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    Nanoporous polymeric foam having high cell density without nanofiller
    1.
    发明授权
    Nanoporous polymeric foam having high cell density without nanofiller 有权
    具有高电池密度的纳米聚合物泡沫，无纳米填料

    公开(公告)号：US09187611B2

    公开(公告)日：2015-11-17

    申请号：US13578092

    申请日：2011-02-23

    申请人： Stephane Costeux ,  Lingbo Zhu ,  Hyun Jeon ,  Shana P. Bunker ,  Thomas H. Kalantar

    发明人： Stephane Costeux ,  Lingbo Zhu ,  Hyun Jeon ,  Shana P. Bunker ,  Thomas H. Kalantar

    IPC分类号： C08J9/12 ,  C08J9/00

    CPC分类号： C08J9/122 ,  C08J9/0071 ,  C08J2201/024 ,  C08J2201/032 ,  C08J2205/046 ,  C08J2333/10

    摘要： A polymeric foam has a thermoplastic polymer matrix defining multiple cells, the foam characterized by: (a) the polymer matrix having greater than 50 weight-percent copolymer containing at least two different monomers at least one of which is a methacrylate monomer, each monomer having a solubility parameter lower than 20 (megaPascals)0.5 and a chemical composition where twice the mass fraction of oxygen plus the mass fraction of nitrogen, fluorine and silicon is greater than 0.2; wherein the monomers comprise at least 90 weight-percent of all monomers in the copolymer; (b) at least one of the following: (i) a nucleation site density of at least 3×1014 effective nucleation sites per cubic centimeter of foamable polymer composition; (ii) an average cell size of 300 nanometer or less; (c) a porosity percentage greater than 30%; (d) an absence of nano-sized nucleating additive; and (e) a thickness of at least one millimeter.

    摘要翻译： 聚合物泡沫具有限定多个细胞的热塑性聚合物基质，泡沫的特征在于：（a）聚合物基质具有大于50重量％的共聚物，其含有至少两个不同的单体，其中至少一个是甲基丙烯酸酯单体，每个单体具有 溶解度参数低于20（兆帕）和化学组成，其中氧质量分数加上氮，氟和硅质量分数的两倍大于0.2; 其中所述单体包含所述共聚物中所有单体的至少90重量％ （b）以下至少之一：（i）成核位点密度为每立方厘米可发泡聚合物组合物至少3×1014个有效成核位点; （ii）平均泡孔尺寸为300纳米以下; （c）孔隙率大于30％; （d）不存在纳米尺寸的成核添加剂; 和（e）至少一毫米的厚度。

    NANOPOROUS POLYMERIC FOAM HAVING HIGH CELL DENSITY WITHOUT NANOFILLER
    2.
    发明申请
    NANOPOROUS POLYMERIC FOAM HAVING HIGH CELL DENSITY WITHOUT NANOFILLER 有权
    具有无纳米纤维素的高密度聚合物的纳米聚合物泡沫

    公开(公告)号：US20120321873A1

    公开(公告)日：2012-12-20

    申请号：US13578092

    申请日：2011-02-23

    申请人： Stephane Costeux ,  Lingbo Zhu ,  Hyun Jeon ,  Shana P. Bunker ,  Thomas H. Kalantar

    发明人： Stephane Costeux ,  Lingbo Zhu ,  Hyun Jeon ,  Shana P. Bunker ,  Thomas H. Kalantar

    IPC分类号： C08J9/02 ,  B29C44/08 ,  B29C47/00

    CPC分类号： C08J9/122 ,  C08J9/0071 ,  C08J2201/024 ,  C08J2201/032 ,  C08J2205/046 ,  C08J2333/10

    摘要： A polymeric foam has a thermoplastic polymer matrix defining multiple cells, the foam characterized by: (a) the polymer matrix having greater than 50 weight-percent copolymer containing at least two different monomers at least one of which is a methacrylate monomer, each monomer having a solubility parameter lower than 20 (megaPascals)0.5 and a chemical composition where twice the mass fraction of oxygen plus the mass fraction of nitrogen, fluorine and silicon is greater than 0.2; wherein the monomers comprise at least 90 weight-percent of all monomers in the copolymer; (b) at least one of the following: (i) a nucleation site density of at least 3×1014 effective nucleation sites per cubic centimeter of foamable polymer composition; (ii) an average cell size of 300 nanometer or less; (c) a porosity percentage greater than 30%; (d) an absence of nano-sized nucleating additive; and (e) a thickness of at least one millimeter.

