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    CATALYST-CONTROLLED ALIPHATIC C-H OXIDATIONS
    2.
    发明申请
    CATALYST-CONTROLLED ALIPHATIC C-H OXIDATIONS 有权
    催化剂控制的氧化C-H氧化

    公开(公告)号：US20160214097A1

    公开(公告)日：2016-07-28

    申请号：US14916966

    申请日：2014-09-09

    Applicant: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS

    Inventor： M. Christina White ,  Paul E. Gormisky

    IPC: B01J31/18 ,  C07D307/93 ,  G06F19/00 ,  C07C67/29 ,  C07B33/00 ,  C07F15/02 ,  C07D493/18

    CPC classification number: B01J31/184 ,  B01J31/1815 ,  B01J2231/70 ,  B01J2531/0258 ,  B01J2531/842 ,  C07B33/00 ,  C07C67/29 ,  C07D307/93 ,  C07D493/18 ,  C07F15/025 ,  G06F19/702 ,  Y02P20/582

    Abstract: The invention provides simple small molecule, non-heme iron catalyst systems with broad substrate scope that can predictably enhance or overturn a Substrate Control Catalyst Control substrate's inherent reactivity preference for sp3-hybridized C—H bond oxidation. The invention also provides methods for selective aliphatic C—H bond oxidation. Furthermore, a structure-based catalyst reactivity model is disclosed that quantitatively correlates the innate physical properties of the substrate to the site-selectivities observed as a function of the catalyst. The catalyst systems can be used in combination with oxidants such as hydrogen peroxide to effect highly selective oxidations of unactivated sp3 C—H bonds over a broad range of substrates.

    Abstract translation: 本发明提供了具有广泛底物范围的简单的小分子，非血红素铁催化剂体系，其可预测地增强或翻转底物对照催化剂对照底物对sp3-杂化的C-H键氧化的固有反应性偏好。 本发明还提供了用于选择性脂族C-H键氧化的方法。 此外，公开了一种基于结构的催化剂反应性模型，其定量地将底物的固有物理性质与作为催化剂的函数观察到的位点选择性相关。 催化剂体系可以与氧化剂如过氧化氢组合使用，以在宽范围的底物上实现未活化的sp 3 C-H键的高选择性氧化。

    METHOD FOR MAKING HARMFUL COMPOUND HARMLESS AND METHOD FOR PRODUCING ORGANIC SEMICONDUCTOR ELEMENT COMPOUND
    4.
    发明申请
    METHOD FOR MAKING HARMFUL COMPOUND HARMLESS AND METHOD FOR PRODUCING ORGANIC SEMICONDUCTOR ELEMENT COMPOUND 有权
    制造有机化合物的方法和用于生产有机半导体元素化合物的方法

    公开(公告)号：US20110178319A1

    公开(公告)日：2011-07-21

    申请号：US13120377

    申请日：2009-11-02

    Applicant: Koichiro Nakamura

    Inventor： Koichiro Nakamura

    IPC: C07F9/72

    CPC classification number: B01J31/184 ,  A62D3/176 ,  A62D3/30 ,  A62D2101/24 ,  A62D2101/43 ,  B01D2257/60 ,  B01J21/063 ,  B01J35/004 ,  B01J2231/40 ,  B01J2531/025 ,  B01J2531/845 ,  C07F9/72

    Abstract: The present invention provides a method for making a harmful arsenic compound, antimony compound and selenium compound harmless by using an organic cobalt complex, in which the cost of the method can be improved. The present invention is a method for making a harmful compound harmless, including irradiating light to an organic cobalt complex containing cobalt as a central metal and a corrin ring as a ligand, a methyl group donor, a titanium oxide photocatalyst, and a harmful compound containing an arsenic atom, an antimony atom or a selenium atom to methylate the harmful compound. In the present invention, it is preferable that the harmful compound be trimethylated.

    Abstract translation: 本发明提供了通过使用有机钴络合物制造有害的砷化合物，锑化合物和硒化合物无害的方法，其中可以提高该方法的成本。 本发明是一种使有害化合物无害化的方法，包括向含有钴作为中心金属和作为配体的corrin环的有机钴络合物照射光，甲基供体，氧化钛光催化剂和含有 砷原子，锑原子或硒原子甲基化有害化合物。 在本发明中，优选将有害化合物进行三甲基化。

    Coupling catalyst and process using the same
    6.
    发明授权
    Coupling catalyst and process using the same 有权
    偶联催化剂和工艺使用相同

    公开(公告)号：US07041856B2

    公开(公告)日：2006-05-09

    申请号：US10277138

    申请日：2002-10-22

    Applicant: Tamon Itahashi ,  Takashi Kamikawa

    Inventor： Tamon Itahashi ,  Takashi Kamikawa

    IPC: C07C41/30 ,  C07C213/06 ,  C07B37/04 ,  C07F15/04

    CPC classification number: B01J31/181 ,  B01J23/755 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/1825 ,  B01J31/184 ,  B01J31/2295 ,  B01J2231/4211 ,  B01J2531/847 ,  C07B37/04 ,  C07D213/06 ,  C07D213/16

    Abstract: There are disclosed a process for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1),  (1) wherein R1 and R2 independently represent a substituted or unsubstituted aryl group, which process is characterized by reacting an unsaturated organic compound of formula (2): n′(R1X1n)  (2) wherein n, n′, and R1 are the same as defined above, and X1 is the same or different and independently represents a leaving group and bonded with a sp2 carbon atom of R1 group, with a boron compound of formula (3): m{R2(BX22)n′}  (3) wherein R2 and n′ are the same as defined above, X2 represents a hydroxy group, an alkoxy group, in the presence of a catalyst containing (A) a nickel compound, and (B) a nitrogen-containing cyclic compound, and the catalyst.

