Metal acetylacetonate latent accelerators for an epoxy-styrene resin
system
    6.
    发明授权
    Metal acetylacetonate latent accelerators for an epoxy-styrene resin system 失效
    环氧 - 苯乙烯树脂体系用金属乙酰丙酮化物潜在促进剂

    公开(公告)号:US4173593A

    公开(公告)日:1979-11-06

    申请号:US784752

    申请日:1977-04-05

    摘要: An epoxy-styrene, solventless resin impregnating varnish, having an atmospheric catalyzed pot life at room temperature of at least 45 days, is made by mixing: (1) the product of the reaction of (a) 1 part of an epoxy resin mixture, comprising solid epoxy resin and liquid epoxy resin wherein the weight ratio of solid epoxy: liquid epoxy is between 1:1 to 1:10; with (b) between about 0.01 part to 0.06 part of maleic anhydride and (c) a catalyst under such conditions that the epoxy diester formed has an acid number of between about 0.5 to 3.0; with (2) a coreactive vinyl monomer; and between about 0.0003 part to 0.004 part of a room temperature stabilizer; (3) between about 0.3 part to 1.2 part of a polycarboxylic anhydride, which is soluble in the mixture of (1) and (2), and an amount of free radical catalyst that is effective to provide a catalytic effect on the impregnating varnish and to cure it at temperatures of over about 85.degree. C., and with (4) between 0.0005 part to 0.005 part of a metal acetylacetonate, selected from the group consisting of chromium (III) acetylacetonate, manganese (III) acetylacetonate, ferric (iron III) acetylacetonate, zinc (II) acetylacetonate, aluminum (III) acetylacetonate, sodium (I) acetylacetonate, uranyl (VI) acetylacetonate, and mixtures thereof, acting as latent accelerator.

    摘要翻译: 通过混合(1)将(a)1份环氧树脂混合物的反应产物,在室温下至少45天的具有大气催化适用期的环氧 - 苯乙烯,无溶剂树脂浸渍清漆, 包括固体环氧树脂和液体环氧树脂,其中固体环氧树脂:液体环氧树脂的重量比为1:1至1:10; 其中(b)约0.01份至0.06份马来酸酐和(c)在形成的环氧二酯的酸值为约0.5至3.0的条件下的催化剂; 与(2)共聚活性乙烯基单体; 和约0.0003份至0.004份的室温稳定剂; (3)约0.3〜1.2份可溶于(1)和(2)的混合物的多元羧酸酐,以及一定量的自由基催化剂,其有效地对浸渍清漆提供催化作用, 在超过约85℃的温度下固化,和(4)在0.0005份至0.005份之间的金属乙酰丙酮化物,其选自乙酰丙酮铬(III),乙酰丙酮酸锰(III),铁(铁) III)乙酰丙酮酸锌(II),乙酰丙酮酸锌(III),乙酰丙酮铝(III),乙酰丙酮酸钠(I),乙酰丙酮铀(VI)及其混合物,用作潜在促进剂。

    Epoxides containing organo-tin compounds and electrical members
insulated therewith
    8.
    发明授权
    Epoxides containing organo-tin compounds and electrical members insulated therewith 失效
    含有有机锡化合物的环氧化物和与其绝缘的电气部件

    公开(公告)号:US4020017A

    公开(公告)日:1977-04-26

    申请号:US575755

    申请日:1975-05-08

    摘要: A resinous composition is made by: admixing (1) an organo-tin compound, having the structural formula: R.sub.1 R.sub.2 R.sub.3 SnX, where R.sub.1, R.sub.2 and R.sub.3 are organic groups, and X is a halide, hydroxide, acetate, butyrate, propionate, or dimethyl phosphate group, effective as a latent catalyst, (2) an amount of a reactive low viscosity epoxide diluent effective to dissolve the organo-tin compound without substantial heating, and (3) a cycloaliphatic epoxide or a glycidyl ester epoxide; wherein the weight ratio of cycloaliphatic epoxide or glycidyl ester epoxide: reactive epoxide diluent is between about 1:0.10 to 1:0.90, in the epoxide mixture; and about 0.00005 part to 0.0005 part by weight of organo-tin compound is used for each 1 part by weight of epoxide mixture.This resinous composition can be impregnated into a sheet material and cured to form insulation for an electrical member.

    摘要翻译: 通过以下方法制备树脂组合物:(1)具有结构式为R1R2R3SnX的有机锡化合物,其中R1,R2和R3是有机基团,X是卤化物,氢氧化物,乙酸酯,丁酸酯,丙酸酯或二甲基 磷酸盐基,有效作为潜在催化剂,(2)一定量的有效溶解有机锡化合物的反应性低粘度环氧化物稀释剂,而不需要大量加热,和(3)环脂族环氧化物或缩水甘油酯环氧化物; 其中环氧化物混合物中脂环族环氧化物或缩水甘油酯环氧化物:反应性环氧化物稀释剂的重量比为约1:0.10至1:0.90; 对于每1重量份的环氧化物混合物使用约0.00005〜0.0005重量份的有机锡化合物。