公开(公告)号：US5416054A

公开(公告)日：1995-05-16

申请号：US77807

申请日：1993-02-25

Applicant: Pei-Shing E. Dai ,  Gerald V. Nelson ,  Govanon Nongbri ,  Roy E. Pratt ,  David E. Sherwood, Jr.

Inventor： Pei-Shing E. Dai ,  Gerald V. Nelson ,  Govanon Nongbri ,  Roy E. Pratt ,  David E. Sherwood, Jr.

IPC: B01J23/85 ,  B01J27/18 ,  B01J27/185 ,  B01J35/10 ,  C07B61/00 ,  C10G45/08 ,  C10G47/12 ,  C10G49/04 ,  B01J27/19 ,  B01J27/188

CPC classification number: C10G45/08 ,  B01J23/85 ,  B01J27/1853 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108

Abstract: Heavy oils may be hydrotreated in the presence of a porous alumina support bearing metals of Group VIII and VI-B and optionally phosphorus, the catalyst having a Total Surface Area of 165-230 m.sup.2 /g, a Total Pore Volume of 0.5-0.8 cc.g, and a Pore Diameter Distribution whereby less than about 5% the Total Pore Volume is present as primary micropores of diameter less than 80 .ANG., and secondary micropores of diameter of +20 .ANG. of a Pore Mode of 100-135 .ANG. are present in amount of at least about 65% of the micropore volume having pores with diameter less than 250 .ANG., and 22-29% of the Total Pore Volume is present as macropores of diameter >250 .ANG..The process of the instant invention is particularly effective in achieving desired levels of hydrodemetallation, hydrodesulfurization, and hydrocracking of asphaltenes in the fraction of hydrotreated/hydrocracked petroleum resid product having a boiling point greater than 1000.degree. F.

Abstract translation: 重油可以在带有VIII族和VI-B族金属和任选的磷的多孔氧化铝载体存在下进行加氢处理，催化剂的总表面积为165-230m2 / g，总孔体积为0.5-0.8cc g和孔径分布，其中总孔径体积小于约5％作为直径小于80的初级微孔，并且存在孔径模式为100-135的直径为+20的二次微孔 至少具有直径小于250的孔的微孔体积的至少约65％，总孔体积的22-29％作为直径大于250的大孔存在。 本发明的方法在沸点高于1000°F的加氢处理/加氢裂化石油渣产品馏分中达到希望水平的加氢脱金属，加氢脱硫和沥青质加氢裂化的水平是特别有效的。

公开(公告)号：US4725408A

公开(公告)日：1988-02-16

申请号：US884772

申请日：1986-08-19

Applicant: Roy E. Pratt ,  Scott M. Sayles ,  Kerry W. Bowers ,  Richard P. Scott, deceased

Inventor： Roy E. Pratt ,  Scott M. Sayles ,  Kerry W. Bowers ,  Richard P. Scott, deceased

IPC: C10G11/18 ,  C10G55/06 ,  B01J8/28

CPC classification number: C10G55/06 ,  C10G11/18

Abstract: Apparatus for catalytic cracking of a selected portion of a hydrocarbon feedstock comprising a riser reactor and a catalyst regenerator, a regenerated catalyst cooler, and an absorber. Regenerated catalyst from the catalyst regenerator is conducted through the catalyst cooler into the absorber where it adsorbs hydrocarbon cracking feedstock and then returned to the riser reactor. A duct carries part of the hot regenerated catalyst from the catalyst regenerator directly to the riser reactor to supply heat for cracking the hydrocarbon feedstock.

Abstract translation: 用于催化裂化选择部分烃原料的装置，其包括提升管反应器和催化剂再生器，再生催化剂冷却器和吸收器。 来自催化剂再生器的再生催化剂通过催化剂冷却器进入吸收器，吸收烃裂解原料，然后返回到提升管反应器。 管道将部分热再生催化剂从催化剂再生器直接运送到提升管反应器以提供用于裂化烃原料的热量。

公开(公告)号：US4243630A

公开(公告)日：1981-01-06

申请号：US21651

申请日：1979-03-19

Applicant: Howard C. Kliesch ,  Daniel N. McWilliams ,  Roy E. Pratt ,  Donald H. Schmude

Inventor： Howard C. Kliesch ,  Daniel N. McWilliams ,  Roy E. Pratt ,  Donald H. Schmude

IPC: C10G11/18 ,  C10G21/00 ,  G06G7/58

CPC classification number: C10G11/187 ,  Y10T436/12

Abstract: A monitor determines the yields of constituents of a product provided by a fluid catalytic cracking unit (FCCU) receiving fresh feed and recycle feed. The monitor includes sensors providing signals corresponding to sensed operating parameters of the FCCU. Analyzers analyze the fresh feed and the recycle feed and provide signals corresponding to the API gravities of the fresh and recycle feeds and to the viscosities of the fresh and recycle feeds. A circuit provides signals corresponding to the Watson K factors associated with the fresh and recycle feeds and the catalyst in accordance with the signals from the analyzers and sensors. A network provides signals representative of the yields of the constituents of the product from FCCU. Display apparatus provides a visual display of the yields.

