METASTABLE CERAMIC FUEL CELL AND METHOD OF MAKING SAME
    1.
    发明申请
    METASTABLE CERAMIC FUEL CELL AND METHOD OF MAKING SAME 有权
    易燃陶瓷燃料电池及其制造方法

    公开(公告)号:US20130143144A1

    公开(公告)日:2013-06-06

    申请号:US13679507

    申请日:2012-11-16

    Abstract: A solid oxide fuel cell has anode, cathode and electrolyte layers each formed essentially of a multi-oxide ceramic material and having a far-from-equilibrium, metastable structure selected from the group consisting of nanocrystalline, nanocomposite and amorphous. The electrolyte layer has a matrix of the ceramic material, and is impervious and serves as a fast oxygen ion conductor. The electrolyte layer has a matrix of the ceramic material and a dopant dispersed therein in an amount substantially greater than its equilibrium solubility in the ceramic matrix. The anode layer includes a continuous surface area metallic phase in which electron conduction is provided by the metallic phase and the multi-oxide ceramic matrix provides ionic conduction.

    Abstract translation: 固体氧化物燃料电池具有主要由多氧化物陶瓷材料形成的阳极,阴极和电解质层,并且具有选自纳米晶体,纳米复合材料和非晶态的远离平衡的亚稳结构。 电解质层具有陶瓷材料的基体,并且是不透水的并且用作快速氧离子导体。 电解质层具有陶瓷材料的基质和分散在其中的掺杂剂,其量基本上大于其在陶瓷基质中的平衡溶解度。 阳极层包括由金属相提供电子传导并且多氧化物陶瓷基体提供离子传导的连续表面区域金属相。

    Ultrafine fiber composites and method of making the same
    4.
    发明授权
    Ultrafine fiber composites and method of making the same 失效
    超细纤维复合材料及其制造方法

    公开(公告)号:US5096739A

    公开(公告)日:1992-03-17

    申请号:US441163

    申请日:1989-11-27

    Abstract: A novel method is presented for synthesizing ultrafine fiber composite materials by laser induced coevaporation of a metallic target and a ceramic target in the presence of a heated tungsten filament, within a reducing environment. The species produced by rapid condensation from the resultant laser plume, along with the products derived from the chemical transport reactions involving the heated filament, form layers of composite material comprising a metal matrix and a random weave fiber network. In a preferred embodiment of the present invention, composite layers are formed on a nickel alloy substrate surface at a rate of about 1 micron per second. The matrix of the composite films is either aluminum or tungsten and the dispersed phase is amorphous silica fibers. The diameter of the fibers are between 25 and 120 nm depending on the laser beam materials interaction time.

    Abstract translation: 提出了一种新的方法,用于在还原环境下,在加热的钨丝丝存在下,通过金属靶和陶瓷靶的激光诱导共蒸发来合成超细纤维复合材料。 由所得激光羽毛快速冷凝产生的物种以及由涉及加热的细丝的化学传输反应产生的产物形成包含金属基质和随机编织纤维网络的复合材料层。 在本发明的优选实施例中,复合层以约1微米/秒的速率在镍合金基底表面上形成。 复合膜的基体为铝或钨,分散相为无定形二氧化硅纤维。 根据激光束材料的相互作用时间,纤维的直径在25和120nm之间。

    Metastable ceramic fuel cell and method of making same
    5.
    发明授权
    Metastable ceramic fuel cell and method of making same 有权
    亚稳态陶瓷燃料电池及其制造方法

    公开(公告)号:US09368820B2

    公开(公告)日:2016-06-14

    申请号:US13679507

    申请日:2012-11-16

    Abstract: A solid oxide fuel cell has anode, cathode and electrolyte layers each formed essentially of a multi-oxide ceramic material and having a far-from-equilibrium, metastable structure selected from the group consisting of nanocrystalline, nanocomposite and amorphous. The electrolyte layer has a matrix of the ceramic material, and is impervious and serves as a fast oxygen ion conductor. The electrolyte layer has a matrix of the ceramic material and a dopant dispersed therein in an amount substantially greater than its equilibrium solubility in the ceramic matrix. The anode layer includes a continuous surface area metallic phase in which electron conduction is provided by the metallic phase and the multi-oxide ceramic matrix provides ionic conduction.

