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公开(公告)号:US20110192722A1
公开(公告)日:2011-08-11
申请号:US12703668
申请日:2010-02-10
申请人: Jun Cheng , Petr Jandik , Christopher A. Pohl
发明人: Jun Cheng , Petr Jandik , Christopher A. Pohl
IPC分类号: G01N27/26
CPC分类号: G01N27/30 , G01N27/301 , G01N27/4166 , G01N30/64
摘要: A detection cell for a chromatography system includes a cell body having an inlet, an outlet, and a counter electrode, a working electrode, a sample flow passageway extending between the inlet and the outlet and in fluid contact with the counter and working electrodes, and a palladium/noble metal reference electrode system. A method of using the detection cell is also described.
摘要翻译: 用于色谱系统的检测电池包括具有入口,出口和对电极的电池体,工作电极,在入口和出口之间延伸并与计数器和工作电极流体接触的样品流动通道,以及 钯/贵金属参考电极系统。 还描述了使用检测单元的方法。
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2.
公开(公告)号:US5156724A
公开(公告)日:1992-10-20
申请号:US642685
申请日:1991-01-17
申请人: William R. Jones , Petr Jandik , Michael Merion , Andrea Weston
发明人: William R. Jones , Petr Jandik , Michael Merion , Andrea Weston
IPC分类号: B01D57/02 , G01N27/447
CPC分类号: G01N27/44721
摘要: A technique for separating, identifying and measuring ions in solution by capillary zone electrophoresis is described, which provides improved sensitivity and resolution of anionic and cationic species. The method involves introducing a sample containing the ionic species into a narrow core capillary filled with a carrier electrolyte containing a selected light-absorbing anion or cation to an electrical current in a capillary column causing the ions to elute according to their ionic mobility. Both UV absorbing and UV-transparent ions can be detected and quantitated by UV/Visible photometric monitoring.
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公开(公告)号:US5132018A
公开(公告)日:1992-07-21
申请号:US729775
申请日:1991-07-10
摘要: An improved gradient ion chromatography process is disclosed. The process employs a gradient eluent which is maintained in a substantially isoconductive state throughout each sample run. By maintaining the gradient in an isoconductive state, conductivity detection and analysis of eluted analytes is enhanced.
摘要翻译: 公开了改进的梯度离子色谱法。 该方法采用梯度洗脱液,其在每个样品运行中保持基本上不同的生理状态。 通过保持等离子体状态的梯度,增强了洗脱分析物的电导率检测和分析。
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公开(公告)号:US09086426B2
公开(公告)日:2015-07-21
申请号:US13611631
申请日:2012-09-12
申请人: Yan Liu , Petr Jandik , Christopher A. Pohl
发明人: Yan Liu , Petr Jandik , Christopher A. Pohl
IPC分类号: B01D15/08 , C25B9/18 , F17D1/00 , G01N30/00 , G01N30/04 , G01N30/96 , G01N30/34 , B01D15/16 , B01D15/36 , B01D61/44
CPC分类号: C25B9/18 , B01D15/166 , B01D15/361 , B01D61/44 , C25B1/02 , C25B1/14 , C25B3/00 , C25B13/00 , G01N30/16 , G01N30/34 , G01N30/96 , G01N2030/965 , Y02E60/34 , Y10T137/0318
摘要: A system and method to generate a concentration gradient eluent flow are described. The concentration gradient eluent flow can include at least two different generants. A liquid can be pumped to an eluent generating device. A first controlling signal can be applied to a first eluent generator to generate a first generant. A second controlling signal can be applied to a second eluent generator to generate a second generant. Either the first and/or the second controlling signal can be varied as a function of time to generate the concentration gradient eluent flow.
摘要翻译: 描述了产生浓度梯度洗脱流的系统和方法。 浓度梯度洗脱液流可以包括至少两种不同的生成剂。 液体可以泵送到洗脱液生成装置。 第一控制信号可以应用于第一洗脱液发生器以产生第一发生器。 第二控制信号可以应用于第二淋洗液发生器以产生第二发生器。 第一和/或第二控制信号可以作为时间的函数而变化以产生浓度梯度洗脱液流。
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公开(公告)号:US07566392B2
公开(公告)日:2009-07-28
申请号:US11403565
申请日:2006-04-12
申请人: Jun Cheng , Petr Jandik , Xiaodong Liu , Christopher A. Pohl
发明人: Jun Cheng , Petr Jandik , Xiaodong Liu , Christopher A. Pohl
IPC分类号: G01N27/403
CPC分类号: G01N27/49
摘要: In one embodiment, the present invention is directed to a pulsed electrochemical detection method comprising (a) flowing a liquid sample stream including at least one analyte past a working electrode in a flow-through cell; (b) applying at least three pulsed electrical potentials to the working electrode, (1) a first conditioning potential, (2) a second detection and oxidative cleaning potential, and (3) a third reductive cleaning potential, said second potential being higher than said first and third potentials and said first potential being higher than said third potential; and (c) detecting the output from said working electrode during the time period of applying said second potential.
摘要翻译: 在一个实施方案中,本发明涉及脉冲电化学检测方法,其包括(a)将包含至少一种分析物的液体样品流流过流通池中的工作电极; (b)向工作电极施加至少三个脉冲电势,(1)第一调节电位,(2)第二检测和氧化清洗电位,和(3)第三还原清洗电位,所述第二电位高于 说第一和第三个潜力,并说第一个潜力高于第三个潜力; 以及(c)在施加所述第二电位的时间段期间检测来自所述工作电极的输出。
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公开(公告)号:US20070240998A1
公开(公告)日:2007-10-18
申请号:US11403565
申请日:2006-04-12
申请人: Jun Cheng , Petr Jandik , Xiaodong Liu , Christopher Pohl
发明人: Jun Cheng , Petr Jandik , Xiaodong Liu , Christopher Pohl
IPC分类号: G01N27/26
CPC分类号: G01N27/49
摘要: In one embodiment, the present invention is directed to a pulsed electrochemical detection method comprising (a) flowing a liquid sample stream including at least one analyte past a working electrode in a flow-through cell; (b) applying at least three pulsed electrical potentials to the working electrode, (1) a first conditioning potential, (2) a second detection and oxidative cleaning potential, and (3) a third reductive cleaning potential, said second potential being higher than said first and third potentials and said first potential being higher than said third potential; and (c) detecting the output from said working electrode during the time period of applying said second potential.
