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公开(公告)号：US09598523B2
公开(公告)日：2017-03-21
申请号：US12641921
申请日：2009-12-18
申请人： Olivier Guerret , Jacques Mongoin , Patrick Trouve
发明人： Olivier Guerret , Jacques Mongoin , Patrick Trouve
IPC分类号： C08K5/00 , C08K5/16 , C08K5/09 , C08K3/10 , C08K3/22 , C08K3/26 , C08K3/18 , C08L67/00 , C08L77/00 , C08L61/06 , C08L63/00 , C08F290/06 , C08L27/06 , C08L51/08
CPC分类号： C08F290/062 , C08L27/06 , C08L51/08 , C08L2666/24 , C08L55/005
摘要： The invention concerns to the use, as an agent improving the thermal stability of (meth)acrylic comb polymers of a macromonomer whose formula (I) is: R-(A-O)m—(B—O)n—R′ (I) wherein both m and n are non-zero and A and B designate alkyl groups having 2 to 4 carbon atoms, but different from one another. The invention further pertains to the implementation of the polymers obtained, as agents improving the thermal stability of the plastic compositions that contain them.
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2.发明申请MACROMONOMERS IMPROVING THE THERMAL STABILITY OF (METH)ACRYLIC COMB POLYMERS, USE OF THESE POLYMERS IN LOADED PLASTIC COMPOSITIONS 有权改进（甲基）丙烯酸聚合物的热稳定性的大分子单体，这些聚合物在加载的塑料组合物中的使用公开(公告)号：US20100174012A1
公开(公告)日：2010-07-08
申请号：US12641921
申请日：2009-12-18
申请人： Olivier GUERRET , Jacques Mongoin , Patrick Trouve
发明人： Olivier GUERRET , Jacques Mongoin , Patrick Trouve
CPC分类号： C08F290/062 , C08L27/06 , C08L51/08 , C08L2666/24 , C08L55/005
摘要： The invention concerns to the use, as an agent improving the thermal stability of (meth)acrylic comb polymers of a macromonomer whose formula (I) is: R-(A-O)m—(B—O)n—R′ (I) wherein both m and n are non-zero and A and B designate alkyl groups having 2 to 4 carbon atoms, but different from one another. The invention further pertains to the implementation of the polymers obtained, as agents improving the thermal stability of the plastic compositions that contain them.
摘要翻译： 本发明涉及作为提高其式（I）为：R-（AO）m - （B-O）n -R'（I）的大分子单体的（甲基）丙烯酸类梳状聚合物的热稳定性的试剂， 其中m和n都不为零，A和B表示具有2至4个碳原子但彼此不同的烷基。 本发明还涉及所获得的聚合物作为改善含有它们的塑料组合物的热稳定性的试剂的实施。
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3.发明申请USE OF A COMB POLYMER WITH AT LEAST ONE POLYALKYLENE OXIDE GRAFTED FUNCTION AS A MINERAL CHARGE COMPATIBILITY AGENT FOR CHLORINATED THERMOPLASTIC MATERIALS 有权使用具有至少一种聚亚烷基氧化物接枝功能的混合聚合物作为氯化物热塑性材料的矿物电荷相容性试剂公开(公告)号：US20100069552A1
公开(公告)日：2010-03-18
申请号：US12447663
申请日：2007-10-17
申请人： Olivier Guerret , Patrick Trouve , Jacques Mongoin
发明人： Olivier Guerret , Patrick Trouve , Jacques Mongoin
CPC分类号： C09C3/10 , C01P2004/62 , C01P2006/60 , C08F259/04 , C08F259/08 , C08F283/06 , C08F290/062 , C08F293/005 , C08L51/003 , C08L51/08 , C09C1/021 , C08L2666/02
摘要： The invention firstly concerns the use as a compatibilising agent, in a process to manufacture a chlorinated thermoplastic resin filled with a mineral material, of a comb polymer having at least one anionic monomer with ethylenic unsaturation, to which is grafted at least one polyalkylene oxide group.The invention also concerns the chlorinated thermoplastic materials thus obtained, which have an improved compatibility between the filler and the chlorinated thermoplastic resin, whilst reducing the quantity of compatibilising agents as used in the chlorinated and filled thermoplastic materials according to the prior art, where the said compatibilising agents used in the prior art were essentially fatty acids, and more specifically stearic acid or its salts.
