公开(公告)号：US08221559B2

公开(公告)日：2012-07-17

申请号：US12077464

申请日：2008-03-19

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C23C10/02 ,  C25D13/12

CPC分类号： C23C22/34 ,  C23C2222/20 ,  C25D3/56 ,  C25D13/20

摘要： A surface treatment with a zirconium ion that enables sufficient throwing power and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid thereof for cation electrodeposition coating includes zirconium ions, copper ions, and other metal ions, and having a pH of 1.5 to 6.5, in which: the other metal ions are at least one selected from the group consisting of tin ions, indium ions, aluminum ions, niobium ions, tantalum ions, yttrium ions and cerium ions; the concentration of zirconium ions is 10 to 10,000 ppm; the concentration ratio of the copper ions to the zirconium ions is 0.005 to 1 on a mass basis; and the concentration ratio of the other metal ions to the copper ions is 0.1 to 1,000 on a mass basis.

摘要翻译： 提供了一种用这种表面处理的金属基材进行阳离子电沉积涂覆时能够发挥足够的抛光力和优异的抗腐蚀性能的锆离子的表面处理。 用于阳离子电沉积涂层的金属表面处理液包括锆离子，铜离子和其它金属离子，并且具有1.5至6.5的pH，其中：其它金属离子是选自锡离子 铟离子，铝离子，铌离子，钽离子，钇离子和铈离子; 锆离子的浓度为10〜10000ppm; 基于质量计，铜离子与锆离子的浓度比为0.005〜1; 并且其他金属离子与铜离子的浓度比以质量计为0.1〜1,000。

公开(公告)号：US20090218228A1

公开(公告)日：2009-09-03

申请号：US12224628

申请日：2007-02-28

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： B32B15/00 ,  C11D3/04 ,  B05D3/10 ,  C25D5/00 ,  C23G1/02

CPC分类号： C23C22/48 ,  C08G59/50 ,  C08G77/26 ,  C08K3/10 ,  C09D163/00 ,  C09D175/04 ,  C23C22/50 ,  C23C22/56 ,  C23C22/83 ,  Y10T428/12729 ,  Y10T428/12736 ,  Y10T428/12792 ,  Y10T428/12951

摘要： An easily handleable composition for metal surface treatment is provided which achieves foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. A method for treating the surface of a metal material in which such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method, are also provided. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.

摘要翻译： 提供了用于金属表面处理的易于处理的组合物，其实现了与通过常规金属表面处理组合物获得的那些相同或更高的基础表面隐蔽性，涂层粘附性和耐腐蚀性。 这种金属表面处理用组合物不会对环境造成负担。 还提供了一种用于处理金属表面处理用金属材料的表面的方法以及通过这种金属表面处理方法处理的金属材料。 具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。 该金属表面处理组合物的pH值不低于1.5但不大于6.5。

公开(公告)号：US08262809B2

公开(公告)日：2012-09-11

申请号：US12224628

申请日：2007-02-28

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： C22C22/48 ,  C25D9/00

CPC分类号： C23C22/48 ,  C08G59/50 ,  C08G77/26 ,  C08K3/10 ,  C09D163/00 ,  C09D175/04 ,  C23C22/50 ,  C23C22/56 ,  C23C22/83 ,  Y10T428/12729 ,  Y10T428/12736 ,  Y10T428/12792 ,  Y10T428/12951

摘要： An easily handleable composition for metal surface treatment is provided which achieves foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. A method for treating the surface of a metal material in which such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method, are also provided. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.

摘要翻译： 提供了用于金属表面处理的易于处理的组合物，其实现了与通过常规金属表面处理组合物获得的那些相同或更高的基础表面隐蔽性，涂层粘附性和耐腐蚀性。 这种金属表面处理用组合物不会对环境造成负担。 还提供了一种用于处理金属表面处理用金属材料的表面的方法以及通过这种金属表面处理方法处理的金属材料。 具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。 该金属表面处理组合物的pH值不低于1.5但不大于6.5。

公开(公告)号：US20100243465A1

公开(公告)日：2010-09-30

申请号：US12679048

申请日：2008-09-26

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C23C22/80 ,  B05D3/10

CPC分类号： C23C22/361 ,  C09D5/4488 ,  C23C22/34 ,  C23C22/83 ,  C23C2222/20 ,  C25D13/04

摘要： A method of producing a surface-treated metal material, comprising: surface treating a metal material using a treatment liquid (1), which comprises from 10 to 10,000 ppm of tin ions and has a pH of 1.0 or greater, and subjecting the metal material that has undergone surface treatment with the treatment liquid (1) to an additional chemical conversion treatment using a treatment liquid (2), which comprises zirconium ions and/or titanium ions.

