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公开(公告)号:US20180265648A1
公开(公告)日:2018-09-20
申请号:US15921198
申请日:2018-03-14
IPC分类号: C08J3/09 , C08F220/46 , D01F6/18 , D01F1/10
CPC分类号: C08J3/097 , C08F220/46 , C08J2333/20 , D01D1/02 , D01F1/10 , D01F6/18 , D01F6/38 , D02G1/006
摘要: A process is described for the preparation of a homogeneous spinning solution for the production of acrylic fibers, which comprises i) a preparation step of an aqueous suspension of homopolymer or copolymer of acrylonitrile through the polymerization of monomers in aqueous suspension, removal of the unreacted monomers, filtration and washing of the aqueous suspension, obtaining a filtration cake, ii) a step for dispersing the filtration cake and a step iii) for evaporating the dispersion of polymer or obtaining the homogeneous spinning solution.
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公开(公告)号:US12091779B2
公开(公告)日:2024-09-17
申请号:US17588510
申请日:2022-01-31
摘要: An integrated and improved process for the production of acrylic fibers is described, specifically a process that starts from the comonomers and reaches the spinning step obtaining the final fiber.
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公开(公告)号:US11313053B2
公开(公告)日:2022-04-26
申请号:US16988843
申请日:2020-08-10
发明人: Franco Francalanci
IPC分类号: C08F20/44 , C08F220/46 , C08F220/48 , C08F236/12 , C08J3/11 , C08K5/17 , C08L33/20 , D01D1/02 , D01D5/06 , D01D10/02 , D01F1/07 , D01F6/38 , D01F9/22 , C08J3/09
摘要: An optimized process for the preparation of a spinning solution for the production of acrylic fiber precursors (PAN) of carbon fibers and an optimized process for the production of carbon fibers from said acrylic precursor (PAN), are described.
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公开(公告)号:US11920262B2
公开(公告)日:2024-03-05
申请号:US17826615
申请日:2022-05-27
IPC分类号: C08F2/16 , C08F2/38 , C08F4/04 , C08F218/08 , C08F220/44 , C08F220/46 , C08L33/20 , D01D1/02 , D01D5/06 , D01D5/12 , D01D5/16 , D01D7/00 , D01D10/06 , D01F1/02 , D01F6/18 , D01F6/38 , D01F9/22
CPC分类号: D01F9/22 , C08F220/44 , D01D1/02 , D01F6/38 , D10B2101/12 , D10B2321/10
摘要: An integrated and improved, single-step, process for the production of a carbon fiber precursor is described, specifically a process which starts from the comonomers and reaches the spinning step, obtaining the final precursor fiber.
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公开(公告)号:US20150376391A1
公开(公告)日:2015-12-31
申请号:US14591330
申请日:2015-01-07
CPC分类号: C08L33/20 , B01F1/0022 , B01F5/0602 , C08L2201/54 , C08L2203/12 , D01D1/02 , D01D4/06 , D01D5/06 , D01F6/18 , D01F6/38 , D10B2321/10
摘要: A process is described for the preparation of a homogeneous spinning solution for the production of acrylic fibers which comprises the following steps: i) preparation of a homogeneous suspension by mixing a powder homopolymer or copolymer of acrylonitrile with a mixture of DMSO/water ranging from 94.5/5.5 to 97/3% w/w at a temperature ranging from 5° C. to 10° C., preferably a mixture of DMSO/water 95/5 at a temperature of 5° C., said mixing being carried out in a time ranging from 5 to 30 minutes, by spraying a stream of the DMSO/water solvent onto a stream of powder homopolymer or copolymer of acrylonitrile, disgregated and premixed; ii) heating the homogeneous suspension coming from step i) to a temperature ranging from 70° C. to 150° C. in a time ranging of from 0.5 to 30 minutes, until the complete dissolution of the homopolymer or copolymer and the formation of a homogeneous solution. This spinning solution is then fed to a storage tank or to the spinning line.