Abstract translation: 显示器确定由接收新鲜进料和再循环进料的流化催化裂化装置（FCCU）提供的产品的成分的产率。 监视器包括提供与FCCU的感测操作参数对应的信号的传感器。 分析仪分析新鲜进料和再循环进料，并提供对应于新鲜和再循环进料的API重量以及新鲜和再循环进料的粘度的信号。 根据来自分析仪和传感器的信号，电路提供对应于与新鲜和再循环进料和催化剂相关的沃森K因子的信号。 网络提供代表FCCU产品成分的产量的信号。 显示装置提供产量的视觉显示。

公开(公告)号：US4060395A

公开(公告)日：1977-11-29

申请号：US684438

申请日：1976-05-07

Applicant: Leonce F. Castagnos, Jr. ,  Roy E. Pratt

Inventor： Leonce F. Castagnos, Jr. ,  Roy E. Pratt

IPC: B01J8/24 ,  B01D15/06

CPC classification number: B01J8/24

Abstract: Apparatus for regeneration of spent, coke contaminated fluidized cracking catalyst by burning coke therefrom with a molecular oxygen containing regeneration gas in a fluidized dense phase bed, and for burning substantially all carbon monoxide to carbon dioxide. Means are provided for transferring heat from the top of said regeneration apparatus to the bottom, employing catalyst as the transfer medium. Additionally, means are provided for maintaining a homogeneous fluidized dense phase bed of catalyst undergoing regeneration.

Abstract translation: 用于通过在流化密相床中用含分子氧的再生气体燃烧焦炭并将基本上所有一氧化碳燃烧成二氧化碳来再生废焦化污染的流化裂化催化剂的装置。 提供了用于将热量从所述再生装置的顶部传递到底部的装置，使用催化剂作为转印介质。 此外，提供了用于维持经历再生的催化剂的均匀流化密相床的装置。

公开(公告)号：US3966587A

公开(公告)日：1976-06-29

申请号：US535408

申请日：1974-12-23

Applicant: Joel S. Bittensky ,  Edward W. Dillingham ,  William R. Menzies, III ,  Roy E. Pratt

Inventor： Joel S. Bittensky ,  Edward W. Dillingham ,  William R. Menzies, III ,  Roy E. Pratt

IPC: C10G11/18 ,  C10G13/18

CPC classification number: C10G11/182 ,  Y02P30/446

Abstract: An improved method is disclosed for controlling the temperature of the fluidized dense catalyst phase of the regeneration zone in a fluid catalytic cracking unit, wherein the coke laydown in the reaction zone is at a level such that the coke concentration of the partially deactivated catalyst from the reaction zone is not sufficient to provide the heat required to maintain the controlled temperature in the fluidized dense catalyst phase of the regeneration zone. In this method, torch oil is added to the partially deactivated catalyst in the spent catalyst transfer line in an amount such that the catalyst charged to the regeneration zone contains sufficient combustible material to provide the heat necessary to maintain the fluidized dense catalyst phase of the regeneration zone at the controlled temperature. Also, as a part of this improved method, the flow of oxygen-containing regeneration gas to the regeneration zone is regulated to provide sufficient oxygen to effect substantially complete combustion of the coke and torch oil to carbon dioxide and to provide an oxygen concentration in the regeneration flue gas within the range of from about 1 to about 10 mol%. Maintaining the oxygen concentration in the flue gas within this range results in a flue gas having a carbon monoxide content of about 500 ppm, or less, and preferably 10 ppm or less.

