公开(公告)号：US07482424B2

公开(公告)日：2009-01-27

申请号：US11664353

申请日：2005-09-16

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C08G4/00

CPC分类号： C08G18/6453

摘要： The invention relates to a method for production of polymeric hydroxylalkyl terminated polysulphides, whereby monomeric hydroxylalkyl terminated polysulphides are reacted with formaldehyde in the presence of an acid catalyst in the form of a solid acid, in particular, an acidic ion exchanger, in which the reaction water and optional added solvent and catalyst are separated off. The products are characterized by a very high uniformity (low polydispersity) and can advantageously be functionalized with subsequent reactions.

摘要翻译： 本发明涉及一种生产聚合羟基烷基封端的多硫化物的方法，其中单体羟基烷基封端的多硫化物在酸催化剂存在下与甲醛反应，形式为固体酸，特别是酸性离子交换剂，其中反应 水和任选的添加溶剂和催化剂被分离出来。 产物的特征在于非常高的均匀性（低分散性），并且可以有利地随后续反应而官能化。

公开(公告)号：US20090236227A1

公开(公告)日：2009-09-24

申请号：US12279517

申请日：2007-02-12

申请人： Boris Kuzmanovic ,  Cornelis Johannes Govardus Van Strien ,  Colin Eric Bartel ,  Michael Zeitler ,  Johanna Christina Speelman

发明人： Boris Kuzmanovic ,  Cornelis Johannes Govardus Van Strien ,  Colin Eric Bartel ,  Michael Zeitler ,  Johanna Christina Speelman

IPC分类号： C25D5/00 ,  C25F3/16

CPC分类号： C25D3/665

摘要： The present invention relates to a method to electroplate or electropolish a metal on a substrate wherein an ionic liquid selected from the group of N+R1R2R3R4X− or N+R5R6R7R8Y− is employed as electrolyte, and a metal salt added to the ionic liquid is employed as the metal source or a metal anode is used as the metal source, wherein any one of R1 to R8 independently represents a hydrogen, alkyl, cycloalkyl, aryl, or aralkyl group that may be substituted with a group selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, COOR9, CHO, COR9, or OR9, at least one of R5 to R8 is a fatty alkyl chain, and one or more of R5 to R8 can be a (poly)oxyalkylene group wherein the alkylene is a C1 to C4 alkylene and the total number of oxyalkylene units can be from 1 to 50 oxyalkylene units, and at least one of R1 to R8 is a C1 to C4 alkyl chain, R9 is an alkyl or cycloalkyl group, X- is an anion having an N-acyl sulphonylimide anion (—CO—N−—SO2—) functionality, Y− is an anion compatible with the N+R5R6R7R8 ammonium cation, such as a halogenide anion, a carboxylate anion, a sulphate (both organic and inorganic sulphate), sulphonate, carbonate, nitrate, nitrite, thiocyanate, hydroxide, or sulphonylimide anion.

摘要翻译： 本发明涉及一种在基板上电镀或电解金属的方法，其中使用选自N + R1R2R3R4X-或N + R5R6R7R8Y-的离子液体作为电解质，并且使用添加到离子液体中的金属盐 由于金属源或金属阳极用作金属源，其中R 1至R 8中的任一个独立地表示可以被选自OH，Cl，Br的基团取代的氢，烷基，环烷基，芳基或芳烷基 ，F，I，苯基，NH2，CN，NO2，COOR9，CHO，COR9或OR9，R5至R8中的至少一个为脂肪烷基链，R5至R8中的一个或多个可为（聚）氧化烯 基团，其中亚烷基是C1-C4亚烷基，氧化烯单元的总数可以是1至50个氧化烯单元，并且R 1至R 8中的至少一个是C 1至C 4烷基链，R 9是烷基或环烷基， X-是具有N-酰基磺酰亚胺阴离子（-CO-N-SO 2 - ）官能团的阴离子，Y-是与N + R5R相容的阴离子 6R7R8铵阳离子，如卤化物阴离子，羧酸根阴离子，硫酸盐（有机和无机硫酸盐），磺酸盐，碳酸盐，硝酸盐，亚硝酸盐，硫氰酸盐，氢氧化物或磺酰亚胺阴离子。