摘要翻译: 描述了制备用于生产丙烯酸纤维的均匀纺丝溶液的方法,其包括以下步骤:i)通过将粉末均聚物或丙烯腈共聚物与DMSO /水的混合物混合制备均匀的悬浮液,其范围为94.5 / 5.5至97/3%w / w,温度为5℃至10℃,优选DMSO /水95/5的混合物,温度为5℃,所述混合在 通过将DMSO /水溶剂流喷射到分散和预混合的丙烯腈粉末均聚物或共聚物流上,时间为5至30分钟; ii)将来自步骤i)的均匀悬浮液加热至70℃至150℃的温度,时间范围为0.5至30分钟,直至均聚物或共聚物完全溶解并形成 均匀溶液。 然后将该纺丝溶液送入储罐或纺纱线。
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公开(公告)号:US11946167B2
公开(公告)日:2024-04-02
申请号:US17982007
申请日:2022-11-07
IPC分类号: B08B3/14 , B08B3/04 , D01D4/02 , D01D5/06 , D01D5/14 , D01D5/16 , D01D10/00 , D01D10/06 , D01D11/00 , D01F6/38 , D06B3/04 , D06B23/14 , D06B23/20 , D01F9/22 , D01H13/02
CPC分类号: D01F6/38 , B08B3/041 , B08B3/048 , D01D5/06 , D01D10/00 , D01D10/06 , D01D11/00 , D01F9/22 , D01H13/02 , D10B2321/10 , D10B2401/063
摘要: A process for the production of acrylic fibers, in particular a spinning process for obtaining precursor fibers of carbon fiber by the wet spinning of a polymer solution in an organic solvent and the relative apparatus.
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公开(公告)号:US20230160108A1
公开(公告)日:2023-05-25
申请号:US17982007
申请日:2022-11-07
摘要: A process for the production of acrylic fibers, in particular a spinning process for obtaining precursor fibers of carbon fiber by the wet spinning of a polymer solution in an organic solvent and the relative apparatus.
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公开(公告)号:US20210054539A1
公开(公告)日:2021-02-25
申请号:US16988843
申请日:2020-08-10
发明人: Franco FRANCALANCI
IPC分类号: D01F9/22
摘要: An optimized process for the preparation of a spinning solution for the production of acrylic fiber precursors (PAN) of carbon fibers and an optimized process for the production of carbon fibers from said acrylic precursor (PAN), are described.
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公开(公告)号:US09296889B2
公开(公告)日:2016-03-29
申请号:US14591330
申请日:2015-01-07
IPC分类号: C08K5/41 , C08L33/20 , D01D1/02 , D01D4/06 , D01D5/06 , D01F6/18 , D01F6/38 , B01F1/00 , B01F5/06
CPC分类号: C08L33/20 , B01F1/0022 , B01F5/0602 , C08L2201/54 , C08L2203/12 , D01D1/02 , D01D4/06 , D01D5/06 , D01F6/18 , D01F6/38 , D10B2321/10
摘要: A process for the preparation of a homogeneous spinning solution for the production of acrylic fibers comprising: i) preparation of a homogeneous suspension by mixing a powder homopolymer or copolymer of acrylonitrile with a mixture of DMSO/water ranging from 94.5/5.5 to 97/3% w/w at a temperature ranging from 5° C. to 10° C., said mixing being carried out in a time from 5 to 30 minutes, by spraying a stream of the DMSO/water solvent onto a stream of powder homopolymer or copolymer of acrylonitrile, disgregated and premixed; ii) heating the homogeneous suspension from step i) to a temperature from 70° C. to 150° C. in a time from 0.5 to 30 minutes, until the complete dissolution of the homopolymer or copolymer and the formation of a homogeneous solution. This spinning solution is then fed to a storage tank or to the spinning line.
摘要翻译: 制备用于制备丙烯酸纤维的均匀纺丝溶液的方法,其包括:i)通过将粉末均聚物或丙烯腈共聚物与DMSO /水的混合物混合制备均匀的悬浮液,其范围为94.5 / 5.5至97/3 在5℃至10℃的温度范围内的w / w%,所述混合在5至30分钟的时间内通过将DMSO /水溶剂流喷射到粉末均聚物流或 丙烯腈共聚物,分散和预混合; ii)在0.5至30分钟的时间内将来自步骤i)的均匀悬浮液加热至70℃至150℃的温度,直到均聚物或共聚物完全溶解并形成均匀溶液。 然后将该纺丝溶液送入储罐或纺纱线。
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10.
公开(公告)号:US20240067766A1
公开(公告)日:2024-02-29
申请号:US18236682
申请日:2023-08-22
IPC分类号: C08F6/00 , C08F6/12 , C08F220/46
CPC分类号: C08F6/003 , C08F6/12 , C08F220/46
摘要: A process for the recovery and recycling of unreacted monomer in a one-step process for the production of a carbon-fiber precursor. An integrated and improved single-step process for the production of a carbon-fiber precursor is also described, which starts from the co-monomers and reaches the spinning step obtaining the final precursor fiber, which provides for the recovery of the unreacted monomers at the end of the polymerization step and their recycling to the polymerization process itself.
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