摘要:
An accelerated process for the complete destruction of a matrix material, such as a matrix material including cement and/or asbestos-containing materials (ACMs), is disclosed. The process comprises forming a slurry or suspension by combining the matrix material with an acid solution (including, for instance, acid waste, which can also be neutralized by the process), causing acid-based chemical reactions in the slurry that cause the destruction of the matrix material. Simultaneously to the chemical reactions, the slurry or suspension is subjected to cavitation, which synergistically cooperates with the chemical reactions to accelerate matrix material destruction. The matrix material can be ground and polarized prior to being submerged in the acid solution to form the slurry. The slurry can be subjected to hydrothermal treatment. Inert secondary raw materials (SRMs) that are non-hazardous to the environment and human health can be obtained from the process.
摘要:
There are provided processes for treating fly ash. For example, the processes can comprise leaching fly ash with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating the solid from the leachate; reacting the leachate with HCl so as to obtain a liquid and a precipitate comprising the aluminum ions in the form of AlCl3, and separating the precipitate from the liquid; and heating the precipitate under conditions effective for converting AlCl3 into Al2O3 and optionally recovering gaseous HCl so-produced.
摘要翻译:提供了处理飞灰的方法。 例如,该方法可以包括用HCl浸出飞灰,以获得包含铝离子和固体的渗滤液,并将固体与渗滤液分离; 使渗滤液与HCl反应,以获得液体和包含AlCl 3形式的铝离子的沉淀物,并将沉淀物与液体分离; 并在有效将AlCl 3转化为Al 2 O 3的条件下加热沉淀物,并任选地回收如此生产的气态HCl。
摘要:
There are provided processes for treating fly ash. For example, the processes can comprise leaching fly ash with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating the solid from the leachate; reacting the leachate with HCl so as to obtain a liquid and a precipitate comprising the aluminum ions in the form of AlCl3, and separating the precipitate from the liquid; and heating the precipitate under conditions effective for converting AlCl3 into Al2O3 and optionally recovering gaseous HCl so-produced.
摘要翻译:提供了处理飞灰的方法。 例如,该方法可以包括用HCl浸出飞灰,以获得包含铝离子和固体的渗滤液,并将固体与渗滤液分离; 使渗滤液与HCl反应,以获得液体和包含AlCl 3形式的铝离子的沉淀物,并将沉淀物与液体分离; 并在有效将AlCl 3转化为Al 2 O 3的条件下加热沉淀物,并任选地回收如此生产的气态HCl。
摘要:
A two step process for the destruction of a precursor material using a steam plasma in a three zone reactor wherein the precursor material is hydrolyzed as a first step in the high temperature zone of the reactor, followed by a second step of medium temperature oxidation of the reactant stream in the combustion zone of the reactor where combustion oxygen or air is injected and immediate quenching of the resulting gas stream to avoid the formation of unwanted by-products. A related apparatus includes a non transferred direct current steam plasma torch, an externally cooled three zone steam plasma reactor means for introducing the precursor material into the plasma plume of the plasma torch, means for introducing the combustion air or oxygen into the combustion zone, means for exiting the reactant mixture from the reactor and means for quenching the reactant mixture located at the exit end of the reactor.
摘要:
A system for decomposing a liquid or gaseous organic compound comprises a ultraviolet decomposition unit and an intermediate product treatment apparatus. The ultraviolet decomposition unit decomposes an organic compound contained in polluted liquid or polluted gas by irradiating ultraviolet rays whose wavelength is less than 300 nm to the polluted liquid or the polluted gas containing the organic compound. An acid electrolytic water feed pipe and an alkali electrolytic water feed pipe are respectively connected to the intermediate product treatment apparatus through valves to neutralize an intermediate product, which results from decomposition of the organic compound, for decomposition by selectively adding strong alkali electrolytic water and strong acid electrolytic water to the polluted liquid or the polluted gas containing the intermediate product.
摘要:
An equipment for making PCB nontoxic comprises: a first burn furnace 10 for burning an oil containing the PCB with auxiliary fuel: a second oxidation reaction unit 12, connecting to the first burn furnace 10 under sealing, comprising a supply source of a solution of metallic phthalocyanine derivatives and a supply source of the solution of the oxygen supply compound.
摘要:
The invention relates to a method for decomposing bromate ions contained in a liquid. The method includes the sequential steps of bringing the liquid into contact with a photocatalyst; and irradiating the photocatalyst with a light ray having an energy that is not lower than that of a band gap of the photocatalyst, thereby generating a photocatalytic reaction to decompose the bromate ions. The invention further relates an apparatus for decomposing bromate ions contained in a liquid. The apparatus includes a first section for generating therein a photocatalytic reaction to decompose the bromate ions; a photocatalyst adapted to be brought into contact with the liquid in the first section; and a light source for irradiating the photocatalyst with the light ray such that the photocatalytic reaction is generated in the first section when the photocatalyst is in contact with the liquid. Thus, it is possible to efficiently and stably decompose the bromate ions. The photocatalyst may be at least one metal oxide including titanium and a metal having an electronegativity lower than that of titanium. In this case, it is possible to omit pH adjustments of the liquid before and after the photocatalytic reaction.
摘要:
Process and apparatus for decomposing halogenated aliphatic hydrocarbon compounds in the presence of functional water under light irradiation, where the target substance for decomposition contained at a low concentration in the exhaust or discharge from the decomposition unit is adsorbed by an adsorption unit, and at regular intervals, the adsorbed target substance is released from the adsorption unit and returned to the decomposition unit. The concentration of the target substance in the waste or discharge can be easily and efficiently reduced below the environmental standard.
摘要:
A method for treating residues derived from garbage and/or industrial waste incineration fumes including the steps of desalting the residues by washing with sodium carbonate in sufficient amount or slightly in excess to solubilize all the salts including the sulphates and precipitate the soluble calcium, the pH being higher than 11, then carrying out a solid/liquid separation to obtain a desalinated cake; leaching the desalinated cake with sodium carbonate in sufficient amount or slightly in excess to obtain, by reaction with the lime present in the cake or added thereto if necessary, the alkalinity required for solubilising amphoteric metals, the pH being higher than 12, and obtaining by solid/liquid separation a cake and a supernatant which is neutralised with carbon dioxide, and filtering the recovered solution to obtain metal hydroxide sludge and an aqueous sodium carbonate solution; and neutralising the resulting residues at a pH between 6.5 and 8.5.
摘要:
The invention relates to a method for decomposing bromate ions contained in a liquid. The method includes the sequential steps of bringing the liquid into contact with a photocatalyst; and irradiating the photocatalyst with a light ray having an energy that is not lower than that of a band gap of the photocatalyst, thereby generating a photocatalytic reaction to decompose the bromate ions. The invention further relates to an apparatus for decomposing bromate ions contained in a liquid. The apparatus includes a first section for generating therein a photocatalytic reaction to decompose the bromate ions; a photocatalyst adapted to be brought into contact with the liquid in the first section; and a light source for irradiating the photoacatalyst with the light ray such that the photocatalytic reaction is generated in the first section when the photocatalyst is in contact with the liquid.