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公开(公告)号：US09255318B2
公开(公告)日：2016-02-09
申请号：US13380371
申请日：2010-06-25
申请人： Yoshihiko Ono , Kenji Takahashi , Kaneharu Okuda , Shoichiro Taira , Michitaka Sakurai , Yusuke Fushiwaki
发明人： Yoshihiko Ono , Kenji Takahashi , Kaneharu Okuda , Shoichiro Taira , Michitaka Sakurai , Yusuke Fushiwaki
IPC分类号： C22C38/04 , C23C2/02 , C21D9/46 , C22C38/00 , C22C38/02 , C22C38/06 , C22C38/22 , C22C38/32 , C22C38/38 , C23C2/06 , C23C2/28
CPC分类号： C23C2/02 , C21D9/46 , C22C38/001 , C22C38/02 , C22C38/04 , C22C38/06 , C22C38/22 , C22C38/32 , C22C38/38 , C23C2/06 , C23C2/28
摘要： A high-strength galvanized steel sheet has a low YP, good stretch flangeability, and excellent corrosion resistance and contains, on a percent by mass basis, more than 0.015% to less than 0.10% of C, 0.5% or less of Si, 1.0% to 1.9% of Mn, 0.015% to 0.050% of P, 0.03% or less of S, 0.01% to 0.5% of sol. Al, 0.005% or less of N, less than 0.40% of Cr, 0.005% or less of B, less than 0.15% of Mo, 0.4% or less of V, and less than 0.020% of Ti, in which 2.2≦[Mneq]≦3.1 and [% Mn]+3.3[% Mo]≦1.9, and [% Mn]+3.3[% Mo])/(1.3[% Cr]+8[% P]+150B*)
摘要翻译： 高强度镀锌钢板具有低YP，良好的拉伸凸缘性和优异的耐腐蚀性，并且以质量％计含有C：0.015以上且小于0.10％的C，0.5％以下的Si，1.0 Mn的1.9％以下，P：0.015〜0.050％，S：0.03％以下，溶胶的0.01〜0.5％。 Al，0.005％以下的N，小于0.40％的Cr，0.005％以下的B，小于0.15％的Mo，0.4％以下的V和小于0.020％的Ti，其中2.2和nlE; [Mneq]＆nlE; 3.1和[％Mn] +3.3 [％Mo]＆nlE; 1.9和[％Mn] +3.3 [％Mo]）/（1.3 [％Cr] +8 [％P] + 150B * <3.5满意。
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公开(公告)号：US08815349B2
公开(公告)日：2014-08-26
申请号：US13208939
申请日：2011-08-12
申请人： Shoichiro Taira , Yoshiharu Sugimoto , Yoichi Miyakawa , Akira Gamou , Masayasu Nagoshi , Takashi Kawano
发明人： Shoichiro Taira , Yoshiharu Sugimoto , Yoichi Miyakawa , Akira Gamou , Masayasu Nagoshi , Takashi Kawano
CPC分类号： C23C2/26 , C23C2/06 , C23C2/28 , C23C22/08 , C23C22/50 , C23C22/53 , C23C22/78 , C23C22/82 , C23C22/83 , Y10T428/12611 , Y10T428/12618 , Y10T428/1266 , Y10T428/12799
摘要： The invention provides a hot dip galvanized steel sheet which has: a hot dip galvanizing layer having a flat part on a surface thereof; and a film formed on the flat part. The film is composed of a compound containing Zn, Fe, and O, having an average film thickness A in a range from 10 to 100 nm determined by an element analysis of the film, and has {[Fe]/([Zn]+[Fe])} in the film in a range from 0.002 to 0.25, where [Zn] and [Fe] designate the content (% by atom) of Zn and Fe in the film, respectively. Since the hot dip galvanized steel sheet of the invention has excellent press-formability, bondability, and phosphatability, it is suitable for automobiles and electrical appliances.