公开(公告)号：US07061940B2

公开(公告)日：2006-06-13

申请号：US09855897

申请日：2001-05-15

申请人： Martin Kiesel ,  Guido Seeger ,  Dietmar Wanner ,  Michael Zeitler

发明人： Martin Kiesel ,  Guido Seeger ,  Dietmar Wanner ,  Michael Zeitler

IPC分类号： H04J3/06 ,  H04L7/06

CPC分类号： H04J3/0652 ,  H03L7/0807 ,  H03L7/085 ,  H04L7/0008 ,  H04L7/033 ,  H04L7/08

摘要： Synchronization of a bus master to a bus slave permits the desired hierarchical structuring of buses by virtue of a bus slave on a bus receiving the synchronization information for an associated bus master is disclosed. A phase locked loop is used to filter this clock information and to regenerate missing clock pulses. This clock which is now “sound,” is supplied to one or more parallel bus masters of other buses, which generate the corresponding clock information using the necessary messages on the respective bus. This principle is independent of the respective bus system, which means that a plurality of identical buses or else different bus systems can be operated hierarchically in synchronization with one another.

摘要翻译： 总线主机与总线从站的同步允许通过接收相关总线主机的同步信息的总线上的总线从站来实现总线的所需层次结构化。 使用锁相环来过滤该时钟信息并重新生成丢失的时钟脉冲。 现在这个“声音”的时钟被提供给其他总线的一个或多个并行总线主机，其使用相应总线上的必要消息产生相应的时钟信息。 该原理独立于相应的总线系统，这意味着多个相同的总线或者不同的总线系统可以彼此同步地分层操作。

公开(公告)号：US07423183B2

公开(公告)日：2008-09-09

申请号：US10558162

申请日：2004-03-31

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C07C319/00 ,  C07C321/00 ,  C07C323/00 ,  C07C381/00

CPC分类号： B01J31/0237 ,  B01J27/24 ,  B01J31/04 ,  B01J31/28 ,  B01J31/32 ,  B01J2231/70 ,  C07C319/24 ,  C07C323/12

摘要： A process for preparing dihydroxyethylene disulfide by reacting mercaptoethanol with oxygen, in which mercaptoethanol is reacted with oxygen or an oxygenous gas in the presence of ammonia and/or amines using copper salts or manganese salts.

摘要翻译： 巯基乙醇与氧反应制备二羟基亚乙基二硫化物的方法，其中巯基乙醇在氨和/或胺的存在下与氧或氧气反应，使用铜盐或锰盐。

公开(公告)号：US20070249860A1

公开(公告)日：2007-10-25

申请号：US11664353

申请日：2005-09-16

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C07C321/14

CPC分类号： C08G18/6453

摘要： The invention relates to a method for production of polymeric hydroxylalkyl terminated polysulphides, whereby monomeric hydroxylalkyl terminated polysulphides are reacted with formaldehyde in the presence of an acid catalyst in the form of a solid acid, in particular, an acidic ion exchanger, in which the reaction water and optional added solvent and catalyst are separated off. The products are characterized by a very high uniformity (low polydispersity) and can advantageously be functionalized with subsequent reactions.

摘要翻译： 本发明涉及一种生产聚合羟基烷基封端的多硫化物的方法，其中单体羟基烷基封端的多硫化物在酸催化剂存在下与甲醛反应，其形式为固体酸，特别是酸性离子交换剂，其中反应 水和任选的添加溶剂和催化剂被分离出来。 产物的特征在于非常高的均匀性（低分散性），并且可以有利地随后续反应而官能化。

公开(公告)号：US20050131207A1

公开(公告)日：2005-06-16

申请号：US10507418

申请日：2003-03-08

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C08G59/02 ,  C08L81/04 ,  C08F8/08