摘要翻译： 本发明首先涉及作为相容剂的用途，在制造填充有矿物材料的氯化热塑性树脂的方法中，所述梳理聚合物具有至少一个具有烯属不饱和键的阴离子单体，其中至少一个聚环氧烷基团 。 本发明还涉及如此获得的氯化热塑性材料，其具有改进的填充剂和氯化热塑性树脂之间的相容性，同时减少了根据现有技术的氯化和填充的热塑性材料中使用的相容剂的量，其中所述 现有技术中使用的相容剂基本上是脂肪酸，更具体地说是硬脂酸或其盐。
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4.发明授权Rheology regulators such as ground natural calcium carbonates optionally treated with a fatty acid or salt and their use 有权流变调节剂，例如任选用脂肪酸或盐处理的磨碎的天然碳酸钙及其用途公开(公告)号：US07300974B2
公开(公告)日：2007-11-27
申请号：US10781686
申请日：2004-02-20
CPC分类号： C01F11/18 , C01P2006/12 , C01P2006/19 , C08K3/26 , C08K2003/265 , C09D5/34 , C09K3/10 , C09K2200/0239
摘要： The invention relates to the selection of a natural calcium carbonate crushed to a high degree of fineness, possibly treated with one or more fatty acids or one or more of their salts or mixtures thereof, and its use as a rheology regulator for polymeric compositions.The specific surface area is 14 to 30 m2/g measured according to the BET method to ISO 4652, and the oil absorption is greater than 16 measured according to ISO 787-V (Rub-out method).The conditions of mixing of the constituents and manufacture are improved, as well as the properties of the final product.
摘要翻译： 本发明涉及粉碎成高度细度的天然碳酸钙的选择，其可能用一种或多种脂肪酸或其一种或多种盐或其混合物处理，以及其作为聚合物组合物的流变调节剂的用途。 比表面积根据BET法按照ISO 4652测量为14至30m 2 / g，吸油率大于根据ISO787-V（擦除法）测量的16， 。 改善了组分和制造的混合条件以及最终产品的性能。
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5.发明授权Use as a rheology agent in a filled plastic paste of a dry-ground calcium carbonate with a copolymer of (meth)acrylic acid with an alkoxy or hydroxy polyalkyleneglycol group 失效在干粉碎碳酸钙的填充塑料糊剂中与（甲基）丙烯酸与烷氧基或羟基聚亚烷基二醇基团的共聚物作为流变剂使用公开(公告)号：US08440754B2
公开(公告)日：2013-05-14
申请号：US13225882
申请日：2011-09-06
CPC分类号： C09C1/021 , C01P2004/61 , C01P2004/62 , C01P2006/22
摘要： The invention resides in the use, as an agent reducing the viscosity of a thermoplastic or thermosetting paste filled with a calcium carbonate, of a calcium carbonate characterized in that it is obtained by dry-grinding, firstly, and in that it is dry-ground in the presence of a grinding aid agent which is a copolymer of (meth)acrylic acid with a monomer containing an alcoxy or hydroxy polyalkyleneglycol group, secondly. The invention also concerns the filled thermoplastic and thermosetting pastes obtained in this manner.
