摘要:
A composition for priming and cleaning glass, aluminium or steel surfaces which comprises a solution in an organic solvent, optionally mixed with water, of an organosilane and a compound which generates an acid on exposure to actinic radiation.
摘要:
A liquid composition which on exposure to actinic radiation polymerizes to form a heat-curable solid film adhesive, said composition comprising (A) a heat-curable phenol-aldehyde resol resin, (B) a photopolymerizable polyurethane or polyester having, on average, more than one polymerizable acrylic group per molecule, or a mixture of said polyurethane and said polyester, (C) a photopolymerization initiator for (B) and (D) a polyvinylacetal.
摘要:
A liquid composition which on exposure to actinic radiation polymerizes to form a heat-curable solid film adhesive, said composition comprising (A) a heat-curable phenol-aldehyde resol resin, (B) a photopolymerizable polyurethane or polyester having, on average, more than one polymerizable acrylic group per molecule, or a mixture of said polyurethane and said polyester, (C) a photopolymerization initiator for (B) and (D) a polyvinylacetal. The heat-curable solid film adhesive is used for bonding friction materials, such as brake linings, to metal.
摘要:
Curable compositions, especially suitable for use as adhesives, contain(A) an anaerobically polymerizable mixture which is stable in oxygen but polymerizes when oxygen is excluded, comprising(i) a free radical polymerizable compound, such as an acrylate or methacrylate ester,(ii) an organic free radical initiator, such as a peroxide or hydroperoxide, and(iii) an organic accelerator of free radical polymerization(B) an epoxide resin, and(C) a curing agent for epoxide resins that is a basic curing agent, a polymercaptan, or a polyhydric phenol.These compositions cure rapidly by an araerobic curing mechanism and then develop high strength by cure of the epoxide resin.
摘要:
A layer of a liquid composition containing a residue that is polymerizable on contact with a gaseous polymerizing agent and a photocurable residue, which residues may be on the same or different molecules, is contained with a gaseous polymerizing agent so that the layer solidifies but remains photocurable. Subsequently the solidified layer is exposed to actinic radiation in a predetermined pattern and those parts of the layer that are not photocured are removed by treatment with a suitable solvent.Typical polymerizable residues include cyanoacrylates that polymerize on exposure to water vapor, ammonia, or an amine. Typical photocurable residues include acrylates, and methacrylates.The process is suitable for the manufacture of printing plates and printed circuits.
摘要:
A polymerizing agent is applied to a substrate followed by a layer of a liquid composition containing both a polymerizable residue and a photocurable residue. The polymerizable residue is polymerized by the polymerizing agent first applied so that the layer solidifies but remains photocurable. Subsequently this solidified layer is exposed to actinic radiation in a predetermined pattern and those parts of the layer that are not photocured are removed by treatment with a suitable solvent.Typical polymerizable residues include cyanoacrylates, the polymerizing agents for which may be water, ammonium hydroxide solution, an alkali metal hydroxide solution, or an amine. Typical photocurable residues include acrylates and methacrylates.The process is suitable for the manufacture of printing plates and printed circuits.
摘要:
A layer of a liquid composition containing (A) a heat-activated polymerizing agent for 1,2-epoxides, (B) a light-sensitive compound having in the same molecule at least one 1,2-epoxide group of formula ##STR1## and at least one unsaturated ester group of formulaCH.sub.2 .dbd.C(R.sup.1)COO-- IIwhere R.sup.1 =H, Cl, Br, or C.sub.1 -C.sub.4 alkyl, a mixture of (C) a compound containing at least one 1,2-epoxide group of formula I together with (D) a compound containing at least one unsaturated ester group of formula II, or a mixture of (B) with (C) and/or (D), is heated to solidify the layer, and subsequently it is exposed to actinic radiation in a predetermined pattern and those parts of the layer that have not become photopolymerized are removed by treatment with a suitable solvent.An example of a suitable polymerizing agent (A) is the complex of boron trifluoride with monoethylamine. An example of a light-sensitive compound (B) is glycidyl methacrylate. The epoxide compound (C) may be the diglycidyl ether of 2,2-bis(4-hydroxyphenyl)propane, and the unsaturated ester (D) may be 1,4-bis(2-hydroxy-3-acryloyloxypropoxy)butane.
摘要:
A polymerizable composition comprises a mixture of(A) a substance having at least one allyl- or methallyl-substituted bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid imide residue, and(B) a substance having at least one polymerizable residue of formulaCH.sub.2 =C(R.sup.1)COO-- I where R.sup.1 denotes a hydrogen atom or a methyl group.Typically, (A) is bis[4-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboximidophenyl)]methane and (B) is an acrylate or methacrylate of a polyhydric alcohol. The compositions can be photopolymerized or heat-cured. They are suitable for use in prepreg manufacture and in image formation.
摘要:
A layer of a liquid composition containing(A) a heat-activated latent polymerizing agent for 1,2-epoxides with(B) a light-sensitive compound having in the same molecule at least one 1,2-epoxide group and at least one chalcone or cinnamate group, or with a mixture of(C) a compound containing at least one 1,2-epoxide group together with(D) a compound containing at least one chalcone or cinnamate group,is heated so that the layer solidifies due to thermal polymerization through the 1,2-epoxide group, remaining, however, photocrosslinkable. The solidified layer is exposed in a predetermined pattern to actinic radiation, the parts so exposed becoming photocrosslinked through the chalcone or cinnamate unit(s) and hence insoluble. An image is produced which can be developed by means of suitable solvents.An example of a suitable latent polymerizing agent (A) is boron trichloride-N-methylpiperidine complex, and a suitable light-sensitive compound (B) is 1-(p-(glycidyloxy)phenyl)-5-phenylpenta-1,4-dien-3-one.
摘要:
Images are prepared by a process in which a layer, supported on a substrate, of a liquid composition comprising(a) an anaerobically polymerizable material and(b) a photopolymerizable material is maintained in a substantially oxygen-free environment such that the composition solidifies. It is then exposed imagewise to actinic radiation and treated with a developer to remove parts of the layer which have not been struck by the radiation.The anaerobically polymerizable and photopolymerizable materials may be a mixture of two or more materials having these different functions, such as an acrylate ester with an azido compound, or the two functions may be combined in a single molecule. The products are suitable for use in producing printing plates and printed circuits.