公开(公告)号：US07951503B2

公开(公告)日：2011-05-31

申请号：US11571620

申请日：2005-05-20

申请人： Mitsuhito Takahashi ,  Toshio Ohba ,  Nobuo Kawada ,  Shigeru Konishi

发明人： Mitsuhito Takahashi ,  Toshio Ohba ,  Nobuo Kawada ,  Shigeru Konishi

IPC分类号： H01M8/10 ,  H01M8/00

CPC分类号： C08F259/08 ,  C08J5/2237 ,  C08J2327/18 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： A curable resin composition for fuel cell electrolyte films characterized by comprising (1) 100 parts by mass of a monomer having at least one ethylenically unsaturated group per molecule and having, per molecule, either at least one, tonically conductive group or at least one precursor group capable of giving an tonically conductive group through a chemical reaction, (2) 10-400 parts by mass of an oligomer which has, per molecule, at least two reactive groups copolymerizable with the ethylenically unsaturated group of the ingredient (1) and has a number-average molecular weight of 400 or higher, (3) 10-400 parts by mass of a fluororesin, and (4) 0-2,000 parts by mass of a solvent.

摘要翻译： 1.一种燃料电池用电解质膜用固化性树脂组合物，其特征在于，含有（1）每分子100质量份具有至少一个烯属不饱和基团的单体，并且每分子具有至少一个导电性基团或至少一种前体 能够通过化学反应赋予导电性基团的基团，（2）10-400质量份的低聚物，其每分子具有至少两个可与成分（1）的烯属不饱和基团共聚的反应性基团，并具有 数均分子量为400以上，（3）10-400质量份氟树脂，和（4）0-2,000质量份溶剂。

公开(公告)号：US20110062379A1

公开(公告)日：2011-03-17

申请号：US12880799

申请日：2010-09-13

申请人： Satoru MIYAWAKI ,  Yoshiyasu Yamada ,  Toshio Ohba ,  Tadao Ikeda ,  Kazuhiro Sunouchi

发明人： Satoru MIYAWAKI ,  Yoshiyasu Yamada ,  Toshio Ohba ,  Tadao Ikeda ,  Kazuhiro Sunouchi

IPC分类号： H01M4/134

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/134 ,  H01M4/364 ,  H01M4/483 ,  H01M4/621 ,  H01M4/622 ,  H01M4/624 ,  H01M4/625

摘要： A negative electrode comprising (A) particles having Si dispersed in SiO, and (B) a polyamide-imide resin which contains amide and imide groups in an amide/imide ratio of 25/75 to 99/1 and has a weight average molecular weight of 10,000-200,000 is suited for nonaqueous electrolyte secondary batteries. The electrode exhibits a high 1st cycle charge/discharge efficiency and improved cycle performance while maintaining a high battery capacity and a low volume expansion.

摘要翻译： 一种负极，其包含（A）分散在SiO中的Si的颗粒，和（B）酰胺/酰亚胺比为25/75〜99/1的酰胺和酰亚胺基的聚酰胺酰亚胺树脂，其重均分子量 10,000-200,000适用于非水电解质二次电池。 该电极具有高的第一循环充电/放电效率和改进的循环性能，同时保持高电池容量和低体积膨胀。

公开(公告)号：US07629020B2

公开(公告)日：2009-12-08

申请号：US10963660

申请日：2004-10-14

申请人： Toshio Ohba ,  Shigeru Konishi ,  Mitsuhito Takahashi ,  Norifumi Takahashi

发明人： Toshio Ohba ,  Shigeru Konishi ,  Mitsuhito Takahashi ,  Norifumi Takahashi

IPC分类号： B05D5/12

CPC分类号： C08J5/2293 ,  C08J2327/12 ,  H01M8/1004 ,  H01M8/1081 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： An electrolyte membrane for fuel cells is prepared by irradiating with radiation a composition comprising a radiation-curable liquid compound having proton conductivity for curing the liquid compound to form a cured film. The methods of the invention are successful in producing an electrolyte membrane and an electrolyte membrane/electrode assembly for fuel cells while satisfying both the requirements of productivity and cell-related properties including proton conduction and membrane strength.

