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    Suppression of ammonia odors from animal wastes
    1.
    发明授权
    Suppression of ammonia odors from animal wastes 失效
    从动物废物中抑制氨气味

    公开(公告)号：US5054434A

    公开(公告)日：1991-10-08

    申请号：US413135

    申请日：1989-09-27

    申请人： Michael J. Wax ,  Timothy A. Boyer

    发明人： Michael J. Wax ,  Timothy A. Boyer

    IPC分类号： A01K1/015

    CPC分类号： A01K1/0152

    摘要： The accumulation of gaseous ammonia in areas wherein animals are housed or maintained is controlled by providing to the areas animal litter, bedding, or other absorbent material which contain a low molecular weight, non-volatile organic acid. Acids such as citric, malic, fumaric, phosphoric, tartaric, maleic, malonic, succinic, sorbic and mixtures of these acids are used and especially phosphoric and fumaric. These acids can be used in concentrations of about 0.0001 to 2 wt % of the dry bedding.

    摘要翻译： 通过向动物垃圾，床上用品或含有低分子量的非挥发性有机酸的其它吸收材料的区域提供气体氨的积聚，其中饲养或维持动物的区域中。 使用酸，例如柠檬酸，苹果酸，富马酸，磷酸，酒石酸，马来酸，丙二酸，琥珀酸，山梨酸和这些酸的混合物，特别是磷酸和富马酸。 这些酸的使用浓度可以为干重层的约0.0001〜2重量％。

    Inorganic supports for bioremediation
    2.
    发明授权
    Inorganic supports for bioremediation 失效
    用于生物修复的无机支架

    公开(公告)号：US5395808A

    公开(公告)日：1995-03-07

    申请号：US994222

    申请日：1992-12-21

    申请人： James G. Miller ,  Michael J. Wax ,  Richard F. Wormsbecher

    发明人： James G. Miller ,  Michael J. Wax ,  Richard F. Wormsbecher

    IPC分类号： B01J35/10 ,  B01J37/00 ,  C02F3/10 ,  B01J21/16 ,  C12Q1/00

    CPC分类号： C02F3/10 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/0018 ,  Y02W10/15

    摘要： Porous bodies are produced which are suitable for use as supports for catalysts, including living cells, such as bacteria. The bodies have a significantly large average pore diameter of about 0.5 to 100 microns, (i.e. 5,000 to 1,000,000 .ANG.) and a total pore volume of about 0.1 to 1.5 cc/g with the large pores contributing a pore volume of from about 0.1 to 1.0 cc/g. The bodies are made by preparing a mixture of ultimate particles of bound clay, one or more optional ingredients such as inorganic binders, extrusion or forming aids, burnout agents, or a forming liquid, such as water. In a preferred embodiment, the ultimate particles are formed by spray drying.

    摘要翻译： 生产适合用作催化剂载体的多孔体，包括活细胞如细菌。 这些主体具有大约0.5至100微米（即5,000至1,000,000安格姆）的显着较大的平均孔径和约0.1至1.5cc / g的总孔体积，其中大孔有助于孔体积为约0.1至1.0 cc / g。 主体通过制备粘结粘土的最终颗粒，一种或多种任选成分如无机粘合剂，挤出或成型助剂，燃烧剂或成形液体如水的混合物制成。 在优选的实施方案中，通过喷雾干燥形成最终颗粒。

    Hydridomethyl iridium complex
    4.
    发明授权
    Hydridomethyl iridium complex 失效
    氢化甲基铱络合物

    公开(公告)号：US4849534A

    公开(公告)日：1989-07-18

    申请号：US703641

    申请日：1985-02-21

    申请人： Robert G. Bergman ,  J. Michael Buchanan ,  Jeffrey M. Stryker ,  Michael J. Wax

    发明人： Robert G. Bergman ,  J. Michael Buchanan ,  Jeffrey M. Stryker ,  Michael J. Wax

