公开(公告)号：US4302611A

公开(公告)日：1981-11-24

申请号：US187691

申请日：1980-09-16

申请人： Richard V. Porcelli

发明人： Richard V. Porcelli

IPC分类号： C07C27/00 ,  C07C45/49 ,  C07C47/06

CPC分类号： C07C45/49

摘要： Acetaldehyde is prepared by reacting methyl acetate and/or dimethyl ether with carbon monoxide and hydrogen in the presence of a palladium catalyst and an iodine moiety in a reaction zone wherein the reaction mixture is in a continuous boiling state.

摘要翻译： 在反应混合物处于连续沸腾状态的反应区中，在钯催化剂和碘部分的存在下，使乙酸甲酯和/或二甲醚与一氧化碳和氢气反应制备乙醛。

公开(公告)号：US4476237A

公开(公告)日：1984-10-09

申请号：US267960

申请日：1981-05-28

申请人： Richard V. Porcelli

发明人： Richard V. Porcelli

IPC分类号： C07C69/14 ,  C07C51/00 ,  C07C51/42 ,  C07C51/47 ,  C07C51/48 ,  C07C51/573 ,  C07C53/12 ,  C07C67/00 ,  B01J27/32 ,  B01J23/96 ,  C07C51/56 ,  C07C67/37

CPC分类号： C07C67/36 ,  C07C51/47 ,  C07C51/48 ,  C07C51/573 ,  C07C67/37

摘要： Tarry residues often are formed in carbonylation reactions, such as those in which esters or ethers are carbonylated to produce ethylidene diacetate or carboxylic acid anhydrides, such as acetic anhydride. Such residues contain Group VIII noble metal catalysts, typically rhodium, which must be separated before the residues can be disposed of. In the process of the invention, a portion of the carbonylation reaction mixture is flashed to a lower pressure and the resulting residues-containing liquid is extracted with solvents which preferentially remove the tars. The tars are separated from the solvents and disposed of while the solvents are recycled for further use. The catalyst-containing liquid is processed to remove residual solvent and returned to the carbonylation reaction.

摘要翻译： 在羰基化反应中常常形成塔里木渣，例如其中酯或醚被羰基化以产生亚乙基二乙酸酯或羧酸酐如乙酸酐的那些。 这样的残留物含有VIII族贵金属催化剂，通常是铑，必须在残留物被处理之前分离。 在本发明的方法中，将羰基化反应混合物的一部分闪蒸至较低的压力，并将所得含残留液体用优先除去焦油的溶剂萃取。 将这些焦油与溶剂分离并处理，同时将溶剂再循环使用。 处理含催化剂的液体以除去残余溶剂并返回羰基化反应。

公开(公告)号：US4358411A

公开(公告)日：1982-11-09

申请号：US53610

申请日：1979-06-29

申请人： Richard V. Porcelli ,  Vijay S. Bhise

发明人： Richard V. Porcelli ,  Vijay S. Bhise

IPC分类号： C07C53/12 ,  B01J23/00 ,  B01J23/46 ,  B01J27/00 ,  B01J27/06 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/56 ,  C07C67/00 ,  C07C51/12

CPC分类号： C07C51/56

摘要： Carbonylation products such as alkanoic anhydrides, e.g., acetic anhydrides, are produced by carbonylation of esters and/or ethers in the presence of a rhodium or iridium catalyst and an iodine moiety in a reaction zone wherein the reaction mixture is in a continuous boiling state.

摘要翻译： 羰基化产物如链烷酸酐，例如乙酸酐，是通过在反应混合物处于连续沸腾状态的反应区中在铑或铱催化剂和碘部分存在下羰基化酯和/或醚来制备的。

公开(公告)号：US4238551A

公开(公告)日：1980-12-09

申请号：US17756

申请日：1979-03-05

申请人： Sudarshan Lal ,  Richard V. Porcelli

发明人： Sudarshan Lal ,  Richard V. Porcelli

IPC分类号： C23C30/00 ,  C23F13/00 ,  B32B15/00

CPC分类号： C23C30/00 ,  C23F13/005 ,  Y10S428/935 ,  Y10T428/12806 ,  Y10T428/12875

摘要： A process is provided for inhibiting the rate of corrosion of titanium metal surfaces from attack by strong acid media in which at least a portion of the titanium metal surface is coated with rhodium metal to provide a treated metal surface which is substantially impervious to corrosion by strong acid media. The article so prepared appears to be uniquely impervious to corrosion by strong acid media and is also claimed herein.

摘要翻译： 提供了一种用于抑制钛金属表面的腐蚀速度被强酸介质侵蚀的方法，其中至少一部分钛金属表面被铑金属涂覆以提供经过处理的金属表面，该表面基本上不受腐蚀强烈 酸性介质。 如此制备的制品似乎对强酸性介质的腐蚀是独一无二的，并且也在此要求保护。

公开(公告)号：US20060052739A1

公开(公告)日：2006-03-09

申请号：US11265383

申请日：2005-11-03

申请人： Julian Henley ,  Kuo Chang ,  Joseph Potter ,  Dennis Goldberg ,  Christopher Porter ,  V. Porcelli

发明人： Julian Henley ,  Kuo Chang ,  Joseph Potter ,  Dennis Goldberg ,  Christopher Porter ,  V. Porcelli

IPC分类号： A61N1/30

CPC分类号： A61N1/0428 ,  A61N1/0436 ,  A61N1/044 ,  A61N1/0448 ,  A61N1/30

摘要： An electrokinetic delivery or diagnostic device for personal use and self-administration of a medicament to a treatment site is provided. The device includes a housing containing a power supply, a first active electrode and a ground tactile electrode. An applicator includes a pad for containing medicament for overlying the first electrode of the device. The medicament may be applied by the user to the pad, contained within the pad or contained in rupturable capsules within the pad, together with a hydrogel if necessary for imparting electrical conductivity whereby, upon application of the applicator to the treatment site, the medicament is electrokinetically transported into the treatment site. In another form, the applicator is self-contained, having a power supply, a first electrode overlying a pad and a ground electrode from the opposite side from the pad whereby the individual presses the pad against the treatment site to complete the electrical circuit and electrokinetically drive the medicament into the treatment site.