摘要翻译： 燃料电池用电解质膜是通过用辐射照射包含具有质子传导性的可辐射固化液体化合物的组合物来固化液体化合物以形成固化膜来制备的。 本发明的方法在生产电解质膜和用于燃料电池的电解质膜/电极组件方面是成功的，同时满足生产力和包括质子传导和膜强度的电池相关性质的要求。

公开(公告)号：US20090286128A1

公开(公告)日：2009-11-19

申请号：US11917324

申请日：2006-06-06

申请人： Nobuo Kawada ,  Toshio Ohba ,  Norifumi Takahashi

发明人： Nobuo Kawada ,  Toshio Ohba ,  Norifumi Takahashi

IPC分类号： H01M8/10

CPC分类号： C08J5/2293 ,  C08F259/08 ,  C08F291/185 ,  C08J2323/06 ,  C08J2327/18 ,  H01B1/122 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： In the present invention, a solid polyelectrolyte film is obtained by irradiating a dense fluorinated resin film having a thickness of 10 to 50 μm in an inert gas atmosphere with an electron beam having been accelerated at an accelerating voltage of 60 to 300 kV in vacuum and transmitted through an electron beam-transmitting window so that an absorbed dose is from 1 to 50 kGy, followed by graft-polymerizing a polymerizable monomer. Moreover, the solid polyelectrolyte film is disposed between a fuel electrode and an air electrode to form a fuel cell.

摘要翻译： 在本发明中，固体聚电解质膜是通过在惰性气体气氛中在真空中加速加速电压为60〜300kV的电子束照射厚度为10〜50μm的致密氟化树脂膜而得到的， 透过电子束透过窗口使吸收剂量为1〜50kGy，接着聚合可聚合单体。 此外，固体聚电解质膜设置在燃料电极和空气电极之间以形成燃料电池。

公开(公告)号：US20080216927A1

公开(公告)日：2008-09-11

申请号：US10569485

申请日：2004-08-27

申请人： Toshio Ohba ,  Kota Sawada ,  Kazuhiro Kimura ,  Hirokazu Okada ,  Fujio Abe

发明人： Toshio Ohba ,  Kota Sawada ,  Kazuhiro Kimura ,  Hirokazu Okada ,  Fujio Abe

IPC分类号： C21D1/78 ,  C22C38/30 ,  C22C38/22

CPC分类号： C22C38/02 ,  C21D1/18 ,  C21D1/28 ,  C21D6/002 ,  C21D9/0093 ,  C22C38/04 ,  C22C38/22 ,  C22C38/24 ,  C22C38/26 ,  C22C38/30 ,  C22C38/32 ,  F01D25/243

摘要： A high temperature bolt material, characterized in that it is a ferrite steel comprising 8 wt % or more of Cr and having a tempered martensite structure and can be used in a high temperature region of higher than 500° C.; and a method for producing the high temperature bolt material which comprises subjecting the above-mentioned steel material to a heat treatment comprising a quenching or normalizing at a temperature of 1000° C. or higher and then to a tempering at a temperature of 730° C. or higher. The above ferrite steel high temperature bolt material is excellent in characteristics of the resistance to stress relaxation.

摘要翻译： 一种高温螺栓材料，其特征在于，其为含有8重量％以上的Cr且具有回火马氏体组织的铁素体钢，可用于高于500℃的高温区域。 以及一种生产高温螺栓材料的方法，该方法包括对上述钢材进行包括在1000℃或更高的温度下骤冷或归一化的热处理，然后在730℃的温度下回火 。 或更高。 上述铁素体高温螺栓材料具有优异的耐应力松弛特性。

公开(公告)号：US20050187338A1

公开(公告)日：2005-08-25

申请号：US11057750

申请日：2005-02-15

申请人： Toshio Ohba ,  Mitsuhito Takahashi ,  Atsuo Itoh

发明人： Toshio Ohba ,  Mitsuhito Takahashi ,  Atsuo Itoh

IPC分类号： H01B13/00 ,  C08J5/22 ,  C09D175/08 ,  H01B1/12 ,  H01M8/02 ,  H01M8/10 ,  G03G15/00 ,  C08K3/00

CPC分类号： C09D175/08 ,  C08J5/2231 ,  C08J2323/04 ,  H01B1/122 ,  H01M8/1004 ,  H01M8/1072 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： A liquid curable resin composition comprising a compound having an ethylenically unsaturated group and an ion conductive group and optionally, an oligomer having at least two reactive groups is cured by heat and/or UV or EB irradiation to form an electrolyte membrane having excellent ionic conduction. The composition has a viscosity of 100-100,000 mPa·s at 25° C. so that it is readily applicable. The electrolyte membrane and an electrolyte membrane/electrode assembly for use in fuel cells satisfy cell-related properties including ionic conduction and film strength as well as productivity.

