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    OPTIMIZED SEPARATION TECHNIQUE FOR WORK-UP OF HOMOGENEOUSLY CATALYSED HYDROFORMYLATION MIXTURES
    4.
    发明申请
    OPTIMIZED SEPARATION TECHNIQUE FOR WORK-UP OF HOMOGENEOUSLY CATALYSED HYDROFORMYLATION MIXTURES 有权
    用于均相催化水解混合物的优化分离技术

    公开(公告)号：US20160002136A1

    公开(公告)日：2016-01-07

    申请号：US14770525

    申请日：2014-02-13

    申请人： Hans-Gerd LUEKEN ,  Bart HAMERS ,  Dirk FRIDAG ,  Robert FRANKE ,  Markus PRISKE ,  Dieter HESS ,  Marc BECKER ,  Markus RUDEK

    发明人： Hans-Gerd LUEKEN ,  Bart HAMERS ,  Dirk FRIDAG ,  Robert FRANKE ,  Markus PRISKE ,  Dieter HESS ,  Marc BECKER ,  Markus RUDEK

    IPC分类号： C07C45/78 ,  C07C29/16 ,  C07C45/81 ,  B01J19/00 ,  C07C45/50

    CPC分类号： C07C45/786 ,  B01D61/02 ,  B01D2311/25 ,  B01D2317/025 ,  B01D2325/30 ,  B01D2325/38 ,  B01J19/00 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/822 ,  C07C29/16 ,  C07C45/50 ,  C07C45/81 ,  C07C45/82 ,  C07C31/02 ,  C07C31/125 ,  C07C47/02

    摘要： The invention relates to a method for producing alcohols by homogeneously catalysed hydroformylation of olefins to aldehydes and subsequent hydration of the aldehydes. The invention further relates to a system for carrying out the method. The main focus is on the separation technique for work-up of the hydroformylation mixture. The problem addressed by the invention is that specifying a work-up method for hydroformylation mixtures that utilises the specific advantages of known separation technologies but at the same time largely avoids the specific disadvantages of said separation technologies. The most important objective is to create a catalyst separation system that is as complete and at the same time conservative as possible and that operates in a technically reliable manner and entails low investment and operating costs. The method should be unrestrictedly suitable for processing the reaction output from oxo systems in “world scale” format. The problem is solved by combining membrane separation units and a thermal separation unit, the thermal separation unit being operated in such a manner that 80% to 98% of the mass introduced with the product stream into the thermal separation unit exits the thermal separation unit again as a head product.

    摘要翻译： 本发明涉及通过将烯烃均匀催化加氢甲酰化成醛并随后醛的水合生产醇的方法。 本发明还涉及一种用于执行该方法的系统。 主要关注加氢甲酰化混合物后处理的分离技术。 本发明解决的问题是指定利用已知分离技术的具体优点但同时大大地避免了所述分离技术的具体缺点的加氢甲酰化混合物的后处理方法。 最重要的目标是创建一个尽可能完整且同时保守的催化剂分离系统，并以技术上可靠的方式运行，并且需要低投资和运营成本。 该方法不受限制地适用于以“世界规模”格式处理氧代系统的反应输出。 通过组合膜分离单元和热分离单元来解决问题，热分离单元以使得进入热分离单元的产物流引入的质量的80％至98％再次离开热分离单元的方式操作 作为头饰产品。

    JET LOOP REACTOR HAVING NANOFILTRATION
    5.
    发明申请
    JET LOOP REACTOR HAVING NANOFILTRATION 有权
    具有纳米光泽的喷射反应器