摘要翻译： 本发明的目的在于，使用碳酸钙作为降低填充有碳酸钙的热塑性或热固性糊剂的粘度的试剂，其特征在于其通过干式研磨获得，并且其干燥地面 在作为（甲基）丙烯酸与含有羟基聚亚烷基二醇基团的单体的共聚物的研磨助剂的存在下进行。 本发明还涉及以这种方式获得的填充的热塑性和热固性浆料。
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6.发明申请USE AS A RHEOLOGY AGENT IN A FILLED PLASTIC PASTE OF A DRY-GROUND CALCIUM CARBONATE WITH A COPOLYMER OF (METH)ACRYLIC ACID WITH AN ALKOXY OR HYDROXY POLYALKYLENEGLYCOL GROUP 失效用作具有烷基或羟基聚乙烯醇基的（甲基）丙烯酸的共聚物的干燥碳酸钙的填充塑料浆料中的流变剂公开(公告)号：US20120053280A1
公开(公告)日：2012-03-01
申请号：US13225882
申请日：2011-09-06
CPC分类号： C09C1/021 , C01P2004/61 , C01P2004/62 , C01P2006/22
摘要： The invention resides in the use, as an agent reducing the viscosity of a thermoplastic or thermosetting paste filled with a calcium carbonate, of a calcium carbonate characterised in that it is obtained by dry-grinding, firstly, and in that it is dry-ground in the presence of a grinding aid agent which is a copolymer of (meth)acrylic acid with a monomer containing an alcoxy or hydroxy polyalkyleneglycol group, secondly. The invention also concerns the filled thermoplastic and thermosetting pastes obtained in this manner.
摘要翻译： 本发明的目的在于，使用碳酸钙作为降低填充有碳酸钙的热塑性或热固性糊剂的粘度的试剂，其特征在于其通过干式研磨获得，并且其干燥地面 在作为（甲基）丙烯酸与含有羟基聚亚烷基二醇基团的单体的共聚物的研磨助剂的存在下进行。 本发明还涉及以这种方式获得的填充的热塑性和热固性浆料。
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7.发明申请Novel rheology regulators of the crushed natural calcium carbonate type, possibly treated with a fatty acid or its salt, and their application in polymeric compositions 审中-公开可能用脂肪酸或其盐处理的破碎的天然碳酸钙类型的新型流变调节剂及其在聚合物组合物中的应用公开(公告)号：US20060148930A1
公开(公告)日：2006-07-06
申请号：US11362761
申请日：2006-02-28
CPC分类号： C01F11/18 , C01P2006/12 , C01P2006/19 , C08K3/26 , C08K2003/265 , C09D5/34 , C09K3/10 , C09K2200/0239
摘要： The invention relates to the selection of a natural calcium carbonate crushed to a high degree of fineness, possibly treated with one or more fatty acids or one or more of their salts or mixtures thereof, and its use as a rheology regulator for polymeric compositions. The specific surface area is 14 to 30 m2/g measured according to the BET method to ISO 4652, and the oil absorption is greater than 16 measured according to ISO 787-V (Rub-out method). The conditions of mixing of the constituents and manufacture are improved, as well as the properties of the final product.
摘要翻译： 本发明涉及粉碎成高度细度的天然碳酸钙的选择，其可能用一种或多种脂肪酸或其一种或多种盐或其混合物处理，以及其作为聚合物组合物的流变调节剂的用途。 比表面积根据BET法按照ISO 4652测量为14至30m 2 / g，吸油率大于根据ISO787-V（擦除法）测量的16， 。 改善了组分和制造的混合条件以及最终产品的性能。
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公开(公告)号：US5786415A
公开(公告)日：1998-07-28
申请号：US767431
申请日：1996-12-16
申请人： Pierre Blanchard , Patrick Trouve
发明人： Pierre Blanchard , Patrick Trouve
CPC分类号： C09C3/10 , C08K3/34 , C09C1/28 , C09C1/3072 , C01P2004/61
摘要： The present invention relates to a method of dispersing or treating a mineral filler into a thermoplastic resin; the dispersing agent or agent for treatment of a mineral filler is a styrene-maleic anhydride copolymer, having an weight average molecular weight preferably between 1000 to 3000; the thermoplastic resin is selected from (a) a hydrocarbon homopolymer without an aryl group, (b) a copolymer without an aryl group, and with a molecule comprised of carbon, hydrogen and oxygen in which the content of oxygen atoms does not exceed 22% by weight or (c) a mixture of the above described homopolymer and copolymer; the mineral fillers are basic or have surfaces that have free hydroxyl groups. The present invention relates also to thermoplastic compounds which are highly filled, stable, fluid and homogeneous and which contain mineral agents; further these compositions are useful in the fabrication of plastic products.