摘要翻译： 包含具有烯键式不饱和基团和离子导电基团的化合物和任选的具有至少两个反应性基团的低聚物的液体可固化树脂组合物通过加热和/或UV或EB照射固化以形成具有优异离子传导性的电解质膜。 该组合物在25℃下的粘度为100-100,000mPa.s，因此易于应用。 电解质膜和用于燃料电池的电解质膜/电极组件满足包括离子传导和膜强度以及生产​​率在内的细胞相关性质。

公开(公告)号：US5942591A

公开(公告)日：1999-08-24

申请号：US879053

申请日：1997-06-19

申请人： Hideyuki Itoh ,  Toshio Ohba ,  Kenichi Isobe ,  Shinji Irifune ,  Takamasa Toyoda

发明人： Hideyuki Itoh ,  Toshio Ohba ,  Kenichi Isobe ,  Shinji Irifune ,  Takamasa Toyoda

IPC分类号： C09D183/05 ,  C09D183/04 ,  C09D183/07 ,  D21H27/00 ,  C08G77/08

CPC分类号： C09D183/04

摘要： A solventless curable silicone release composition contains (A) a branched organopolysiloxane having a vinyl group attached to a silicon atom at an end of its molecular chain, (B) an organohydrogenpolysiloxane having at least three SiH groups in a molecule, and (C) a platinum group metal catalyst. The composition is easily applicable to a thin gage and cures into a releasable silicone coating ensuring light release at high speeds. A release sheet having the cured coating formed thereon has improved release characteristics.

摘要翻译： 无溶剂固化性有机硅剥离组合物含有（A）在其分子链末端具有与硅原子相连的乙烯基的支链有机聚硅氧烷，（B）分子中具有至少三个SiH基的有机氢聚硅氧烷，（C） 铂族金属催化剂。 该组合物易于应用于薄规格并固化成可释放的硅氧烷涂层，确保高速下的光释放。 具有形成在其上的固化涂层的剥离片具有改善的剥离特性。

公开(公告)号：US5436281A

公开(公告)日：1995-07-25

申请号：US242394

申请日：1994-05-13

申请人： Shinji Irifune ,  Toshio Ohba

发明人： Shinji Irifune ,  Toshio Ohba

IPC分类号： C08F2/48 ,  C08L83/06 ,  C09D183/06 ,  C09J7/02

CPC分类号： C09J7/0228 ,  C08L83/06 ,  C09D183/06 ,  C09J2205/31 ,  C09J2483/005

摘要： Proposed is an improved radiation-curable organopolysiloxane composition capable of giving a cured surface film on a substrate surface which exhibits excellent releasability against sticky substances. The composition is obtained by combining two kinds of (meth)acryloxyalkyl-containing organopolysiloxanes in a specified weight proportion, of which one has a relatively large degree of polymerization but contains only a relatively small amount of the silicon-bonded (meth)acryloxyalkyl groups while the other has a relatively small degree of polymerization but contains a relatively large amount of the silicon-bonded (meth)acryloxyalkyl groups. By virtue of this unique formulation, the surface-release sheet provided with a cured surface film of this organopolysiloxane composition and attached to a sticky surface for temporary protection is safe from generation of a peeling noise which is unavoidable in the prior art when a surface-release sheet is peeled off from the sticky surface at a high peeling velocity, especially, when the peeling resistance is great.