    公开(公告)号：US20140343327A1

    公开(公告)日：2014-11-20

    申请号：US14343917

    申请日：2012-09-07

    申请人： Bart Hamers ,  Dirk Fridag ,  Robert Franke ,  Marc Becker ,  Markus Priske

    发明人： Bart Hamers ,  Dirk Fridag ,  Robert Franke ,  Marc Becker ,  Markus Priske

    IPC分类号： B01J8/00 ,  C07C45/50

    CPC分类号： B01J8/0065 ,  B01J4/002 ,  B01J19/2435 ,  B01J19/2445 ,  B01J19/2475 ,  B01J2219/24 ,  C07C45/50 ,  C07C45/505 ,  C07C47/02

    摘要： The invention relates to a device for the continuous, homogeneous-catalysis reaction of a liquid with a gas and optionally an additional fluid, wherein the device comprises at least one reactor having an external liquid circulation driven by a pump, and wherein the device has at least one membrane separation stage that preferably holds back the homogeneous catalyst. The aim of the invention is to specify a device that allows homogeneous-catalysis gas/liquid phase reactions, in particular hydroformylations, which operate with membrane separation of the catalyst to be performed economically at an industrially relevant scale. Said aim is achieved in that a jet loop reactor is provided as the reactor, and that the pump and the membrane separation stage are arranged in the same external liquid circuit.

    摘要翻译： 本发明涉及一种用于液体与气体和任选的附加流体的连续，均相催化反应的装置，其中该装置包括至少一个具有由泵驱动的外部液体循环的反应器，并且其中该装置具有 至少一个膜分离阶段优选阻止均相催化剂。 本发明的目的是指定允许均相催化气/液相反应，特别是加氢甲酰化反应的装置，其通过膜分离催化剂在工业上相关规模下经济地进行操作。 所述目的是通过提供作为反应器的喷射回路反应器，并且将泵和膜分离级设置在相同的外部液体回路中。

    TWO-STAGE HYDROFORMYLATION PROCESS WITH CIRCULATING GAS AND SILP TECHNOLOGY
    9.
    发明申请
    TWO-STAGE HYDROFORMYLATION PROCESS WITH CIRCULATING GAS AND SILP TECHNOLOGY 有权
    具有循环气和硅胶技术的两级氢化方法

    公开(公告)号：US20160304426A1

    公开(公告)日：2016-10-20

    申请号：US15103842

    申请日：2014-12-10

    申请人： Marc Becker ,  Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Hanna Hahn ,  Marina Lazar ,  Markus Priske ,  Guido Stochniol

    发明人： Marc Becker ,  Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Hanna Hahn ,  Marina Lazar ,  Markus Priske ,  Guido Stochniol

    IPC分类号： C07C45/50 ,  C07C45/79 ,  B01D61/36 ,  B01J31/18 ,  B01J31/02 ,  B01D5/00 ,  C07C45/82 ,  B01J31/24

    CPC分类号： C07C45/50 ,  B01D5/006 ,  B01D5/0072 ,  B01D61/362 ,  B01D61/38 ,  B01D2311/02 ,  B01D2311/04 ,  B01D2311/06 ,  B01D2311/263 ,  B01D2311/2669 ,  B01D2311/2673 ,  B01J31/0292 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/786 ,  C07C45/79 ,  C07C45/82 ,  C07C47/02

    摘要： The invention relates to processes for preparing aldehydes by hydroformylation of alkenes, in which an alkene-containing feed mixture is subjected to a primary hydroformylation with synthesis gas in the presence of a homogeneous catalyst system, the primary hydroformylation being effected in a primary reaction zone from which a cycle gas containing at least some of the products and unconverted reactants of the primary hydroformylation are drawn off continuously and partly condensed, with recycling of uncondensed components of the cycle gas into the primary reaction zone, and with distillative separation of condensed components of the cycle gas in an aldehyde removal stage to give an aldehyde-rich mixture and a low-aldehyde mixture. The problem that it addresses is that of developing the process such that it achieves high conversions and affords aldehyde in good product quality even in the case of a deteriorating raw material position. More particularly, a solution is to be found for making legacy oxo process plants capable of utilizing lower-value raw material sources. This problem is solved by separating the low-aldehyde mixture into a retentate and a permeate by means of a membrane separation unit in such a way that alkenes present in the low-aldehyde mixture become enriched in the permeate, while alkanes present in the low-aldehyde mixture become enriched in the retentate. The alkene-rich permeate is then transferred into a secondary reaction zone and subjected to a secondary hydroformylation therein with synthesis gas in the presence of an SILP catalyst system. The reaction product obtained from the secondary hydroformylation is recycled into the aldehyde removal stage.