摘要翻译： 一种表面处理金属材料的制造方法，其特征在于，包括：使用处理液（1）对金属材料进行表面处理，所述处理液包含10〜10000ppm的锡离子，pH为1.0以上，并对所述金属材料 已经用处理液（1）进行表面处理，使用包含锆离子和/或钛离子的处理液（2）进行附加的化学转化处理。

公开(公告)号：US20080230395A1

公开(公告)日：2008-09-25

申请号：US12077464

申请日：2008-03-19

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C25D5/00

CPC分类号： C23C22/34 ,  C23C2222/20 ,  C25D3/56 ,  C25D13/20

摘要： A surface treatment with a zirconium ion that enables sufficient throwing power and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid thereof for cation electrodeposition coating includes zirconium ions, copper ions, and other metal ions, and having a pH of 1.5 to 6.5, in which: the other metal ions are at least one selected from the group consisting of tin ions, indium ions, aluminum ions, niobium ions, tantalum ions, yttrium ions and cerium ions; the concentration of zirconium ions is 10 to 10,000 ppm; the concentration ratio of the copper ions to the zirconium ions is 0.005 to 1 on a mass basis; and the concentration ratio of the other metal ions to the copper ions is 0.1 to 1,000 on a mass basis.

摘要翻译： 提供了一种用这种表面处理的金属基材进行阳离子电沉积涂覆时能够发挥足够的抛光力和优异的抗腐蚀性能的锆离子的表面处理。 用于阳离子电沉积涂层的金属表面处理液包括锆离子，铜离子和其它金属离子，并且具有1.5至6.5的pH，其中：其它金属离子是选自锡离子 铟离子，铝离子，铌离子，钽离子，钇离子和铈离子; 锆离子的浓度为10〜10000ppm; 基于质量计，铜离子与锆离子的浓度比为0.005〜1; 并且其他金属离子与铜离子的浓度比以质量计为0.1〜1,000。

公开(公告)号：US09028667B2

公开(公告)日：2015-05-12

申请号：US13613544

申请日：2012-09-13

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： C23C22/48 ,  C25D3/02 ,  C25D11/00 ,  C09D183/08 ,  C23C22/34 ,  C23C22/83 ,  C25D13/20 ,  C23C22/02 ,  C23C22/00

CPC分类号： C25D11/00 ,  C09D183/08 ,  C23C22/02 ,  C23C22/34 ,  C23C22/361 ,  C23C22/48 ,  C23C22/82 ,  C23C22/83 ,  C25D3/02 ,  C25D13/20 ,  Y02T50/67 ,  Y10T428/12472 ,  Y10T428/273 ,  Y10T428/31529

摘要： A metal material is contacted with a treatment solution containing zirconium and/or titanium compound, and a polyamine compound having a number average molecular weight from 150 to 500,000 and containing from 0.1 mmol to 17 mmol of primary and/or secondary amino group per 1 g of solid content and at least one siloxane unit. Concentration of zirconium and/or titanium compound in the metal surface treatment composition is from 10 ppm to 10,000 ppm with respect to the metal element, and mass ratio of the zirconium and/or titanium element is from 0.1 to 100 with respect to the polyamine compound. The metal material is washed with water after contacted by the treatment solution.

摘要翻译： 将金属材料与含有锆和/或钛化合物的处理溶液和数均分子量为150至500,000的多胺化合物接触，并且每1g含有0.1mmol至17mmol的伯和/或仲氨基 的固体含量和至少一种硅氧烷单元。 金属表面处理组合物中锆和/或钛化合物的浓度相对于金属元素为10ppm〜10000ppm，相对于多胺化合物，锆和/或钛元素的质量比为0.1〜100 。 金属材料在用处理溶液接触后用水洗涤。

公开(公告)号：US08828151B2

公开(公告)日：2014-09-09

申请号：US13479570

申请日：2012-05-24

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： C23C22/48 ,  C25D9/00

CPC分类号： C23C22/48 ,  C08G59/50 ,  C08G77/26 ,  C08K3/10 ,  C09D163/00 ,  C09D175/04 ,  C23C22/50 ,  C23C22/56 ,  C23C22/83 ,  Y10T428/12729 ,  Y10T428/12736 ,  Y10T428/12792 ,  Y10T428/12951

摘要： Disclosed is an easily handleable composition for metal surface treatment which enables to achieve foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. Also disclosed are a method for treating the surface of a metal material wherein such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.