CPC分类号： C08G59/02 ,  C08G2650/02 ,  C08L81/04

摘要： Disclosed is a method for producing polymeric polysulfides containing terminal epoxy groups, according to which polysulfides containing terminal thiol groups are reacted with an excess of epichlorohydrin and alkaline lye, water is azeotropically distilled away with epichlorohydrin, the epichlorohydrin-containing epoxidized polysulfide solution is separated from the eliminated salt, the epichlorohydrin is distilled away, and the residue is optionally purified by means of thin film distillation. The reaction product is particularly suitable for the production of high-quality sealants, adhesives, and coatings. Said product has a high degree of purity and an extremely low chlorine content. The inventive method does not require any additional organic solvents and is very environmentally friendly.

摘要翻译： 公开了一种含有末端环氧基的聚合多硫化物的方法，根据该方法，含有末端巯基的多硫化物与过量的表氯醇和碱性碱液反应，将水与表氯醇共沸蒸馏掉，将含表氯醇的环氧化多硫化物溶液与 除去的盐，表氯醇被蒸馏除去，并且残余物任选地通过薄膜蒸馏进行纯化。 反应产物特别适用于生产高质量的密封剂，粘合剂和涂料。 所述产品具有高纯度和极低的氯含量。 本发明的方法不需要任何额外的有机溶剂，并且是非常环境友好的。

公开(公告)号：US08361300B2

公开(公告)日：2013-01-29

申请号：US12279517

申请日：2007-02-12

申请人： Boris Kuzmanovic ,  Cornelis Johannes Govardus Van Strien ,  Colin Eric Bartel ,  Michael Zeitler ,  Johanna Christina Speelman

发明人： Boris Kuzmanovic ,  Cornelis Johannes Govardus Van Strien ,  Colin Eric Bartel ,  Michael Zeitler ,  Johanna Christina Speelman

IPC分类号： C25D3/00

CPC分类号： C25D3/665

摘要： The present invention relates to a method to electroplate or electropolish a metal on a substrate wherein an ionic liquid is selected from the group of N+R1R2R3R4 X− or N+R5R6R7R8 Y− is employed as electrolyte, and a metal salt added to the ionic liquid is employed as the metal source or a metal anode is used as the metal source, wherein any one of R1 to R8 independently represents a hydrogen, alkyl, cycloalkyl, aryl, or aralkyl group that may be substituted with a group selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, COOR9, CHO, COR9, or OR9, at least one of R5 to R8 is a fatty alkyl chain, and one or more of R5 to R8 can be a (poly)oxyalkylene group wherein the alkylene is a C1 to C4 alkylene and the total number of oxyalkylene units can be from 1 to 50 oxyalkylene units, and at least one of R1 to R8 is a C1 to C4 alkyl chain, R9 is an alkyl or cycloalkyl group, X− is an anion having an N-acyl sulphonylimide anion (—CO—N−—SO2—) functionality, Y− is an anion compatible with the N+R5R6R7R8 ammonium cation, such as a halogenide anion, a carboxylate anion, a sulphate (both organic and inorganic sulphate), sulphonate, carbonate, nitrate, nitrite, thiocyanate, hydroxide, or sulphonylimide anion.

摘要翻译： 本发明涉及一种在基板上电镀或电解金属的方法，其中离子液体选自N + R1R2R3R4X-或N + R5R6R7R8Y-的组，用作电解质，并将金属盐加入到离子 使用液体作为金属源或使用金属阳极作为金属源，其中R 1至R 8中的任何一个独立地表示可以被选自下列基团的氢，烷基，环烷基，芳基或芳烷基取代：OH， Cl，Br，F，I，苯基，NH2，CN，NO2，COOR9，CHO，COR9或OR9，R5至R8中的至少一个为脂肪烷基链，R5至R8中的一个或多个可为（ 聚）氧化烯基，其中亚烷基是C1-C4亚烷基，氧化烯单元的总数可以是1至50个氧化烯单元，并且R 1至R 8中的至少一个是C 1至C 4烷基链，R 9是烷基或 环烷基，X-是具有N-酰基磺酰亚胺阴离子（-CO-N-SO 2 - ）官能团的阴离子，Y-是阴离子 与N + R5R6R7R8铵阳离子如卤化物阴离子，羧酸根阴离子，硫酸盐（有机和无机硫酸盐），磺酸盐，碳酸盐，硝酸盐，亚硝酸盐，硫氰酸盐，氢氧化物或磺酰亚胺阴离子相容。