摘要翻译: 在一个实施方案中,本发明涉及脉冲电化学检测方法,其包括(a)将包含至少一种分析物的液体样品流流过流通池中的工作电极; (b)向工作电极施加至少三个脉冲电势,(1)第一调节电位,(2)第二检测和氧化清洗电位,和(3)第三还原清洗电位,所述第二电位高于 说第一和第三个潜力,并说第一个潜力高于第三个潜力; 以及(c)在施加所述第二电位的时间段期间检测来自所述工作电极的输出。
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公开(公告)号:US20140069176A1
公开(公告)日:2014-03-13
申请号:US13611631
申请日:2012-09-12
申请人: Yan LIU , Petr JANDIK , Christopher A. POHL
发明人: Yan LIU , Petr JANDIK , Christopher A. POHL
CPC分类号: C25B9/18 , B01D15/166 , B01D15/361 , B01D61/44 , C25B1/02 , C25B1/14 , C25B3/00 , C25B13/00 , G01N30/16 , G01N30/34 , G01N30/96 , G01N2030/965 , Y02E60/34 , Y10T137/0318
摘要: A system and method to generate a concentration gradient eluent flow are described. The concentration gradient eluent flow can include at least two different generants. A liquid can be pumped to an eluent generating device. A first controlling signal can be applied to a first eluent generator to generate a first generant. A second controlling signal can be applied to a second eluent generator to generate a second generant. Either the first and/or the second controlling signal can be varied as a function of time to generate the concentration gradient eluent flow.
摘要翻译: 描述了产生浓度梯度洗脱流的系统和方法。 浓度梯度洗脱液流可以包括至少两种不同的生成剂。 液体可以泵送到洗脱液生成装置。 第一控制信号可以应用于第一洗脱液发生器以产生第一发生器。 第二控制信号可以应用于第二淋洗液发生器以产生第二发生器。 第一和/或第二控制信号可以作为时间的函数而变化以产生浓度梯度洗脱液流。
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公开(公告)号:US08342007B2
公开(公告)日:2013-01-01
申请号:US12703668
申请日:2010-02-10
申请人: Jun Cheng , Petr Jandik , Christopher A. Pohl
发明人: Jun Cheng , Petr Jandik , Christopher A. Pohl
IPC分类号: G01N30/00
CPC分类号: G01N27/30 , G01N27/301 , G01N27/4166 , G01N30/64
摘要: A detection cell for a chromatography system includes a cell body having an inlet, an outlet, and a counter electrode, a working electrode, a sample flow passageway extending between the inlet and the outlet and in fluid contact with the counter and working electrodes, and a palladium/noble metal reference electrode system. A method of using the detection cell is also described.
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公开(公告)号:US06783645B2
公开(公告)日:2004-08-31
申请号:US10081691
申请日:2002-02-20
申请人: Jun Cheng , Petr Jandik , Nebojsa Avdalovic
发明人: Jun Cheng , Petr Jandik , Nebojsa Avdalovic
IPC分类号: C25B902
CPC分类号: G01N27/307 , Y10T29/49002
摘要: A flow-through electrochemical cell assembly with a disposable working electrode structure, including (a) a perimeter wall defining a sample flow channel including an inlet and an outlet, (b) a sample inlet line in fluid communication with the sample flow channel inlet, (c) a sample outlet line providing fluid communication between the sample flow channel outlet and a remote reference electrode, and (d) a disposable working electrode structure comprising an electrically conductive and electrochemically active working electrode region bound as a layer, directly or indirectly, to an electrically insulating substrate surface. The substrate surface is in fluid-sealing relationship with the sample flow channel, and the working electrode region is in fluid communication with said sample flow channel. The working electrode is vapor deposited, directly or indirectly, onto the organic polymer substrate through a mask, and a fluid seal is formed between said working electrode region and perimeter wall.
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10.
公开(公告)号:US5366601A
公开(公告)日:1994-11-22
申请号:US963685
申请日:1992-10-20
申请人: William R. Jones , Petr Jandik
发明人: William R. Jones , Petr Jandik
IPC分类号: B01D57/02 , G01N27/447
CPC分类号: G01N27/44721
摘要: A technique for separating, identifying and measuring ions in solution by capillary zone electrophoresis is described, which provides improved sensitivity and resolution of anionic species. The method involves introducing a sample containing the ionic species into a narrow bore capillary filled with a carrier electrolyte containing a selected light-absorbing anion. An electrical potential is applied across the capillary column causing the ions to elute according to their ionic mobility. Both UV absorbing and UV-transparent ions can be detected and quantitated by UV/visible photometric monitoring.
摘要翻译: 描述了通过毛细管区带电泳分离,鉴定和测量溶液中的离子的技术,其提供阴离子物质的改进的灵敏度和分辨率。 该方法包括将含有离子物质的样品引入填充有选择的吸光阴离子的载体电解质的窄孔毛细管中。 在毛细管柱上施加电位,使离子根据其离子迁移率而洗脱。 UV /可见光度监测可以检测和定量UV吸收和UV透明离子。
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