摘要翻译： 公开了用于金属表面处理的易于处理的组合物，其能够实现等于或高于通过常规金属表面处理组合物获得的基础表面隐蔽性，涂层粘附性和耐腐蚀性。 这种金属表面处理用组合物不会对环境造成负担。 还公开了一种处理金属材料的表面的方法，其中使用了这种用于金属表面处理的组合物，以及通过这种金属表面处理方法处理的金属材料。 具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。 该金属表面处理组合物的pH值不低于1.5但不大于6.5。

公开(公告)号：US08784629B2

公开(公告)日：2014-07-22

申请号：US12679048

申请日：2008-09-26

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C25D13/04 ,  C23C10/02 ,  C23C22/80

CPC分类号： C23C22/361 ,  C09D5/4488 ,  C23C22/34 ,  C23C22/83 ,  C23C2222/20 ,  C25D13/04

摘要： A method of producing a surface-treated metal material, comprising: surface treating a metal material using a treatment liquid (1), which comprises from 10 to 10,000 ppm of tin ions and has a pH of 1.0 or greater, and subjecting the metal material that has undergone surface treatment with the treatment liquid (1) to an additional chemical conversion treatment using a treatment liquid (2), which comprises zirconium ions and/or titanium ions.

摘要翻译： 一种表面处理金属材料的制造方法，其特征在于，包括：使用处理液（1）对金属材料进行表面处理，所述处理液包含10〜10000ppm的锡离子，pH为1.0以上，并对金属材料 已经用处理液（1）进行表面处理，使用包含锆离子和/或钛离子的处理液（2）进行附加的化学转化处理。

公开(公告)号：US20130244026A1

公开(公告)日：2013-09-19

申请号：US13613544

申请日：2012-09-13

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： C25D11/00 ,  C23C22/02 ,  C25D3/02

CPC分类号： C25D11/00 ,  C09D183/08 ,  C23C22/02 ,  C23C22/34 ,  C23C22/361 ,  C23C22/48 ,  C23C22/82 ,  C23C22/83 ,  C25D3/02 ,  C25D13/20 ,  Y02T50/67 ,  Y10T428/12472 ,  Y10T428/273 ,  Y10T428/31529

摘要： A metal material is contacted with a treatment solution containing zirconium and/or titanium compound, and a polyamine compound having a number average molecular weight from 150 to 500,000 and containing from 0.1 mmol to 17 mmol of primary and/or secondary amino group per 1 g of solid content and at least one siloxane unit. Concentration of zirconium and/or titanium compound in the metal surface treatment composition is from 10 ppm to 10,000 ppm with respect to the metal element, and mass ratio of the zirconium and/or titanium element is from 0.1 to 100 with respect to the polyamine compound. The metal material is washed with water after contacted by the treatment solution.

摘要翻译： 将金属材料与含有锆和/或钛化合物的处理溶液和数均分子量为150至500,000的多胺化合物接触，并且每1g含有0.1mmol至17mmol的伯和/或仲氨基 的固体含量和至少一种硅氧烷单元。 金属表面处理组合物中锆和/或钛化合物的浓度相对于金属元素为10ppm〜10000ppm，相对于多胺化合物，锆和/或钛元素的质量比为0.1〜100 。 金属材料在用处理溶液接触后用水洗涤。

公开(公告)号：US08430972B2

公开(公告)日：2013-04-30

申请号：US12876612

申请日：2010-09-07

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： C23C10/18 ,  C23C22/48

CPC分类号： C09D183/08 ,  C08K3/10 ,  C23C18/1216 ,  C23C18/122 ,  C23C18/1241 ,  C23C18/1295 ,  C23C22/34 ,  C23C2222/20 ,  Y10T428/12 ,  Y10T428/12729 ,  Y10T428/12743 ,  Y10T428/12792 ,  Y10T428/12951 ,  Y10T428/31663

摘要： A metal surface treatment composition including at least one compound selected from the group consisting of a zirconium compound and a titanium compound, and an organosiloxane, which is a polycondensate of organosilane and has in a molecule thereof of at least two amino groups, in which the Degree of polycondensation of the organosiloxane is at least 40%, the content of at least one compound selected from the group consisting of the zirconium compound and the titanium compound is predetermined content, the content of the organosiloxane in the metal surface treatment composition is predetermined content, and the mass ratio of at least one element selected from the group consisting of the zirconium element and the titanium element contained in the zirconium compound and the titanium compound, respectively, to the silicon element contained in the organosiloxane is a predetermined ratio.