摘要翻译： 本发明提供一种热浸镀锌钢板，其具有：在其表面上具有平坦部分的热浸镀锌层; 以及形成在平坦部分上的膜。 该膜由含有Zn，Fe和O的化合物组成，其具有通过膜的元素分析确定的平均膜厚度A在10至100nm的范围内，并且具有{[Fe] /（[Zn] [Fe]）}在0.002〜0.25的范围内，其中[Zn]和[Fe]分别表示膜中Zn和Fe的含量（％原子）。 由于本发明的热浸镀锌钢板具有优异的压制成形性，粘合性和磷化性，因此适用于汽车和电器。
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公开(公告)号：US20120301709A1
公开(公告)日：2012-11-29
申请号：US13570994
申请日：2012-08-09
申请人： Hiroyuki MASUOKA , Shoichiro TAIRA , Yoshiharu SUGIMOTO , Naoto YOSHIMI , Masayasu NAGOSHI , Wataru TANIMOTO
发明人： Hiroyuki MASUOKA , Shoichiro TAIRA , Yoshiharu SUGIMOTO , Naoto YOSHIMI , Masayasu NAGOSHI , Wataru TANIMOTO
CPC分类号： C23C2/06 , C23C2/26 , C23C2/28 , C23C2/40 , C23C22/08 , C23C22/53 , Y10T428/12792 , Y10T428/12799 , Y10T428/26 , Y10T428/265
摘要： A hot dip galvannealed steel sheet, which is a plated steel sheet, the plated sheet including an oxide layer being formed on the surface of the plated steel sheet, having an average thickness of 10 nm or more, and containing Zn and at least one element selected from the group consisting of Zr, Ti and Sn.
摘要翻译： 作为电镀钢板的热浸镀锌合金化热镀锌钢板，镀覆板包括在镀覆钢板的表面上形成的氧化物层，其平均厚度为10nm以上，并含有Zn和至少一种元素 选自Zr，Ti和Sn组成的组。
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4.发明授权Method of manufacturing hot dip galvannealed steel sheet and hot dip galvannealed steel sheet 有权热浸合金化热镀锌钢板和热浸合金化热镀锌钢板的制造方法公开(公告)号：US08268095B2
公开(公告)日：2012-09-18
申请号：US12226168
申请日：2007-04-26
申请人： Hiroyuki Masuoka , Shoichiro Taira , Yoshiharu Sugimoto , Naoto Yoshimi , Masayasu Nagoshi , Wataru Tanimoto
发明人： Hiroyuki Masuoka , Shoichiro Taira , Yoshiharu Sugimoto , Naoto Yoshimi , Masayasu Nagoshi , Wataru Tanimoto
CPC分类号： C23C2/06 , C23C2/26 , C23C2/28 , C23C2/40 , C23C22/08 , C23C22/53 , Y10T428/12792 , Y10T428/12799 , Y10T428/26 , Y10T428/265
摘要： A method of manufacturing a hot dip galvannealed steel sheet, including the steps of: subjecting a steel sheet to hot dip galvanizing to manufacture a hot dip galvanized steel sheet; heating the hot dip galvanized steel sheet for alloying; subjecting the hot dip galvanized steel sheet to temper rolling; bringing the temper-rolled hot dip galvanized steel sheet into contact with an acid solution containing at least one ion selected from the group consisting of Zr ions, Ti ions, and Sn ions to thereby form an acid solution film on the surface of the steel sheet; after completion of the contact, a state where the acid solution film is formed on the surface of the steel sheet is held for at least 1 second; and washing with water the hot dip galvanized steel sheet after holding, to thereby form a Zn oxide layer having a thickness of 10 nm or more on the surface of the galvanized steel sheet. The hot dip galvannealed steel sheet has an oxide layer having an average thickness of 10 nm or more on the surface of the plated steel sheet.