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9.发明申请NOVEL RHEOLOGY REGULATORS SUCH AS GROUND NATURAL CALCIUM CARBONATES OPTIONALLY TREATED WITH A FATTY ACID OR SALT AND THEIR USE 审中-公开新型流变学调节剂如天然碳酸钙与脂肪酸或盐及其使用有针对性的处理公开(公告)号：US20110245396A1
公开(公告)日：2011-10-06
申请号：US12938616
申请日：2010-11-03
CPC分类号： C01F11/18 , C01P2006/12 , C01P2006/19 , C08K3/26 , C08K2003/265 , C09D5/34 , C09K3/10 , C09K2200/0239
摘要： The invention relates to the selection of a natural calcium carbonate crushed to a high degree of fineness, possibly treated with one or more fatty acids or one or more of their salts or mixtures thereof, and its use as a rheology regulator for polymeric compositions.The specific surface area is 14 to 30 m2/g measured according to the BET method to ISO 4652, and the oil absorption is greater than 16 measured according to ISO 787-V (Rub-out method).The conditions of mixing of the constituents and manufacture are improved, as well as the properties of the final product.
摘要翻译： 本发明涉及粉碎成高度细度的天然碳酸钙的选择，其可能用一种或多种脂肪酸或其一种或多种盐或其混合物处理，以及其作为聚合物组合物的流变调节剂的用途。 比表面积为14〜30m2 / g，按照ISO 4652的BET法测定，吸油率大于16，按照ISO 787-V（擦除法）测定。 改善了组分和制造的混合条件以及最终产品的性能。
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10.发明授权Use of styrene and maleic anhydride copolymers as dispersing agents and/or for treatment of mineral fillers and thermoplastic compounds containing same 失效使用苯乙烯和马来酸酐共聚物作为分散剂和/或用于处理含有它们的矿物填料和热塑性化合物
公开(公告)号：US6114454A
公开(公告)日：2000-09-05
申请号：US50197
申请日：1998-03-30
申请人： Pierre Blanchard , Patrick Trouve
发明人： Pierre Blanchard , Patrick Trouve
CPC分类号： C09C3/10 , C08K3/34 , C09C1/28 , C09C1/3072 , C01P2004/61
摘要： The present invention relates to a method of dispersing or treating a mineral filler into a thermoplastic resin; the dispersing agent or agent for treatment of a mineral filler is a styrene-maleic anhydride copolymer, having an weight average molecular weight preferably between 1000 to 3000; the thermoplastic resin is selected from (a) a hydrocarbon homopolymer without an aryl group, (b) a copolymer without an aryl group, and with a molecule comprised of carbon, hydrogen and oxygen in which the content of oxygen atoms does not exceed 22% by weight or (c) a mixture of the above described homopolymer and copolymer; the mineral fillers are basic or have surfaces that have free hydroxyl groups. The present invention relates also to thermoplastic compounds which are highly filled, stable, fluid and homogeneous and which contain mineral agents; further these compositions are useful in the fabrication of plastic products.
摘要翻译： 本发明涉及将矿物填料分散或处理成热塑性树脂的方法; 用于处理矿物填料的分散剂或试剂是苯乙烯 - 马来酸酐共聚物，其重均分子量优选为1000-3000; 热塑性树脂选自（a）不具有芳基的烃均聚物，（b）不含芳基的共聚物，以及由氧，氧和氧组成的分子，氧原子含量不超过22％ 或（c）上述均聚物和共聚物的混合物; 矿物填料是碱性的或具有游离羟基的表面。 本发明还涉及高度填充，稳定，流动和均匀且含有矿物质的热塑性化合物; 此外，这些组合物可用于制造塑料制品。
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