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1.发明授权公开(公告)号：US10138128B2
公开(公告)日：2018-11-27
申请号：US14174715
申请日：2014-02-06
IPC分类号： H05H1/00 , C01B32/16 , B01J21/18 , B01J23/745 , B01J35/00 , B01J37/02 , B82Y30/00 , B82Y40/00 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , C01B32/162
摘要： A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application systems for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
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2.发明申请公开(公告)号：US20170240425A9
公开(公告)日：2017-08-24
申请号：US14174715
申请日：2014-02-06
IPC分类号： C01B31/02
CPC分类号： C01B32/16 , B01J21/185 , B01J23/745 , B01J35/0013 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/162 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , Y10S977/842 , Y10T428/2495 , Y10T428/25
摘要： A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application systems for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
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公开(公告)号：US09650501B2
公开(公告)日：2017-05-16
申请号：US15245081
申请日：2016-08-23
CPC分类号： C08K9/04 , C08J3/203 , C08K7/06 , C08K7/24 , C08K2201/011 , Y02P20/582
摘要： Carbon nanostructures free of an adhered growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Under applied shear, crosslinks between the carbon nanotubes in carbon nanostructures can break to form fractured carbon nanotubes that are branched and share common walls. Methods for making polymer composites from carbon nanostructures can include combining a polymer matrix and a plurality of carbon nanostructures that are free of an adhered growth substrate, and dispersing the carbon nanostructures in the polymer matrix under applied shear. The applied shear breaks crosslinks between the carbon nanotubes to form a plurality of fractured carbon nanotubes that are dispersed as individuals in the polymer matrix. Polymer composites can include a polymer matrix and a plurality of fractured carbon nanotubes dispersed as individuals in the polymer matrix.
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4.发明授权Composite materials formed by shear mixing of carbon nanostructures and related methods 有权通过碳纳米结构剪切混合形成的复合材料和相关方法公开(公告)号：US09447259B2
公开(公告)日：2016-09-20
申请号：US14040529
申请日：2013-09-27
CPC分类号： C08K9/04 , C08J3/203 , C08K7/06 , C08K7/24 , C08K2201/011 , Y02P20/582
摘要： Carbon nanostructures free of an adhered growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Under applied shear, crosslinks between the carbon nanotubes in carbon nanostructures can break to form fractured carbon nanotubes that are branched and share common walls. Methods for making polymer composites from carbon nanostructures can include combining a polymer matrix and a plurality of carbon nanostructures that are free of an adhered growth substrate, and dispersing the carbon nanostructures in the polymer matrix under applied shear. The applied shear breaks crosslinks between the carbon nanotubes to form a plurality of fractured carbon nanotubes that are dispersed as individuals in the polymer matrix. Polymer composites can include a polymer matrix and a plurality of fractured carbon nanotubes dispersed as individuals in the polymer matrix.
摘要翻译： 没有附着生长衬底的碳纳米结构可以包括多个分支，交联和共享共同的壁的碳纳米管。 在施加的剪切下，碳纳米管结构中的碳纳米管之间的交联可能破裂，形成分支并共享共同壁的断裂碳纳米管。 用于从碳纳米结构制备聚合物复合材料的方法可以包括组合聚合物基质和多个没有附着的生长基底的碳纳米结构，并且在施加的剪切下将碳纳米结构分散在聚合物基质中。 施加的剪切破坏了碳纳米管之间的交联，以形成多个作为个体分散在聚合物基质中的断裂碳纳米管。 聚合物复合材料可以包括聚合物基质和作为个体分散在聚合物基质中的多个断裂碳纳米管。
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公开(公告)号：US09574300B2
公开(公告)日：2017-02-21
申请号：US14581908
申请日：2014-12-23
IPC分类号： D06M11/74 , D02G3/16 , D03D15/00 , D04H1/4242 , D04H1/76 , C01B31/02 , B01J23/74 , B01J23/745 , B01J23/75 , B01J23/755 , B82Y30/00 , B82Y40/00 , D06M101/40
CPC分类号： D06M11/74 , B01J23/74 , B01J23/745 , B01J23/75 , B01J23/755 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/164 , D02G3/16 , D03D15/00 , D03D15/0088 , D04H1/4242 , D04H1/76 , D06M2101/40 , D10B2101/06 , D10B2101/08 , D10B2101/12 , D10B2101/122 , D10B2101/20 , D10B2331/021 , D10B2401/063 , Y10S977/742 , Y10S977/75 , Y10S977/752 , Y10S977/843 , Y10T428/249948 , Y10T428/292 , Y10T428/2924 , Y10T442/3057 , Y10T442/605
摘要： A composition includes a carbon nanotube (CNT)-infused carbon fiber material that includes a carbon fiber material of spoolable dimensions and carbon nanotubes (CNTs) infused to the carbon fiber material. The infused CNTs are uniform in length and uniform in distribution. The CNT infused carbon fiber material also includes a barrier coating conformally disposed about the carbon fiber material, while the CNTs are substantially free of the barrier coating. A continuous CNT infusion process includes: (a) functionalizing a carbon fiber material; (b) disposing a barrier coating on the functionalized carbon fiber material (c) disposing a carbon nanotube (CNT)-forming catalyst on the functionalized carbon fiber material; and (d) synthesizing carbon nanotubes, thereby forming a carbon nanotube-infused carbon fiber material.