    Abstract translation: 固体氧化物燃料电池具有主要由多氧化物陶瓷材料形成的阳极,阴极和电解质层,并且具有选自纳米晶体,纳米复合材料和非晶态的远离平衡的亚稳结构。 电解质层具有陶瓷材料的基体,并且是不透水的并且用作快速氧离子导体。 电解质层具有陶瓷材料的基质和分散在其中的掺杂剂,其量基本上大于其在陶瓷基质中的平衡溶解度。 阳极层包括由金属相提供电子传导并且多氧化物陶瓷基体提供离子传导的连续表面区域金属相。

    Electrode assembly for a solid oxide fuel cell and method for making the same
    6.
    发明授权
    Electrode assembly for a solid oxide fuel cell and method for making the same 有权
    一种固体氧化物燃料电池用电极组件及其制造方法

    公开(公告)号:US08173327B2

    公开(公告)日:2012-05-08

    申请号:US11999775

    申请日:2007-12-07

    Abstract: An electrode assembly for a solid oxide fuel cell, the electrode assembly including a porous ceramic oxide matrix and an array of fluid conduits. The porous ceramic oxide matrix includes a labyrinth of reinforcing walls interconnected to one another. Each of the fluid conduits is formed from the porous ceramic oxide matrix and has an external surface with a plurality of struts projecting outwardly therefrom and an internal surface defining a first passage for flowing a first fluid therethrough. The struts are configured to connect the fluid conduits to one another and the external surfaces and the struts define a second passage around the fluid conduits for flowing a second fluid therethrough.

    Abstract translation: 一种用于固体氧化物燃料电池的电极组件,所述电极组件包括多孔陶瓷氧化物基体和流体导管阵列。 多孔陶瓷氧化物基体包括彼此互连的增强壁的迷宫。 每个流体导管由多孔陶瓷氧化物基体形成并且具有外表面,其具有从其向外突出的多个支柱和限定用于使第一流体流过其中的第一通道的内表面。 支柱构造成将流体导管彼此连接,并且外表面和支柱围绕流体导管限定第二通道,用于使第二流体流过其中。

    Nanosize particle coatings made by thermally spraying solution precursor feedstocks
    9.
    发明授权
    Nanosize particle coatings made by thermally spraying solution precursor feedstocks 失效
    通过热喷涂溶液前体原料制成的纳米颗粒涂层

    公开(公告)号:US06447848B1

    公开(公告)日:2002-09-10

    申请号:US09106456

    申请日:1998-06-30

    CPC classification number: C23C4/134 Y10T428/24942 Y10T428/25

    Abstract: Thin films or coatings having a thickness of about 100 nanometers or larger are made of nanostructured particles which have a particle size less than 100 nm (i.e. 0.1 micron) by thermally spraying a solution of a liquid coating precursor feedstock onto a substrate to form the film or coating. By thermal spraying with different precursor feedstock solutions, coatings can be made with more than one layer. Also, by varying the composition of the precursor feedstock during spraying, a fine composition gradient coating can be formed which is made up of the same small nanoparticle size particles of less than, 100 nm. Many combinations of materials can be co-deposited and by applying an external energy source either during the coating process or during post deposition, the resulting coating can be modified.

    Abstract translation: 具有约100纳米或更大厚度的薄膜或涂层由具有小于100nm(即0.1微米)的粒度的纳米结构粒子制成,通过将液体涂覆前体原料的溶液热喷涂到基底上以形成膜 或涂层。 通过用不同的前体原料溶液进行热喷涂,涂层可以制成多层。 而且,通过改变喷雾前体原料的组成,可以形成由相同小于100nm的小纳米颗粒尺寸的颗粒组成的精细组成梯度涂层。 可以共同沉积许多材料的组合,并且通过在涂布过程期间或在后沉积期间施加外部能量源,可以改变所得到的涂层。

    ELECTRODE ASSEMBLY FOR A SOLID OXIDE FUEL CELL AND METHOD FOR MAKING THE SAME
    10.
    发明申请
    ELECTRODE ASSEMBLY FOR A SOLID OXIDE FUEL CELL AND METHOD FOR MAKING THE SAME 有权
    用于固体氧化物燃料电池的电极组件及其制造方法

    公开(公告)号:US20120225373A1

    公开(公告)日:2012-09-06

    申请号:US13465616

    申请日:2012-05-07

    Abstract: An electrode assembly for a solid oxide fuel cell, the electrode assembly including a porous ceramic oxide matrix and an array of fluid conduits. The porous ceramic oxide matrix includes a labyrinth of reinforcing walls interconnected to one another. Each of the fluid conduits is formed from the porous ceramic oxide matrix and has an external surface with a plurality of struts projecting outwardly therefrom and an internal surface defining a first passage for flowing a first fluid therethrough. The struts are configured to connect the fluid conduits to one another and the external surfaces and the struts define a second passage around the fluid conduits for flowing a second fluid therethrough.

    Abstract translation: 一种用于固体氧化物燃料电池的电极组件,所述电极组件包括多孔陶瓷氧化物基体和流体导管阵列。 多孔陶瓷氧化物基体包括彼此互连的增强壁的迷宫。 每个流体导管由多孔陶瓷氧化物基体形成并且具有外表面,其具有从其向外突出的多个支柱和限定用于使第一流体流过其中的第一通道的内表面。 支柱构造成将流体导管彼此连接,并且外表面和支柱围绕流体导管限定第二通道,用于使第二流体流过其中。

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