公开(公告)号：US20060287466A1

公开(公告)日：2006-12-21

申请号：US10555726

申请日：2004-05-03

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C08G59/66

CPC分类号： C08L63/00 ,  C08L81/04 ,  C08L81/00 ,  C08L2666/22

摘要： A method for the production of prepolymers by reaction of polysulphides with polyepoxides is disclosed, whereby polyepoxides are reacted with polysulphides, having at least two mercapto groups, in the presence of quaternary ammonium compounds as catalyst. The method permits a rapid quantitative reaction and gives uniform products with regard to functionality and the proportion of functional groups per weight unit. The products thus produced have stable, may be stored, may be cured in a very reproducible manner, or may be processed to give products with a defined property profile.

摘要翻译： 公开了通过多硫化物与聚环氧化物的反应生产预聚物的方法，由此在季铵化合物作为催化剂的存在下，聚环氧化物与具有至少两个巯基的多硫化物反应。 该方法允许快速定量反应，并且在功能性和每重量单位的官能团的比例方面给出均匀的产物。 由此生产的产品具有稳定性，可以储存，可以以非常可重复的方式固化，或者可以加工以产生具有限定性质的产品。

公开(公告)号：US20060142616A1

公开(公告)日：2006-06-29

申请号：US10558162

申请日：2004-03-31

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C07C319/00

CPC分类号： B01J31/0237 ,  B01J27/24 ,  B01J31/04 ,  B01J31/28 ,  B01J31/32 ,  B01J2231/70 ,  C07C319/24 ,  C07C323/12

摘要： A process for preparing dihydroxyethylene disulfide by reacting mercaptoethanol with oxygen, in which mercaptoethanol is reacted with oxygen or an oxygenous gas in the presence of ammonia and/or amines using copper salts or manganese salts.

摘要翻译： 巯基乙醇与氧反应制备二羟基亚乙基二硫化物的方法，其中巯基乙醇在氨和/或胺的存在下与氧或氧气反应，使用铜盐或锰盐。

公开(公告)号：US20050119449A1

公开(公告)日：2005-06-02

申请号：US10513896

申请日：2003-05-22

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C08G75/14 ,  C08F8/08 ,  C08G59/30 ,  C08G75/04

CPC分类号： C08G75/14 ,  C08G59/302

摘要： The invention relates to a method for producing polymer polysulfides comprising epoxy end groups, by reacting polysulfides comprising thiol end groups with epichlorohydrine in the presence of aqueous alkali lye. According to the invention, the polysulfide comprising thiol end groups is optionally dosed with aqueous soda lye into a recipient containing epichlorohydrine and optionally aqueous alkali lye, and the reaction mixture is finished. The inventive method is carried out in one step and has considerable advantages in terms of process technique. It especially enables savings to be made in terms of measuring and regulating techniques and enables energy to be saved. Furthermore, it is essentially risk-free and very environmentally friendly, and therefore enables pure products to be produced.

摘要翻译： 本发明涉及通过在碱性碱水溶液的存在下使包含硫醇端基的多硫化物与表氯醇反应制备包含环氧端基的聚合物多硫化物的方法。 根据本发明，包含硫醇端基的多硫化物任选地将含水苏打碱液加入到含有表氯醇和任选的碱性碱水溶液的接收器中，并且反应混合物完成。 本发明的方法在一个步骤中进行，并且在加工技术方面具有相当大的优点。 它特别能够在测量和调节技术方面节省成本，并能够节省能源。 此外，它基本上是无风险且非常环保的，因此可以生产纯产品。