摘要翻译： 提出了能够在基材表面上赋予固化的表面膜的改进的可辐射固化的有机基聚硅氧烷组合物，其对粘性物质具有优异的脱模性。 通过组合两种（甲基）丙烯酰氧基烷基的有机聚硅氧烷以特定重量比例组合，其中聚合度相对较高但仅含有相对少量的与硅键合的（甲基）丙烯酰氧基烷基，而 另一方面具有相对较小的聚合度，但含有相对大量的与硅键合的（甲基）丙烯酰氧基烷基。 由于这种独特的配方，具有这种有机基聚硅氧烷组合物的固化的表面膜并附着在粘性表面上用于临时保护的表面剥离片材就不会产生现有技术中不可避免的剥离噪音， 剥离片以高剥离速度从粘性表面剥离，特别是耐剥离性大时，

公开(公告)号：US5391405A

公开(公告)日：1995-02-21

申请号：US964685

申请日：1992-10-22

申请人： Shinji Irifune ,  Toshio Ohba

发明人： Shinji Irifune ,  Toshio Ohba

IPC分类号： C08G77/20 ,  C09D183/06 ,  B05D3/06 ,  C08F2/50

CPC分类号： C08G77/20 ,  C09D183/06

摘要： Disclosed is a method for imparting anti-sticking surface-releasability to the surface of a substrate which comprises: coating the surface with a novel radiation-curable (meth)acryloxy-containing organopolysiloxane; and curing the coating layer by the irradiation with radiation such as electron beams and ultraviolet light. Different from conventional radiation-curable (meth)acryloxy-containing organopolysiloxanes, the novel organopolysiloxane here used is characteristic in comprising at least one trifunctional organosiloxane unit in a molecule, by virtue of which the (meth)acryloxy-containing organopolysiloxane has good curability by the irradiation to exhibit excellent surface-releasability with high durability against aging.

摘要翻译： 公开了一种赋予基材表面的抗粘着表面剥离性的方法，该方法包括：用新的可辐射固化（甲基）丙烯酰氧基的有机基聚硅氧烷涂覆表面; 并且通过用诸如电子束和紫外光的辐射照射来固化涂层。 与常规的可辐射固化的（甲基）丙烯酰氧基的有机聚硅氧烷不同，这里使用的新型有机聚硅氧烷具有在分子中包含至少一个三官能有机硅氧烷单元的特征，由此，（甲基）丙烯酰氧基的有机聚硅氧烷具有良好的固化性 照射以表现出优异的表面剥离性，并且耐老化性高。

公开(公告)号：US5190988A

公开(公告)日：1993-03-02

申请号：US706706

申请日：1991-05-29

申请人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara

发明人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara

IPC分类号： C08K5/42 ,  C08F2/50 ,  C08F4/08 ,  C08F290/00 ,  C08F299/08 ,  C08L83/04 ,  C08L83/06 ,  C08L83/07 ,  C09D183/06 ,  C09J183/00 ,  C09J183/07

CPC分类号： C09D183/06

摘要： The invention provides a high-sensitivity ultraviolet-curable organopolysiloxane composition suitable for use as a surface-release treatment of various substrate such as release-paper sheets and the like. The composition comprises, as the essential ingredients, (a) an organopolysiloxane having a viscosity in the range from 50 to 3000 centipoise at 25.degree. C. and containing, in a molecule, at least one (meth)acryloxy-substituted monovalent hydrocarbon group or at least one epoxy- or glycidyloxy-substituted monovalent hydrocarbon group, and (b) a sulfonate compound such as 2-hydroxy-3-oxy-2,3-diphenylpropyl methanesulfonate as the photopolymerization initiator. The sensitivity of the composition to photopolymerization can be further increased by the addition of a specific salt such as sodium hexafluoroantimonate and sodium hexafluorophosphate.

摘要翻译： 本发明提供一种适用于各种基材如脱模纸等的表面剥离处理的高灵敏度紫外线固化型有机基聚硅氧烷组合物。 该组合物包含作为必要成分的（a）在25℃下粘度为50-3000厘泊的有机聚硅氧烷，并且在一分子中含有至少一个（甲基）丙烯酰氧基取代的一价烃基或 至少一个环氧基或缩水甘油氧基取代的一价烃基，和（b）磺酸酯化合物如2-羟基-3-氧基-2,3-二苯基丙基甲磺酸酯作为光聚合引发剂。 通过加入特定的盐如六氟锑酸钠和六氟磷酸钠可以进一步提高组合物对光聚合的敏感性。