摘要:
Process for confinement of waste containing at least one chemical species to be confined, by in-can vitrification in a hot metal can into which waste and a vitrification additive are added, the waste and the vitrification additive are melted to obtain a glass melt which is then cooled, characterised in that at least one oxidising agent is also added into the metal can and in that the concentration of oxidising agent(s) expressed as oxide(s) in the glass melt is between 0.1 and 20% by mass, preferably 4 and 20% by mass, even more preferably 5 and 15% by mass, and even more preferably 10 and 13% by mass of the glass melt mass.
摘要:
Process for the production of hydrogen by the thermochemical route from water, based on the chlorine/cerium cycle, in which, according to a first reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2; (A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O; (B) 2CeCl3+4H2O=2CeO2+6HCl+H2; (C) or in which, according to a second reaction scheme, the following reactions are carried out: H2O+Cl2=2HCl+½O2; (A) 8HCl+2CeO2=2CeCl3+Cl2+4H2O; (B) 2CeCl3+2H2O=2CeOCl+4HCl; (B′) 2CeOCl+2H2O=2CeO2+2HCl+H2; (C′) and in which the reaction (B) for the chlorination of cerium oxide is carried out in the liquid phase, the cerium chloride passing into solution.
摘要:
Electromagnetic device for fusion and interfacial agitation of diphase systems, particularly for the acceleration of metallurgic or pyrochemical processes. This device comprises for example a crucible (2, 28), to contain a diphase system, an inductor (4) surrounding this crucible and means (18) for the supply of the inductor by a current with two components, namely a high frequency component which melts the phases of the system and a low frequency component which agitates the interface (12) of the phases.
摘要:
This invention relates to a process for treating fly ash produced by a waste incinerator and containing chlorides of toxic metals, which includes a step consisting of subjecting said fly ash to a phosphating reaction, at high temperature, to convert the chlorides of toxic metals into phosphates, the phosphating reaction being obtained by the addition of a reactant comprising a phosphorus compound, characterised in that said phosphorus compound is a non-metallic compound and in that the chlorinated products obtained are discharged in a gaseous form. It also relates to an installation for implementing this process.
摘要:
A process is described for the incineration and vitrification of mainly mineral waste in which at least one pure or substantially pure oxygen plasma jet is used for melting the waste, the process taking place in a metal crucible containing a tapping valve and its wall is cooled by liquids flowing in internal channels.
摘要:
A melting furnace for insulating materials is provided with a cooled crucible (10) having continuous metal side malls, a partitioned and cooled bottom (12) and at least one induction coil (28) placed under the bottom which serves as the sole heating means. The depth of the melting bath contained in the crucible and the excitation frequency of the induction coil are selected so that the depth and half of the inside radius of the crucible are less than the skin thickness of the bath.
摘要:
Furnace for the continuous melting of mixtures of oxides by direct induction at high frequency and a very short refining time and with a low energy consumption, comprising an intake (14) and a nozzle (15) for the continuous discharge of oxides into a metal crucible (3) having cold walls heated by a high frequency coil (5), characterized in that the height of the oxide bath is between 2 cm and 20% of the diameter of the metal crucible and in that the furnace hearth (4) is both transparent to the inducing magnetic field and sufficiently cooled to ensure the formation and maintenance of a protective solid crust at the bottom of the crucible.
摘要:
Process for confinement of waste containing at least one chemical species to be confined, by in-can vitrification in a hot metal can into which waste and a vitrification additive are added, the waste and the vitrification additive are melted to obtain a glass melt which is then cooled, characterised in that at least one oxidising agent is also added into the metal can and in that the concentration of oxidising agent(s) expressed as oxide(s) in the glass melt is between 0.1 and 20% by mass, preferably 4 and 20% by mass, even more preferably 5 and 15% by mass, and even more preferably 10 and 13% by mass of the glass melt mass.
摘要:
Electromagnetic device for fusion and interfacial agitation of diphase systems, particularly for the acceleration of metallurgic or pyrochemical processes, which includes for example a crucible to contain a diphase system, an inductor surrounding this crucible, and a circuit for the supply of the inductor by a current with two components, namely a high frequency component which melts the phases of the system and a low frequency component which agitates the interface of the phases.
摘要:
The mass to be vitrified undergoes a reduction operation in order to have the ruthenium pass from an oxidized state to a metal state in order to reduce the viscosity, the electric conductivity and to obtain good chemical kinetics.