摘要翻译： 一种制造热浸镀锌钢板的方法，包括以下步骤：对钢板进行热浸镀锌以制造热浸镀锌钢板; 加热热镀锌钢板进行合金化; 对热浸镀锌钢板进行回火轧制; 使回火热浸镀锌钢板与含有选自Zr离子，Ti离子和Sn离子中的至少一种离子的酸溶液接触，从而在钢板表面形成酸溶液膜 ; 接触完成后，在钢板表面形成酸溶液膜的状态保持至少1秒钟; 并在保持之后用水洗涤热浸镀锌钢板，从而在镀锌钢板的表面上形成厚度为10nm以上的Zn氧化物层。 热镀锌合金化热镀锌钢板在镀覆钢板的表面上具有平均厚度为10nm以上的氧化物层。
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5.发明授权公开(公告)号：US07338718B2
公开(公告)日：2008-03-04
申请号：US10521474
申请日：2003-10-17
申请人： Shoichiro Taira , Masaki Tada , Yoshiharu Sugimoto , Masayasu Nagoshi , Takashi Kawano , Etsuo Hamada , Satoru Ando , Shinji Ootsuka , Masaaki Yamashita
发明人： Shoichiro Taira , Masaki Tada , Yoshiharu Sugimoto , Masayasu Nagoshi , Takashi Kawano , Etsuo Hamada , Satoru Ando , Shinji Ootsuka , Masaaki Yamashita
CPC分类号： C23C2/06 , C23C2/26 , C23C22/53 , C23C22/78 , Y10T428/12549 , Y10T428/12611 , Y10T428/12618 , Y10T428/12799 , Y10T428/12993
摘要： A hot-dip galvanized steel sheet includes a plating layer substantially composed of the η phase and an oxide layer disposed on a surface of the plating layer. The oxide layer has an average thickness of 10 nm or more and includes a Zn-based oxide layer and an Al-based oxide layer. A method for producing the hot-dip galvanized steel sheet includes a hot-dip galvanization step, a temper rolling step, and an oxidation step.
摘要翻译： 热镀锌钢板包括基本上由eta相组成的镀层和设置在镀层表面上的氧化物层。 氧化物层的平均厚度为10nm以上，并且包含Zn基氧化物层和Al系氧化物层。 热镀锌钢板的制造方法包括热浸镀锌工序，回火轧制工序和氧化工序。
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6.发明申请公开(公告)号：US20050139291A1
公开(公告)日：2005-06-30
申请号：US10521474
申请日：2003-10-17
申请人： Shoichiro Taira , Masaki Tada , Yoshiharu Sugimoto , Masayasu Nagoshi , Takashi Kawano , Etsuo Hamada , Satoru Ando , Shinji Ootsuka , Masaaki Yamashita
发明人： Shoichiro Taira , Masaki Tada , Yoshiharu Sugimoto , Masayasu Nagoshi , Takashi Kawano , Etsuo Hamada , Satoru Ando , Shinji Ootsuka , Masaaki Yamashita
CPC分类号： C23C2/06 , C23C2/26 , C23C22/53 , C23C22/78 , Y10T428/12549 , Y10T428/12611 , Y10T428/12618 , Y10T428/12799 , Y10T428/12993
摘要： A hot-dip galvanized steel sheet includes a plating layer substantially composed of the η phase and an oxide layer disposed on a surface of the plating layer. The oxide layer has an average thickness of 10 nm or more and includes a Zn-based oxide layer and an Al-based oxide layer. A method for producing the hot-dip galvanized steel sheet includes a hot-dip galvanization step, a temper rolling step, and an oxidation step.
摘要翻译： 热镀锌钢板包括基本上由eta相组成的镀层和设置在镀层表面上的氧化物层。 氧化物层的平均厚度为10nm以上，并且包含Zn基氧化物层和Al系氧化物层。 热镀锌钢板的制造方法包括热浸镀锌工序，回火轧制工序和氧化工序。
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公开(公告)号：US20120037281A1
公开(公告)日：2012-02-16
申请号：US13147304
申请日：2010-02-02
CPC分类号： C23C2/40 , C21D6/00 , C21D9/46 , C21D2211/005 , C21D2211/008 , C22C38/001 , C22C38/002 , C22C38/02 , C22C38/04 , C22C38/06 , C22C38/12 , C22C38/14 , C22C38/18 , C22C38/22 , C22C38/28 , C22C38/32 , C23C2/02 , C23C2/06 , C23C2/28 , Y10T428/12799 , Y10T428/12972
摘要： The high strength galvanized steel sheet contains C: more than 0.015% and lower than 0.100%, Si: 0.3% or lower, Mn: lower than 1.90%, P: 0.015% or more and 0.05% or lower, S: 0.03% or lower, sol.Al: 0.01% or more and 0.5% or lower, N: 0.005% or lower, Cr: lower than 0.30%, B: 0.0003% or more and 0.005% or lower, and Ti: lower than 0.014% in terms of mass %, and satisfies 2.2≦[Mneq]≦3.1 and 0.42≦8[% P]+150B*≦0.73. The steel microstructure contains ferrite and a second phase, in which the second phase area ratio is 3 to 15%, the ratio of the area ratio of martensite and retained γ to the second phase area ratio is more than 70%, and 50% or more of the area ratio of the second phase exists in the grain boundary triple point.