    Abstract translation: 公开了一种制备式（1）的偶联化合物的方法：<？in-line-formula description =“In-line Formulas”end =“lead”→（Y - ） （n'-1），（（1））（n'-1）其中R 1和R 2独立地表示取代或未取代的 芳基，该方法的特征在于使式（2）的不饱和有机化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> n'（R＆ （2）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中n，n '和R 1'与上述定义相同，X 1相同或不同，并且独立地表示离去基团并与R a的sp 2碳原子键合， 具有式（3）的硼化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> m {R SUP>（BX <2> （3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R <2> 和n'与上述相同，X 2表示羟基，烷氧基，在含有（A）镍化合物的催化剂存在下，和（B） 含氮环状化合物和催化剂。

    Metal ligand containing bleaching compositions
    7.
    发明授权
    Metal ligand containing bleaching compositions 失效
    含有漂白组合物的金属配体

    公开(公告)号：US6099586A

    公开(公告)日：2000-08-08

    申请号：US119459

    申请日：1998-07-20

    Applicant: Terrence J. Collins ,  Colin P. Horwitz

    Inventor： Terrence J. Collins ,  Colin P. Horwitz

    IPC: C07D257/02 ,  C07D257/10 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02 ,  D21C9/10 ,  D21C9/16 ,  C01B15/00 ,  C01B15/055 ,  D06L3/06

    CPC classification number: D21C9/1036 ,  B01J31/006 ,  C07D257/10 ,  C11D3/3932 ,  B01J2231/70 ,  B01J2531/72 ,  B01J2531/842 ,  B01J31/184

    Abstract: The invention provides a novel bleaching composition comprising:(a) an oxidatively stable bleach activator having the structure ##STR1## wherein Y.sub.1, Y.sub.3 and Y.sub.4 each represents a bridging group, i.e., zero, one, two or three carbon containing nodes for substitution while Y.sub.2 is a bridging group of at least one carbon containing node for substitution, each said node containing a C(R), C(R.sub.1)(R.sub.2), or a C(R).sub.2 unit and each R substituent is the same or different from the remaining R substituent and is selected from the group consisting of H, alkyl, cycloalkyl, cycloalkenyl, alkenyl, aryl, alkynyl, alkylaryl, halogen, alkoxy, or phenoxy, CH.sub.2 CF.sub.3, CF.sub.1 and combinations thereof, or form a substituted or unsubstituted benzene ring of which two carbon atoms in the ring form notes in the Y unit, or together with a paired R substituent bound to the same carbon atom form a cycloalkyl or cyloalkenyl ring, which may include an atom other than carbon, e.g., cyclopentyl or cyclohexyl; M is a transition metal with oxidation states of I, II, III, IV, V or VI, or selected IV from Groups VIA, VIIA, VIII, and IB; Q is any counterion which would balance the charge of the compound on a stoichiometric basis; L is any labile ligand; and,(b) an effective amount of a source of peroxy compound.

    Abstract translation: 本发明提供了一种新颖的漂白组合物，其包含：（a）具有结构的氧化稳定的漂白活化剂，其中Y 1，Y 3和Y 4各自表示桥连基团，即用于取代的0,1,2或3个含碳的结点，而Y2是 每个所述节点含有C（R），C（R 1）（R 2）或C（R）2单元，并且每个R取代基与剩余的碳原子的相同或不同） R选自H，烷基，环烷基，环烯基，烯基，芳基，炔基，烷基芳基，卤素，烷氧基或苯氧基，CH 2 CF 3，CF 1及其组合，或形成其取代或未取代的苯环 环中的两个碳原子在Y单元中形成音符，或与与相同碳原子结合的成对的R取代基一起形成环烷基或环烯基环，其可以包括除碳以外的原子，例如环戊基或环己基; M是氧化态为I，II，III，IV，V或VI的过渡金属，或VIA，VIIA，VIII和IB族选自IV; Q是以化学计量为基础平衡化合物的电荷的任何抗衡离子; L是任何不稳定的配体; 和（b）有效量的过氧化合物源。

    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS
    10.
    发明申请
    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS 有权
    聚碳酸酯多元醇组合物和方法

    公开(公告)号：US20150152221A1

    公开(公告)日：2015-06-04

    申请号：US14402835

    申请日：2013-05-24

    Applicant: NOVOMER, INC.

    Inventor： Jay J. Farmer

    IPC: C08G64/34 ,  C08G18/44 ,  C08G64/02

    CPC classification number: C08G64/34 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/183 ,  B01J31/184 ,  B01J31/22 ,  B01J31/2217 ,  B01J31/2243 ,  B01J2231/14 ,  B01J2531/0238 ,  B01J2531/025 ,  B01J2531/0252 ,  B01J2531/845 ,  C08G18/44 ,  C08G64/0208 ,  C08G64/0216 ,  C08G65/2603 ,  C08G65/266 ,  Y02P20/52

    Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO2, wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

    Abstract translation: 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有能够引发环氧化物和CO 2共聚的一个或多个位点，其中链转移剂含有一个或多个掩蔽的羟基。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基，高百分比的碳酸酯键，并且基本上所有具有羟基端基的聚碳酸酯链都没有嵌入链转移剂 。

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