公开(公告)号：US4340569A

公开(公告)日：1982-07-20

申请号：US241180

申请日：1981-03-06

申请人： Walter C. Davidson ,  Richard V. Porcelli

发明人： Walter C. Davidson ,  Richard V. Porcelli

IPC分类号： C07C69/16 ,  B01J23/00 ,  B01J31/40 ,  B01J38/00 ,  C01G55/00 ,  C07B31/00 ,  C07B41/12 ,  C07B61/00 ,  C07C27/00 ,  C07C45/00 ,  C07C50/08 ,  C07C51/00 ,  C07C51/56 ,  C07C53/08 ,  C07C53/12 ,  C07C67/00 ,  C07F15/00 ,  C22B3/26 ,  C22B3/28

CPC分类号： B01J31/4046 ,  B01J31/04 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/2404 ,  B01J31/26 ,  B01J31/4038 ,  C01G55/00 ,  C01G55/001 ,  C01G55/005 ,  C07C51/56 ,  C07C67/36 ,  C07C67/37 ,  C22B3/0009 ,  C22B3/001 ,  C22B3/0012 ,  B01J2231/34 ,  B01J23/40 ,  B01J2531/82 ,  B01J2531/822 ,  B01J27/08 ,  B01J31/0237 ,  Y02P10/234 ,  Y02P20/584

摘要： Residues are formed in the carbonylation of esters or ethers, particularly in the production of acetic anhydride or ethylidene diacetate. When such residues contain noble metal, typically rhodium, used as a catalyst, the noble metals must be recovered before the residues can be disposed of. The metal values are freed from the residues by treatment with amines, thereby enabling the rhodium to be extracted by subsequent contact with an aqueous halogen acid. The residues are pretreated with alkanols and concentrated by evaporation to improve the effect of such amine treatments.

摘要翻译： 残留物在酯或醚的羰基化中形成，特别是在制备乙酸酐或亚乙基二乙酸酯时。 当这种残留物含有用作催化剂的贵金属（通常为铑）时，贵金属必须在残留物被处理之前被回收。 金属值通过用胺处理从残余物中除去，从而使铑通过随后与卤酸水溶液的接触而被萃取。 残余物用链烷醇预处理并通过蒸发浓缩以改善这种胺处理的效果。

公开(公告)号：US4330376A

公开(公告)日：1982-05-18

申请号：US169534

申请日：1980-07-17

申请人： Sudarshan Lal ,  Richard V. Porcelli

发明人： Sudarshan Lal ,  Richard V. Porcelli

IPC分类号： C23C30/00 ,  C23F13/00 ,  C25D3/50

CPC分类号： C25D3/50 ,  C23C30/00 ,  C23F13/005

摘要： A process is provided for inhibiting the rate of corrosion of titanium metal surfaces from attack by strong acid media in which at least a portion of the titanium metal surface is coated with rhodium metal to provide a treated metal surface which is substantially impervious to corrosion by strong acid media. The article so prepared appears to be uniquely impervious to corrosion by strong acid media and is also claimed herein.

摘要翻译： 提供了一种用于抑制钛金属表面的腐蚀速度被强酸介质侵蚀的方法，其中至少一部分钛金属表面被铑金属涂覆以提供经过处理的金属表面，该表面基本上不受腐蚀强烈 酸性介质。 如此制备的制品似乎对强酸性介质的腐蚀是独一无二的，并且也在此要求保护。

公开(公告)号：US4252741A

公开(公告)日：1981-02-24

申请号：US949344

申请日：1978-10-06

申请人： Richard V. Porcelli ,  Vijay S. Bhise ,  Arnold J. Shapiro

发明人： Richard V. Porcelli ,  Vijay S. Bhise ,  Arnold J. Shapiro

IPC分类号： C07C53/00 ,  B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C51/00 ,  C07C51/56 ,  C07C53/12 ,  C07C67/00

CPC分类号： C07C51/56

摘要： In the carbonylation of alkyl esters in the presence of a Group VIII noble metal catalyst to produce a reaction mixture comprising volatile components and the non-volatile Group VIII noble metal catalyst, and the volatile components are separated from the catalyst, catalyst activity is maintained by providing a partial pressure of hydrogen of at least 10 psi during the separation of the volatile products. A partial pressure of at least 15 psi of carbon monoxide is also preferably provided, particularly when a metal promoter for the Group VIII noble metal catalyst is present, during such separation.

摘要翻译： 在VIII族贵金属催化剂存在下羰基化烷基酯以产生包含挥发性组分和非挥发性VIII族贵金属催化剂的反应混合物，并将挥发性组分与催化剂分离，催化剂活性由 在分离挥发性产物期间提供至少10psi的氢的分压。 还优选提供至少15psi的一氧化碳的分压，特别是在这种分离期间，存在第VIII族贵金属催化剂的金属助催化剂。