    IPC分类号： C07F15/00

    CPC分类号： C07F15/0033

    摘要： A process for functionalizing methane comprising:(a) reacting methane with a hydridoalkyl metal complex of the formula:CpIr[P(R.sub.1).sub.3 ]H(R.sub.2)wherein Cp represents a cyclopentadienyl or alkylcyclopentadienyl radical having from 1 to 5 carbon atoms;Ir represents an iridium atom;P represents a phosphorus atom;R.sub.1 represents an alkyl group;R.sub.2 represents an alkyl group having at least two carbon atoms; andH represents a hydrogen atom, in the presence of a liquid alkane R.sub.3 H having at least three carbon atoms to form a hydridomethyl complex of the formula:CpIr[P(R.sub.1).sub.3 ]HMewhere Me represents a methyl radical.(b) reacting said hydridomethyl complex with an organic halogenating agent such as a tetrahalomethane or a haloform of the formulas:CX'X"X'"X"" or CHX'X"X'";wherein X', X", X"', and X"" represent halogens selected from bromine, iodine and chlorine, to halomethyl complex of step (a) having the formula:CpIr[P(R.sub.1).sub.3 ]MeX:(c) reacting said halomethyl complex with a mercuric halide of the formula HgX.sub.2 to form a methyl mercuric halide of the formula HgMeX; and(d) reacting said methyl mercuric halide with a molecular halogen of the formula X.sub.2 to form methyl halide.

    摘要翻译： 一种使甲烷官能化的方法，包括：（a）使甲烷与下式的氢化烷基金属络合物反应：CpIr [P（R1）3] H（R2）其中Cp代表具有1至5个碳原子的环戊二烯基或烷基环戊二烯基; Ir表示铱原子; P表示磷原子; R1表示烷基; R2表示具有至少两个碳原子的烷基; 在具有至少三个碳原子的液态烷烃R3H的存在下，H代表氢原子，以形成式：CpIr [P（R1）3] HMe的氢化甲基络合物，其中Me代表甲基。 （b）使所述氢化甲基配合物与有机卤化剂如四卤甲烷或下式的卤代甲基反应：CX'X''X“'X”'或CHX'X“X”'; 其中X'，X“，X”“和X”表示选自溴，碘和氯的卤素，具有下式的步骤（a）的卤代甲基络合物：CpIr [P（R1）3] MeX （c）使所述卤代甲基络合物与式HgX 2的卤化汞反应，形成式为HgMeX的甲基汞卤化物; 和（d）使所述甲基汞卤化物与式X2的分子卤素反应以形成甲基卤化物。

    Composite inorganic supports containing carbon for bioremediation
    6.
    发明授权
    Composite inorganic supports containing carbon for bioremediation 失效
    含碳的复合无机载体用于生物修复

    公开(公告)号：US5403809A

    公开(公告)日：1995-04-04

    申请号：US993745

    申请日：1992-12-21

    申请人： James G. Miller ,  Michael J. Wax ,  Alan B. Chmurny ,  Donald R. Durham

    发明人： James G. Miller ,  Michael J. Wax ,  Alan B. Chmurny ,  Donald R. Durham

    IPC分类号： B01J21/18 ,  B01J37/00 ,  C02F3/10 ,  C02F3/34 ,  B01J20/20

    CPC分类号： C02F3/10 ,  B01J21/18 ,  B01J37/0009 ,  C02F3/34 ,  Y02W10/15

    摘要： Porous bodies are produced which are suitable for use as supports for catalysts, including living cells, such as bacteria and which are upset resistant to acids and bases. The bodies have a significantly large average pore diameter of about 0.5 to 100 microns, (i.e. 5,000 to 1,000,000 .ANG.) and a total pore volume of about 0.1 to 1.5 cc/g with the large pores contributing a pore volume of from about 0.1 to 1.0 cc/g. The bodies are made by preparing a mixture of ultimate particles containing a zeolite and one or more optional ingredients such as inorganic binders, extrusion or forming aids, burnout agents, or a forming liquid, such as water. Incorporated into the support is activated carbon which provides improved properties. In a preferred embodiment, the ultimate particles are formed by spray drying.

    摘要翻译： 生产适合用作催化剂载体的多孔体，包括活细胞如细菌，并且对酸和碱不利。 这些主体具有大约0.5至100微米（即5,000至1,000,000安格姆）的显着较大的平均孔径和约0.1至1.5cc / g的总孔体积，其中大孔有助于孔体积为约0.1至1.0 cc / g。 主体通过制备含有沸石和一种或多种任选成分如无机粘合剂，挤出或成型助剂，燃烧剂或成形液体如水的最终颗粒的混合物制成。 加入载体是活性炭，其提供改进的性质。 在优选的实施方案中，通过喷雾干燥形成最终颗粒。