摘要翻译： 高强度镀锌钢板含有C：大于0.015％且低于0.100％，Si：0.3％以下，Mn：低于1.90％，P：0.015％以上0.05％以下，S：0.03％以下 较低，sol.Al：0.01％以上且0.5％以下，N：0.005％以下，Cr：0.30以下，B：0.0003％以上且0.005％以下，Ti：低于0.014％ 质量％，满足2.2＆nlE; [Mneq]＆nlE; 3.1和0.42＆nlE; 8 [％P] + 150B *＆nlE; 0.73。 钢微结构含有铁素体和第二相，其中第二相面积比为3〜15％，马氏体与残留γ的面积比与第二相面积比的比例为70％以上，50％以下 在晶界三点存在更多的第二相面积比。
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公开(公告)号：US20070122554A1
公开(公告)日：2007-05-31
申请号：US10575054
申请日：2004-12-16
申请人： Hiroshi Matsuda , Shoichiro Taira , Keisuke Ono , Toshiaki Urabe , Yasunobu Nagataki , Yasushi Tanaka , Michitaka Sakurai , Yoshiharu Sugimoto
发明人： Hiroshi Matsuda , Shoichiro Taira , Keisuke Ono , Toshiaki Urabe , Yasunobu Nagataki , Yasushi Tanaka , Michitaka Sakurai , Yoshiharu Sugimoto
IPC分类号： B05D3/02
CPC分类号： C22C38/18 , B32B15/013 , C22C38/002 , C22C38/02 , C22C38/04 , C22C38/06 , C22C38/12 , C22C38/14 , C22C38/38 , C23C2/06 , C23C2/28
摘要： A galvannealed steel sheet is manufactured by preparing a hot-dip galvanized steel sheet, alloying the steel sheet, and controlling time and temperature for alloying thereof depending on Si and Al contents. The hot-dip galvanized steel sheet contains 0.05 to 0.30% C, 0.01 to 2.0% Si, 0.08 to 3.0% Mn, 0.003 to 0.1% P, 0 to 0.07% S, 0.01 to 2.5% Al, 0 to 0.007% N, by mass, and the balance being Fe and inevitable impurities. Alloying time and temperature are controlled by the formula [Si+Al≧1.5×10−7×t0.75×(T−465)3+0.117], where t is the total time (sec) of holding the sheet at 465° C. or more on alloying the coating layer thereon, and T is the average temperature (° C.) of the sheet during the total time t (sec) of holding the steel sheet at 465° C. or more on alloying the coating layer thereon.