    摘要翻译： 本发明涉及通过烯烃的加氢甲酰化制备醛的方法，其中含烯烃的进料混合物在均相催化剂体系的存在下用合成气进行初级加氢甲酰化，初级加氢甲酰化在主反应区 其中包含至少一些产物的循环气体和初级加氢甲酰基化的未转化的反应物被连续地和部分地冷凝，循环气体的未冷凝的组分循环进入初级反应区，并且通过蒸馏分离 在醛去除阶段中循环气体，得到富含醛的混合物和低醛混合物。 它所解决的问题是开发该方法，即使在原料位置恶化的情况下，其达到高转化率并提供良好的产品质量的醛。 更具体地说，可以找到一种解决方案，用于制造能够利用较低价值的原材料来源的传统氧化工艺装置。 通过将低醛混合物通过膜分离单元将低醛混合物分离成滞留物和渗透物来解决，使得存在于低醛混合物中的烯烃变得富集在渗透物中， 醛混合物在保留物中变得富集。 然后将富含烯烃的渗透物转移到第二反应区中，并在有SILP催化剂体系的情况下用合成气对其进行二次加氢甲酰化。 从二次加氢甲酰化得到的反应产物再循环到醛去除阶段。

    JET LOOP REACTOR HAVING NANOFILTRATION
    10.
    发明申请
    JET LOOP REACTOR HAVING NANOFILTRATION 审中-公开
    具有纳米光泽的喷射反应器

    公开(公告)号：US20150336078A1

    公开(公告)日：2015-11-26

    申请号：US14810807

    申请日：2015-07-28

    申请人： Bart HAMERS ,  Dirk FRIDAG ,  Robert FRANKE ,  Marc BECKER ,  Markus PRISKE

    发明人： Bart HAMERS ,  Dirk FRIDAG ,  Robert FRANKE ,  Marc BECKER ,  Markus PRISKE

    IPC分类号： B01J19/24

    CPC分类号： B01J8/0065 ,  B01J4/002 ,  B01J19/2435 ,  B01J19/2445 ,  B01J19/2475 ,  B01J2219/24 ,  C07C45/50 ,  C07C45/505 ,  C07C47/02

    摘要： The invention relates to a device for the continuous, homogeneous-catalysis reaction of a liquid with a gas and optionally an additional fluid, wherein the device comprises at least one reactor having an external liquid circulation driven by a pump, and wherein the device has at least one membrane separation stage that preferably holds back the homogeneous catalyst. The aim of the invention is to specify a device that allows homogeneous-catalysis gas/liquid phase reactions, in particular hydroformylations, which operate with membrane separation of the catalyst to be performed economically at an industrially relevant scale. Said aim is achieved in that a jet loop reactor is provided as the reactor, and that the pump and the membrane separation stage are arranged in the same external liquid circuit.

    摘要翻译： 本发明涉及一种用于液体与气体和任选的附加流体的连续，均相催化反应的装置，其中该装置包括至少一个具有由泵驱动的外部液体循环的反应器，并且其中该装置具有 至少一个膜分离阶段优选阻止均相催化剂。 本发明的目的是指定允许均相催化气/液相反应，特别是加氢甲酰化反应的装置，其通过膜分离催化剂在工业上相关规模下经济地进行操作。 所述目的是通过提供作为反应器的喷射回路反应器，并且将泵和膜分离级设置在相同的外部液体回路中。