Abstract translation: 公开了一种用于在流化催化裂化装置中控制再生区的流化致密催化剂相的温度的改进方法，其中反应区中的焦炭沉积处于使部分失活的催化剂的焦炭浓度从 反应区不足以提供在再生区的流化致密催化剂相中维持受控温度所需的热量。 在该方法中，在废催化剂输送管线中将炬油加入到部分失活的催化剂中，其量使得装入再生区的催化剂含有足够的可燃材料，以提供维持再生的流化致密催化剂相所需的热量 区域在受控温度。 此外，作为该改进方法的一部分，调节到再生区的含氧再生气体的流动以提供足够的氧气，以使焦炭和炬油基本上完全燃烧成二氧化碳，并且在 再生烟气在约1至约10mol％的范围内。 将烟气中的氧浓度维持在该范围内，导致一氧化碳含量为约500ppm以下，优选为10ppm以下的烟道气。

公开(公告)号：US4388176A

公开(公告)日：1983-06-14

申请号：US323097

申请日：1981-11-19

Applicant: Roy E. Pratt ,  Scott M. Sayles ,  Kerry W. Bowers ,  Richard P. Scott, deceased

Inventor： Roy E. Pratt ,  Scott M. Sayles ,  Kerry W. Bowers ,  Richard P. Scott, deceased

IPC: C10G25/03 ,  C10G69/04 ,  C10G11/05 ,  C10G51/06 ,  C10G55/08

CPC classification number: C10G69/04 ,  C10G25/03

Abstract: A process for conversion of paraffinic base petroleum cracking stocks to high octane motor fuels and petrochemical feedstocks in which paraffinic components are separated from the cracking stock to yield a deparaffined fraction which is hydrotreated and catalytically cracked and a paraffin fraction which is separately catalytically cracked whereby improved yields of normally gaseous olefins and normally liquid products including high octane motor fuel components are obtained.

Abstract translation: 将石蜡基石油裂解原料转化为高辛烷值汽油和石油化工原料的方法，其中将链烷烃组分与裂化原料分离，得到加氢处理和催化裂化的脱硫馏分，以及单独催化裂化的链烷烃馏分，从而改进 获得通常为气态烯烃和通常为液体产物（包括高辛烷值汽油燃料组分）的产率。

公开(公告)号：US4324688A

公开(公告)日：1982-04-13

申请号：US142582

申请日：1980-04-21

Applicant: Leonce F. Castagnos, Jr. ,  William R. Menzies, III ,  Roy E. Pratt

Inventor： Leonce F. Castagnos, Jr. ,  William R. Menzies, III ,  Roy E. Pratt

IPC: B01J8/24 ,  B01J8/26 ,  C10G11/18 ,  B01J29/38 ,  B01J21/20 ,  C10G11/04 ,  C10G11/05

CPC classification number: B01J8/24 ,  B01J8/26 ,  C10G11/182 ,  Y02P30/446

Abstract: A process for the regeneration of coke-contaminated fluidizable catalytic cracking catalyst wherein the regeneration flue gas having a reduced concentration of carbon monoxide and regenerated catalyst having a reduced residual carbon content are obtained. By this method a fluidized dense catalyst phase of coke-contaminated catalyst is regenerated with an excess amount of oxygen-containing regeneration gas at an elevated temperature such that there is a controlled afterburn of carbon monoxide to carbon dioxide in the dilute catalyst phase whereby a flue gas having a carbon monoxide content of from 0 to 500 ppm is obtained. The residence time of catalyst in the fluidized dense catalyst phase is adjusted to provide a low level of residual carbon-on-regenerated-catalyst.

Abstract translation: 一种焦炭污染的可流化催化裂化催化剂的再生方法，其中获得具有降低的一氧化碳浓度的再生烟气和具有降低的残余碳含量的再生催化剂。 通过这种方法，在高温下用过量的含氧再生气体再生焦炭污染的催化剂的流化致密催化剂相，使得在稀催化剂相中存在一氧化碳对二氧化碳的有害燃烧，由此烟道 得到一氧化碳含量为0〜500ppm的气体。 调节催化剂在流化致密催化剂相中的停留时间以提供低水平的残留碳再生催化剂。

公开(公告)号：US4062759A

公开(公告)日：1977-12-13

申请号：US684338

申请日：1976-05-07

Applicant: Leonce F. Castagnos, Jr. ,  Roy E. Pratt

Inventor： Leonce F. Castagnos, Jr. ,  Roy E. Pratt

IPC: C10G11/18 ,  C10G13/02 ,  B01J8/24

CPC classification number: C10G11/182 ,  Y02P30/446

Abstract: A process is described herein for regeneration of spent, coke contaminated fluidized cracking catalyst by burning coke therefrom with a molecular oxygen containing regeneration gas in a fluidized dense phase bed, and for burning substantially all carbon monoxide formed to carbon dioxide. A method is provided for establishing a homogeneous dense phase fluidized bed of catalyst undergoing regeneration. Additionally, a method is provided for transferring heat from a dilute phase back to the fluidized dense phase catalyst bed.