    摘要翻译： 聚合物泡沫具有限定多个细胞的热塑性聚合物基质，泡沫的特征在于：（a）聚合物基质具有大于50重量％的共聚物，其含有至少两个不同的单体，其中至少一个是甲基丙烯酸酯单体，每个单体具有 溶解度参数低于20（兆帕）和化学组成，其中氧质量分数加上氮，氟和硅质量分数的两倍大于0.2; 其中所述单体包含所述共聚物中所有单体的至少90重量％ （b）以下至少之一：（i）成核位点密度为每立方厘米可发泡聚合物组合物至少3×1014个有效成核位点; （ii）平均泡孔尺寸为300纳米以下; （c）孔隙率大于30％; （d）不存在纳米尺寸的成核添加剂; 和（e）至少一毫米的厚度。

    POLYMERIC NANOFOAM
    8.
    发明申请
    POLYMERIC NANOFOAM 审中-公开
    聚合纳米粉体

    公开(公告)号：US20140200283A1

    公开(公告)日：2014-07-17

    申请号：US14238746

    申请日：2012-09-14

    申请人： Stéphane Costeux ,  Shana P. Bunker ,  Hyun K. Jeon ,  Prasanna K. Jog

    发明人： Stéphane Costeux ,  Shana P. Bunker ,  Hyun K. Jeon ,  Prasanna K. Jog

    IPC分类号： C08L33/20 ,  C08L33/10

    CPC分类号： C08L33/20 ,  B32B5/32 ,  C08J9/0061 ,  C08J9/122 ,  C08J2203/06 ,  C08J2333/06 ,  C08J2425/12 ,  C08J2455/02 ,  C08L33/10

    摘要： A polymeric nanofoam has a continuous polymer phase containing at least one (meth)acrylic-free acrylonitrile-containing copolymer and at least one (meth)acrylic polymer where the concentration of (meth)acrylic polymer is in a range of 5-90 weight-percent of the total continuous polymer phase while the amount of methacrylic copolymer is 50 weight-percent or less of the total continuous polymer phase; the polymeric foam having a porosity of at least 50%, an absence of nano-sized nucleating additives and at least one of the following: (a) a number average cell size of 500 nanometers or less; and (b) an effective nucleation site density of at least 1×1014 sites per cubic centimeter of prefoamed material. The total weight of copolymerized acrylonitrile is in a range of 3-28 weight-percent based on total continuous polymer phase weight. At least one (meth)acrylic-free acrylonitrile-containing copolymer has a higher glass transition temperature than all of the (meth)acrylic polymers.

    摘要翻译： 聚合物纳米纤维具有包含至少一种（甲基）丙烯酸 - 丙烯腈共聚物和至少一种（甲基）丙烯酸类聚合物的连续聚合物相，其中（甲基）丙烯酸聚合物的浓度在5-90重量％ 的总连续聚合物相的百分比，而甲基丙烯酸共聚物的量为总连续聚合物相的50重量％或更少; 所述聚合物泡沫具有至少50％的孔隙率，不存在纳米尺寸的成核添加剂和以下至少一种：（a）500纳米或更小的数均孔数; 和（b）有效成核位点密度为每立方厘米预发泡材料至少1×1014个位点。 基于总连续聚合物相重量，共聚丙烯腈的总重量在3-28重量％的范围内。 至少一种（甲基）丙烯酸 - 含丙烯腈的共聚物具有比所有（甲基）丙烯酸聚合物更高的玻璃化转变温度。

    Pressure sensitive adhesives from plant oils
    9.
    发明授权
    Pressure sensitive adhesives from plant oils 失效
    来自植物油的压敏粘合剂

    公开(公告)号：US06646033B2

    公开(公告)日：2003-11-11

    申请号：US10163220

    申请日：2002-06-05

    申请人： Richard P. Wool ,  Shana P. Bunker

    发明人： Richard P. Wool ,  Shana P. Bunker

    IPC分类号： C08K542

    CPC分类号： C08K5/0008 ,  C08L33/06

    摘要： A Pressure Sensitive Adhesive composition having low volatile organics content and low odor that is suitable for forming pressure sensitive adhesives containing an aqueous dispersion containing a blended mixture of: (a) a polymer obtained by the polymerization of (i) an internally plasticizing and cross-linkable long chain methyl ester having at least one double bond in said methyl ester chain; and (ii) one or more unsaturated monomers copolymerizable therewith; and (b) a surface-active agent.

    摘要翻译： 一种具有低挥发性有机物含量和低气味的压敏粘合剂组合物，其适用于形成含有含有以下混合混合物的混合混合物的水分散体的压敏粘合剂：（a）通过聚合获得的聚合反应获得的聚合反应（i）内部增塑和交联， 在所述甲基酯链中具有至少一个双键的可连接的长链甲基酯; 和（ii）可与其共聚的一种或多种不饱和单体; 和（b）表面活性剂。