摘要翻译： 通过制备合金化钢板的热镀锌钢板，根据Si和Al含量控制其合金化的时间和温度来制造合金化热浸镀锌钢板。 该热镀锌钢板含有0.05〜0.30％的C，0.01〜2.0％的Si，0.08〜3.0％的Mn，0.003〜0.1％的P，0〜0.07％的S，0.01〜2.5％的Al，0〜0.007％的N， ，余量为Fe和不可避免的杂质。 合金时间和温度由公式[Si + Al> = 1.5×10 -7 -7×0.75×（T-465）3 + 0.117]，其中t是在465℃或更高的时间将片材保持在其上的涂层上的总时间（秒），T是在总时间t内的片材的平均温度（℃）（℃） 秒），使钢板在其上合金化时为465℃以上。
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公开(公告)号：US20120118439A1
公开(公告)日：2012-05-17
申请号：US13380371
申请日：2010-06-25
申请人： Yoshihiko Ono , Kenji Takahashi , Kaneharu Okuda , Shoichiro Taira , Michitaka Sakurai , Yusuke Fushiwaki
发明人： Yoshihiko Ono , Kenji Takahashi , Kaneharu Okuda , Shoichiro Taira , Michitaka Sakurai , Yusuke Fushiwaki
CPC分类号： C23C2/02 , C21D9/46 , C22C38/001 , C22C38/02 , C22C38/04 , C22C38/06 , C22C38/22 , C22C38/32 , C22C38/38 , C23C2/06 , C23C2/28
摘要： A high-strength galvanized steel sheet has a low YP, good stretch flangeability, and excellent corrosion resistance and contains, on a percent by mass basis, more than 0.015% to less than 0.10% of C, 0.5% or less of Si, 1.0% to 1.9% of Mn, 0.015% to 0.050% of P, 0.03% or less of S, 0.01% to 0.5% of sol. Al, 0.005% or less of N, less than 0.40% of Cr, 0.005% or less of B, less than 0.15% of Mo, 0.4% or less of V, and less than 0.020% of Ti, in which 2.2≦[Mneq]≦3.1 and [% Mn]+3.3[% Mo]≦1.9, and [% Mn]+3.3 [% Mo])/(1.3[% Cr]+8[% P]+150B*)
摘要翻译： 高强度镀锌钢板具有低YP，良好的拉伸凸缘性和优异的耐腐蚀性，并且以质量％计含有C：0.015％以上且小于0.10％的C，0.5％以下的Si，1.0 Mn的1.9％以下，P：0.015〜0.050％，S：0.03％以下，溶胶的0.01〜0.5％。 Al，0.005％以下的N，小于0.40％的Cr，0.005％以下的B，小于0.15％的Mo，0.4％以下的V和小于0.020％的Ti，其中2.2和nlE; [Mneq]＆nlE; 3.1和[％Mn] +3.3 [％Mo]＆nlE; 1.9和[％Mn] +3.3 [％Mo]）/（1.3 [％Cr] +8 [％P] + 150B * <3.5满意。
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公开(公告)号：US20120031531A1
公开(公告)日：2012-02-09
申请号：US13208939
申请日：2011-08-12
申请人： Shoichiro Taira , Yoshiharu Sugimoto , Yoichi Miyakawa , Akira Gamou , Masayasu Nagoshi , Takashi Kawano
发明人： Shoichiro Taira , Yoshiharu Sugimoto , Yoichi Miyakawa , Akira Gamou , Masayasu Nagoshi , Takashi Kawano
CPC分类号： C23C2/26 , C23C2/06 , C23C2/28 , C23C22/08 , C23C22/50 , C23C22/53 , C23C22/78 , C23C22/82 , C23C22/83 , Y10T428/12611 , Y10T428/12618 , Y10T428/1266 , Y10T428/12799
摘要： The invention provides a hot dip galvanized steel sheet which has: a hot dip galvanizing layer having a flat part on a surface thereof; and a film formed on the flat part. The film is composed of a compound containing Zn, Fe, and O, having an average film thickness A in a range from 10 to 100 nm determined by an element analysis of the film, and has {[Fe]/{[Zn]+[Fe]}} in the film in a range from 0.002 to 0.25, where [Zn] and [Fe] designate the content (% by atom) of Zn and Fe in the film, respectively. Since the hot dip galvanized steel sheet of the invention has excellent press-formability, bondability, and phosphatability, it is suitable for automobiles and electrical appliances.
摘要翻译： 本发明提供一种热浸镀锌钢板，其具有：在其表面上具有平坦部分的热浸镀锌层; 以及形成在平坦部分上的膜。 该膜由含有Zn，Fe和O的化合物组成，其具有通过膜的元素分析确定的平均膜厚度A在10至100nm的范围内，并且具有{[Fe] / {[Zn] [Fe]}}在0.002至0.25的范围内，其中[Zn]和[Fe]分别表示膜中Zn和Fe的含量（％原子）。 由于本发明的热浸镀锌钢板具有优异的压制成形性，粘合性和磷化性，因此适用于汽车和电器。
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