摘要:
A reversible SOFC monolithic stack is provided which comprises: 1) a first component which comprises at least one porous metal containing layer (1) with a combined electrolyte and sealing layer on the porous metal containing layer (1); wherein the at least one porous metal containing layer (1) hosts an electrode; 2) a second component comprising at least one porous metal containing layer (1) with a combined interconnect and sealing layer on the porous metal containing layer; wherein the at least one porous metal containing layers hosts an electrode. Further provided is a method for preparing a reversible solid oxide fuel cell stack. The obtained solid oxide fuel cell stack has improved mechanical stability and high electrical performance, while the process for obtaining same is cost effective.
摘要:
A solid oxide cell obtainable by a process comprising the steps of: depositing a fuel electrode layer on a fuel electrode support layer; depositing an electrolyte layer comprising stabilised zirconia on the fuel electrode layer to provide an assembly of fuel electrode support, fuel electrode and electrolyte; optionally sintering the assembly of fuel electrode support, fuel electrode and electrolyte together to provide a pre-sintered half cell; depositing on the electrolyte layer of the pre-sintered half cell one or more oxygen electrode layers, at least one of the oxygen electrode layers comprising a composite of lanthanum-strontium-manganite and stabilised zirconia to provide a complete solid oxide cell; sintering the oxygen electrode layers together with the pre-sintered half cell to provide a sintered complete solid oxide cell; and impregnating the one or more oxygen electrode layers of the sintered complete solid oxide cell with manganese to obtain a manganese impregnated solid oxide cell.
摘要:
A method for producing and reactivating a solid oxide cell stack structure by providing a catalyst precursor in at least one of the electrode layers by impregnation and subsequent drying after the stack has been assembled and initiated. The method includes impregnating a catalyst precursor into a cathode of a solid oxide cell stack which already contains an active material (an anode reduction) for example, in the form of Ni/YSZ anodes. Due to a significantly improved performance and an unexpected voltage improvement this solid oxide cell stack structure is particularly suitable for use in solid oxide fuel cell (SOFC) and solid oxide electrolysing cell (SOEC) applications.
摘要:
A method for producing and reactivating a solid oxide cell stack structure by providing a catalyst precursor in at least one of the electrode layers by impregnation and subsequent drying after the stack has been assembled and initiated. Due to a significantly improved performance and an unexpected voltage improvement this solid oxide cell stack structure is particularly suitable for use in solid oxide fuel cell (SOFC) and solid oxide electrolysing cell (SOEC) applications.
摘要:
The present invention provides a membrane, comprising a porous support layer a gas tight electronically and ionically conducting membrane layer and a catalyst layer, characterized in that the electronically and ionically conducting membrane layer is formed from a material having a crystallite structure with a crystal size of about 1 to 100 nm, and a method for producing same.
摘要:
A multi-layer coating for protection of metals and alloys against oxidation at high temperatures in general is provided. The invention utilizes a multi-layer ceramic coating on metals or alloys for increased oxidation-resistance, comprising at least two layers, wherein the first layer (3) which faces the metal containing surface and the second layer facing the surrounding atmosphere (4) both comprise an oxide, and wherein the first layer (3) has a tracer diffusion coefficient for cations Mm+, where M is the scale forming element of the alloy, and the second layer (4) has a tracer diffusion coefficient for oxygen ions O2− satisfying the following formula: wherein p(O2)m is the oxygen partial pressure in equilibrium between the metallic sub-strate and MaOb, p(O2)ex is the oxygen partial pressure in the reaction atmosphere, DM is the tracer diffusion coefficient of the metal cations Mm+ in the first layer (3), and Do is O tracer diffusion coefficient in the second layer (4). The coating may be used in high temperature devices, particularly for coating interconnect materials in solid oxide electrolytic devices, including solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs).
摘要:
The present invention relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material, at least one metal and a catalyst material, and wherein the overall thickness of the thin reversible cell is about 150 μm or less, and to a method for producing same. The present invention also relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material and a catalyst material, wherein the electrolyte material is doper zirconia, and wherein the overall thickness of the thin reversible cell is about 150 μm or less, and to a method for producing same. The present invention further provides a thin separation membrane, comprising at least a porous anode layer, a membrane layer comprising a mixed conducting material and a porous cathode layer, wherein the anode layer and the cathode layer comprise the mixed conducting material and a catalyst material, and wherein the overall thickness of the thin separation membrane is about 1050 μm or less.
摘要:
A multi-layer coating for protection of metals and alloys against oxidation at high temperatures is provided. The invention utilizes a multi-layer ceramic coating on metals or alloys for increased oxidation-resistance, comprising at least two layers, wherein the first layer (3) and the second layer (4) both comprise an oxide, and wherein the first layer (3) has a tracer diffusion coefficient for cations Mm+, where M is the scale forming element of the alloy, and the second layer (4) has a tracer diffusion coefficient for oxygen ions O2− satisfying the following formula: ∫ ln p ( O 2 ) in ln p ( O 2 ) ex ( D O + m 2 D M ) ⅆ ln p ( O 2 )
摘要:
A reversible SOFC monolithic stack is provided which comprises: 1) a first component which comprises at least one porous metal containing layer (1) with a combined electrolyte and sealing layer on the porous metal containing layer (1); wherein the at least one porous metal containing layer (1) hosts an electrode; 2) a second component comprising at least one porous metal containing layer (1) with a combined interconnect and sealing layer on the porous metal containing layer; wherein the at least one porous metal containing layers hosts an electrode. Further provided is a method for preparing a reversible solid oxide fuel cell stack. The obtained solid oxide fuel cell stack has improved mechanical stability and high electrical performance, while the process for obtaining same is cost effective.
摘要:
The present invention provides a solid oxide cell comprising a support layer, a first electrode layer, an electrolyte layer, and a second cathode layer, wherein at least one of the electrode layers comprises electrolyte material, a catalyst and agglomerated particles selected from the group consisting of alkali oxides, earth alkali oxides and transition metal oxides.