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公开(公告)号:US20160340293A1
公开(公告)日:2016-11-24
申请号:US15104822
申请日:2014-12-19
申请人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS , Nourdin GHALIT , SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V.
发明人: Mansour I. TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS , Nourdin GHALIT
IPC分类号: C07C233/69 , C07C235/48 , C08F110/06 , C07C233/18
CPC分类号: C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要: A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R1, R2, R3, R4, R5 and R6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.
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公开(公告)号:US10106632B2
公开(公告)日:2018-10-23
申请号:US15406124
申请日:2017-01-13
申请人: Mansour Taftaf , Jaiprakash Brijlal Sainani , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Vimalkumar Mahendrabhai Patel , Sergei Andreevich Sergeev , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts
发明人: Mansour Taftaf , Jaiprakash Brijlal Sainani , Vladimir Aleksandrovich Zakharov , Gennadii Dimitrievich Bukatov , Vimalkumar Mahendrabhai Patel , Sergei Andreevich Sergeev , Martin Alexander Zuideveld , Aurora Alexandra Batinas-Geurts
IPC分类号: C08F4/649 , C08F4/654 , C08F4/656 , C08F10/06 , C08F110/06 , C07C233/23 , C07C233/18 , C08F4/655 , C07C233/69
摘要: The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R9zMgX2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to given a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR10)v-w(OR11)w, wherein M can be Ti, Zr, Hf, Al or Si, and M(OR10)v-w(R11)w, wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.
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公开(公告)号:US20170129974A1
公开(公告)日:2017-05-11
申请号:US15406124
申请日:2017-01-13
申请人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander Zuideveld , Aurora Alexandra BATINAS-GEURTS
发明人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander Zuideveld , Aurora Alexandra BATINAS-GEURTS
IPC分类号: C08F110/06
CPC分类号: C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要: The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R9zMgXz2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloky-containing silane compound pound to given first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR10)v-w(OR11)w, wherein M can be Ti, Zr, HI, Al or Si, and M(OR10)v-w(R11)w, wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.
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