摘要翻译： 组合物包括碳纳米管（CNT） - 不含碳纤维材料，其包括可卷绕尺寸的碳纤维材料和注入碳纤维材料的碳纳米管（CNT）。 注入的CNT长度均匀，分布均匀。 CNT注入的碳纤维材料还包括围绕碳纤维材料保形地设置的阻挡涂层，而CNT基本上没有阻挡涂层。 连续CNT浸渍工艺包括：（a）使碳纤维材料官能化; （b）在官能化的碳纤维材料上设置阻挡涂层（c），将碳纳米管（CNT）形成催化剂置于官能化碳纤维材料上; 和（d）合成碳纳米管，从而形成碳纳米管注入的碳纤维材料。
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公开(公告)号：US09573812B2
公开(公告)日：2017-02-21
申请号：US14582034
申请日：2014-12-23
IPC分类号： C01B31/02 , B22F3/00 , C22C47/04 , B05C3/12 , B05D7/20 , C23C16/02 , C23C16/26 , C23C16/453 , C23C16/54 , B05D1/18 , B05D7/00
CPC分类号： C01B31/0226 , B05C3/125 , B05D1/18 , B05D7/20 , B05D7/544 , B22F3/002 , C01B32/16 , C22C47/04 , C23C16/02 , C23C16/0272 , C23C16/26 , C23C16/453 , C23C16/545 , Y10S977/742 , Y10S977/75 , Y10S977/752 , Y10S977/843 , Y10T428/292 , Y10T428/2924
摘要： A composition includes a carbon nanotube (CNT)-infused metal fiber material which includes a metal fiber material of spoolable dimensions, a barrier coating conformally disposed about the metal fiber material, and carbon nanotubes (CNTs) infused to the metal fiber material. A continuous CNT infusion process includes: (a) disposing a barrier coating and a carbon nanotube (CNT)-forming catalyst on a surface of a metal fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the metal fiber material, thereby forming a carbon nanotube-infused metal fiber material.
摘要翻译： 组合物包括碳纳米管（CNT） - 金属纤维材料，其包括可卷绕尺寸的金属纤维材料，围绕金属纤维材料保形地设置的阻挡涂层，以及注入金属纤维材料的碳纳米管（CNT）。 连续CNT输注方法包括：（a）在可卷绕的尺寸的金属纤维材料的表面上设置阻挡涂层和形成碳纳米管（CNT）的催化剂; 和（b）在金属纤维材料上合成碳纳米管，由此形成碳纳米管注入的金属纤维材料。
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7.发明申请SYSTEM AND METHOD FOR SURFACE TREATMENT AND BARRIER COATING OF FIBERS FOR IN SITU CNT GROWTH 审中-公开用于表面处理的纤维的表面处理和遮蔽涂层的系统和方法公开(公告)号：US20140154412A1
公开(公告)日：2014-06-05
申请号：US14174715
申请日：2014-02-06
IPC分类号： C01B31/02
CPC分类号： C01B32/16 , B01J21/185 , B01J23/745 , B01J35/0013 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/162 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , Y10S977/842 , Y10T428/2495 , Y10T428/25
摘要： A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application systems for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
摘要翻译： 用于在纤维材料上合成碳纳米管（CNT）的系统包括：表面处理系统，其适于改变纤维材料的表面以接收要在其上生长碳纳米管的阻挡涂层，在表面下游的阻挡涂层施加系统 适于将阻挡涂层施加到经处理的纤维材料表面的处理系统以及用于部分固化所施加的阻隔涂层以增强CNT生长催化剂纳米颗粒的接收的阻隔涂层施加系统下游的阻隔涂层固化体系。
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