）至少一种多官能羟基化合物; 和d）至少一种固化剂。
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公开(公告)号：US5451345A
公开(公告)日：1995-09-19
申请号：US129701
申请日：1993-09-30
IPC分类号： B05D3/00 , B05D3/10 , C03C17/28 , C03C17/30 , C03C17/32 , C03C23/00 , C09D4/00 , C09J5/02 , C11D3/16 , C11D3/43 , C11D7/60 , C11D7/22
CPC分类号： C11D3/43 , B05D3/10 , C03C17/28 , C03C17/30 , C03C17/32 , C03C23/0075 , C03C23/008 , C09D4/00 , C09J5/02 , C11D3/162 , C09J2400/146 , C09J2400/166
摘要： A composition for priming and cleaning glass, aluminium or steel surfaces which comprises a solution in an organic solvent, optionally mixed with water, of an organosilane and a compound which generates an acid on exposure to actinic radiation.
摘要翻译： 一种用于起泡和清洁玻璃，铝或钢表面的组合物，其包含有机溶剂中任选与水混合的有机硅烷和在曝光于光化辐射下产生酸的化合物的溶液。
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5.发明授权Process for the preparation of reaction products of cycloaliphatic epoxides with multifunctional hydroxy compounds 失效用多官能羟基化合物制备环脂族环氧化物的反应产物的方法公开(公告)号：US06774250B1
公开(公告)日：2004-08-10
申请号：US10018667
申请日：2002-08-02
IPC分类号： C07D30300
摘要： The invention relates to the process for the preparation of liquid reaction products of cycloaliphatic epoxides with mono- or multifunctional hydroxy compounds. The process comprises reacting a polyfunctional cycloaliphatic epoxy resin with a mono- or multifunctional hydroxy compound in the presence of a heterogeneous surface-active catalyst. The invention also relates to curable compositions containing the product obtained by the process.
摘要翻译： 本发明涉及用单 - 或多官能羟基化合物制备环脂族环氧化物的液体反应产物的方法。 该方法包括在多相表面活性催化剂存在下使多官能环脂族环氧树脂与单官能或多官能羟基化合物反应。 本发明还涉及包含通过该方法获得的产物的可固化组合物。
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公开(公告)号：US07202286B2
公开(公告)日：2007-04-10
申请号：US11054208
申请日：2005-02-08
申请人： Kevin B Hatton
发明人： Kevin B Hatton
摘要： The present invention relates to UV-curable compositions, the process for preparing the compositions and to the use of the curable compositions. The compositions contain: a) at least one oxetane compound; b) at least one polyfunctional cycloaliphatic epoxy compound; c) at least one multifunctional hydroxy compound; and d) at least one curing agent.
摘要翻译： 本发明涉及UV可固化组合物，制备组合物的方法和可固化组合物的用途。 组合物含有：a）至少一种氧杂环丁烷化合物; b）至少一种多官能环脂族环氧化合物; c）至少一种多官能羟基化合物; 和d）至少一种固化剂。
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