Low temperature synthesis of metallic nanoparticles
    1.
    发明授权
    Low temperature synthesis of metallic nanoparticles 失效
    低温合成金属纳米粒子

    公开(公告)号:US07033416B2

    公开(公告)日:2006-04-25

    申请号:US10443228

    申请日:2003-05-22

    IPC分类号: B22F9/24

    摘要: A new low temperature method of reducing metallic salts, both inorganic and organic to metallic nanoparticles has been discovered. The reduction reaction is carried out in low boiling point monoalkylethers of ethylene glycol and mixtures of this solvent with alkane diols. Metallic nanoparticles are produced with size range of 1–100 nm.

    摘要翻译: 已经发现了一种将金属盐还原成无机和有机金属纳米颗粒的新型低温方法。 还原反应在乙二醇的低沸点单烷基醚和该溶剂与烷烃二醇的混合物中进行。 生产尺寸范围为1-100nm的金属纳米粒子。

    Synthesis of nanostructured composite particles using a polyol process
    4.
    发明授权
    Synthesis of nanostructured composite particles using a polyol process 失效
    使用多元醇工艺合成纳米结构复合颗粒

    公开(公告)号:US06436167B1

    公开(公告)日:2002-08-20

    申请号:US08645397

    申请日:1996-05-13

    IPC分类号: B22F100

    摘要: The present invention is a polyol method for making composite particles of two or more immiscible transition metals, where these particles are of nanoscale dimensions, and where the constituent metals are of essentially nanocrystalline morphology. The method of the invention has the steps of (1) dissolving or suspending two or more precursor metal compounds in an alcohol or polyol (diol, triol, etc.) solution, and (2) taking the solution or suspension to a temperature where the metal compound reduces, causing the first and second metals to form nanoscale composites. The term “polyol solution” will be used herein to describe solutions that contain either alcohol or polyol.

    摘要翻译: 本发明是用于制备两种或更多种不混溶的过渡金属的复合颗粒的多元醇方法,其中这些颗粒具有纳米级尺寸,并且组成金属基本上是纳米晶体形态。 本发明的方法具有以下步骤:(1)将两种或更多种前体金属化合物溶解或悬浮在醇或多元醇(二醇,三醇等)溶液中,和(2)将溶液或悬浮液置于 金属化合物减少,导致第一和第二金属形成纳米级复合材料。 本文中将使用术语“多元醇溶液”来描述含有醇或多元醇的溶液。

    Nanosize particle coatings made by thermally spraying solution precursor feedstocks
    6.
    发明授权
    Nanosize particle coatings made by thermally spraying solution precursor feedstocks 失效
    通过热喷涂溶液前体原料制成的纳米颗粒涂层

    公开(公告)号:US06447848B1

    公开(公告)日:2002-09-10

    申请号:US09106456

    申请日:1998-06-30

    IPC分类号: C23C404

    摘要: Thin films or coatings having a thickness of about 100 nanometers or larger are made of nanostructured particles which have a particle size less than 100 nm (i.e. 0.1 micron) by thermally spraying a solution of a liquid coating precursor feedstock onto a substrate to form the film or coating. By thermal spraying with different precursor feedstock solutions, coatings can be made with more than one layer. Also, by varying the composition of the precursor feedstock during spraying, a fine composition gradient coating can be formed which is made up of the same small nanoparticle size particles of less than, 100 nm. Many combinations of materials can be co-deposited and by applying an external energy source either during the coating process or during post deposition, the resulting coating can be modified.

    摘要翻译: 具有约100纳米或更大厚度的薄膜或涂层由具有小于100nm(即0.1微米)的粒度的纳米结构粒子制成,通过将液体涂覆前体原料的溶液热喷涂到基底上以形成膜 或涂层。 通过用不同的前体原料溶液进行热喷涂,涂层可以制成多层。 而且,通过改变喷雾前体原料的组成,可以形成由相同小于100nm的小纳米颗粒尺寸的颗粒组成的精细组成梯度涂层。 可以共同沉积许多材料的组合,并且通过在涂布过程期间或在后沉积期间施加外部能量源,可以改变所得到的涂层。