Abstract translation: 本文描述了一种用于通过在流化密相床中用含分子氧的再生气体从其中燃烧焦炭并且将形成的二氧化碳基本上燃烧的所有一氧化碳燃烧的废焦炭污染的流化裂化催化剂再生的方法。 提供了一种用于建立经历再生的催化剂的均相稠相流化床的方法。 此外，提供了一种将热从稀相转移回到流化密相催化剂床的方法。

公开(公告)号：US5399259A

公开(公告)日：1995-03-21

申请号：US870970

申请日：1992-04-20

Applicant: Pei-Shing E. Dai ,  Gerald V. Nelson ,  Govanon Nongbri ,  Roy E. Pratt ,  David E. Sherwood, Jr.

Inventor： Pei-Shing E. Dai ,  Gerald V. Nelson ,  Govanon Nongbri ,  Roy E. Pratt ,  David E. Sherwood, Jr.

IPC: B01J23/85 ,  B01J27/18 ,  B01J27/185 ,  B01J35/10 ,  C07B61/00 ,  C10G45/08 ,  C10G47/12 ,  C10G49/04 ,  C01G45/04 ,  C01G47/12

CPC classification number: C10G45/08 ,  B01J23/85 ,  B01J27/1853 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108

Abstract: Heavy oils may be hydrotreated in the presence of a porous alumina support bearing metals of Group VIII and VI-B and optionally phosphorus, the catalyst having a Total Surface Area of 165-230 m.sup.2 /g, a Total Pore Volume of 0.5-0.8 cc.g, and a Pore Diameter Distribution whereby less than about 5% of the Total Pore Volume is present as primary micropores of diameter less than 80.ANG., and secondary micropores of diameter of .+-.20.ANG. of a Pore Mode of 100-135.ANG. are present in amount of at least about 65% of the micropore volume having pores with diameter less than 250.ANG., and 22-29% of the Total Pore Volume is present as macropores of diameter >250.ANG.. The process of the instant invention is particularly effective in achieving desired levels of hydrodemetallation, hydrodesulfurization, and hydrocracking of asphaltenes in the fraction of hydrotreated/hydrocracked petroleum resid product having a boiling point greater than 1000.degree. F.

Abstract translation: 重油可以在带有VIII族和VI-B族金属和任选的磷的多孔氧化铝载体存在下进行加氢处理，催化剂的总表面积为165-230m2 / g，总孔体积为0.5-0.8cc 孔和直径分布，其中小于总孔体积的约5％作为直径小于80的初级微孔存在，孔径模式的直径为+/- 20的第二微孔为100-135 ANGSTROM以直径小于250的孔的微孔体积的至少约65％的量存在，并且总孔体积的22-29％作为直径大于250的大孔存在。 本发明的方法在沸点高于1000°F的加氢处理/加氢裂化石油渣产品馏分中达到希望水平的加氢脱金属，加氢脱硫和沥青质加氢裂化的水平是特别有效的。

公开(公告)号：US5395512A

公开(公告)日：1995-03-07

申请号：US60634

申请日：1993-05-14

Applicant: Hsu-Hui Hsing ,  Roy E. Pratt ,  Chih-Hao M. Tsang ,  Chi-Lin O'Young

Inventor： Hsu-Hui Hsing ,  Roy E. Pratt ,  Chih-Hao M. Tsang ,  Chi-Lin O'Young

IPC: B01J29/70 ,  B01J29/80 ,  C10G11/05 ,  B01J29/06

CPC classification number: B01J29/80 ,  C10G11/05 ,  B01J29/70 ,  B01J29/7003

Abstract: A hydrocarbon feedstock is catalytically cracked at an elevated temperature in a cracking zone with a zeolite cracking catalyst. The cracking catalyst employed comprises a crystalline aluminosilicate zeolite catalyst and a hybrid [Al,B]-zeolite catalyst. In this process the hydrocarbon feedstock is contacted with the zeolite catalyst in, for example, a fluidized bed catalytic cracking unit to yield cracked products containing increased amounts of C.sub.3 /C.sub.8 olefins.

Abstract translation: 在具有沸石裂化催化剂的裂化区中，烃原料在高温下被催化裂化。 所用的裂化催化剂包括结晶硅铝酸盐沸石催化剂和混合[Al，B] - 沸石催化剂。 在该方法中，烃原料与例如流化床催化裂化装置中的沸石催化剂接触，产生含有增加量的C3 / C8烯烃的裂化产物。