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公开(公告)号:US3706806A
公开(公告)日:1972-12-19
申请号:US3706806D
申请日:1970-01-28
Applicant: AQUITAINE PETROLE
Inventor: ESCLAMADON CHRISTIAN , LABAT YVES , SIGNOURET JEAN-BAPTISTE
IPC: C08K5/00 , C01B17/02 , C01B17/40 , C07C67/00 , C07C313/00 , C07C319/02 , C07C323/12 , C08K5/37 , C08L21/00 , C09D5/22 , C10M135/22 , C10N30/00 , C07C149/14
CPC classification number: C01B17/0243 , C07C323/00
Abstract: NEW DITHIOL COMPOUNDS INCLUDE A FORMAL GROUP AND HAVE THE GNERAL FORMULA HS-R-O-CH2-O-R-SH, IN WHICH R IS A HYDROCARBON GROUP OF FROM 1 TO 12 CARBON ATOMS, WHICH CAN BE SUBSTITUTED OR UNSUBSTITUTED ALIPHATIC, CYCLOALKYL OR AROMATIC RADICALS. THESE COMPOUNDS ARE PREPARED BY CAUSING A CHLORALKYL ALCOHOL (C1-R-OH) TO REACT WITH FORMALDEHYDE SO AS TO EFFECT THE ACETALIZATION OF THE ALCOHOL AND BY TREATING THE DICHLORO DIALKYL FORMAL WHICH IS OBTAINED WITH AN ACID SULPHIDE OF AN ALKALI METAL AND WITH HYDROGEN SULPHIDE. THESE NEW DITHIOL COMPOUNDS ARE USED FOR THE PLASTICISATION OF SULPHUR AND FOR TE PRODUCTION, AS NEW INDUSTRIAL PRODUCTS, OF PLASTICISED SULPHUR COMPOSITIONS.
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2.
公开(公告)号:US3862922A
公开(公告)日:1975-01-28
申请号:US39644473
申请日:1973-09-12
Applicant: AQUITAINE PETROLE
Inventor: SIGNOURET JEAN-BAPTISTE , LABAT YVES , ESCLAMADON CHRISTIAN
CPC classification number: C08G75/16 , C01B17/02 , C04B28/36 , E01C7/08 , E01C7/30 , E01C7/35 , E01F9/506 , C04B24/16 , C04B24/28
Abstract: A process for the preparation of organic dithiol polysulfides with a molecular weight of between 500 and 10,000, characterized by the fact that these products are obtained when a dihalogenated organic derivative and hydrogen sulfide react simultaneously with an alkaline polysulfide solution. New products are obtained by this process, using dichlorodiethyl formal and dichlorodibutyl formal. These dithiol polysulfides react with sulfur to form either plasticized sulfur, with many possible applications in the coating field, or polysulfide polymers, one of the applications of which is the modification of bitumens.
Abstract translation: 一种制备分子量在500至10,000之间的有机二硫醇多硫化物的方法,其特征在于当二卤代有机衍生物和硫化氢与碱性多硫化物溶液同时反应时获得这些产物。 通过该方法获得新产物,使用二氯二乙基甲缩醛和二氯正丁基甲醛。 这些二硫醇多硫化物与硫反应以形成增塑硫,在涂层领域有许多可能的应用,或多硫化物聚合物,其应用之一是改性沥青。
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公开(公告)号:US3459717A
公开(公告)日:1969-08-05
申请号:US3459717D
申请日:1967-06-26
Applicant: AQUITAINE PETROLE
Inventor: SIGNOURET JEAN-BAPTISTE
CPC classification number: C04B28/36 , C08G75/14 , C08G79/04 , C04B24/00 , C04B24/003
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公开(公告)号:US3560451A
公开(公告)日:1971-02-02
申请号:US3560451D
申请日:1968-02-12
Applicant: AQUITAINE PETROLE
Inventor: SIGNOURET JEAN-BAPTISTE
CPC classification number: C04B28/36 , C04B24/00 , C04B24/003 , C04B24/16
Abstract: A NONFLAMMABLE PLASTIC COMPOSITION IS OBTAINED BY MELTING TOGETHER SULFUR WITH THREE COMPOUNDS WHICH ARE: (1) A DITHIOPHOSPHORIC ACID ESTER ACRYLIC HYDROCARBYLS, (2) A VINYL-ARYL HYDROCARBON AND ( 3) A POLYTHIOMETHYLENE-ALKANOL RESIN, THE THREE COMPOUNDS ARE MIXED WITH THE MOLTEN SULFUR SEPARATELY OR JOINTLY, EXCEPT THAT THE ESTER (1) AND THE RESIN (3) ARE NEVER ADDED AT THE SAME TIME, AND THE MOMENTS OF THEIR ADDITION ARE SEPARATED BY A PERIOD OF HEATING THE MIXTURE AT 120 * TO 180*C.
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5.
公开(公告)号:US3465064A
公开(公告)日:1969-09-02
申请号:US3465064D
申请日:1967-03-02
Applicant: AQUITAINE PETROLE
Inventor: SIGNOURET JEAN-BAPTISTE
IPC: C01B17/02 , C04B28/36 , C08G75/14 , C08K3/06 , C08L23/00 , C08L23/02 , C08L81/02 , C09D5/22 , C09J123/02 , C08G43/02
CPC classification number: C08L81/02 , C01B17/0243 , C04B28/36 , C08G75/14 , C08K3/06 , C08L23/00 , C08L23/02 , C08L2666/14 , C08L2666/54 , C09D5/22 , C09J123/02 , C04B24/00 , C04B24/16 , C04B14/30 , C04B20/0048 , C04B40/02 , C04B14/22 , C04B16/08 , C04B24/28 , C08L81/00 , C08L2666/04
Abstract: 1,182,171. Treating polymers; polysulphide products; sulphur compositions. SOC. NATIONALE DES PETROLES D'AQUITAINE. 7 March, 1967 [11 March, 1966], No. 10685/67. Headings C3N, C3P and C3R. [Also in Divisions C5 and El] ' Plastic reaction products are prepared by heating while stirring at 100‹ to 200‹ C. 40 to 95 parts by weight of molten sulphur, 0-05 to 59.5 parts by weight of a dithiolpolysulphide and 0À05 to 59À5 parts by weight of an olefin polymer, and optionally up to 49À5 parts by weight of an ethylenically unsaturated compound until a homogeneous plastic is formed. Specified olefin polymers are polymers and copolymers of ethylene, propylene, butene, isobutene, pentenes, hexenes, heptenes and octenes. The dithiol polysulphide may be of formula where m is 0 to 17, R and R 1 are hydrogen or alkyl and p is at least 2; and may be prepared by reaction of a haloepoxy alkane, e.g. 1-chloro- 5,6 - epoxyhexane, 2 - chloro - 5,6 - epoxyhexane, 1 - chloro - 4,5 - epoxypentane, 1- chloro - 3,4 - epoxybutane, 2 - bromo - 3,4- epoxybutane, 1 - chloro - 2,3 - epoxybutane and 1 - chloro - 2,3 - epoxypropane, with hydrogen sulphide and an alkali or alkaline earth metal polysulphide in aqueous solution. Specified unsaturated compounds are isobutene, diisobutene, triisobutene, cyclopentene, cyclohexene, pinene, camphene, allo-ocimene, myrcene, styrene, a-methylstyrene, chlorostyrene, indene, allene, butadiene, isoprene, chloroprene, hexadiene-1,5, diallyl, dimethallyl, heptadiene- 1,6, cyclopentadiene, vinyl cyclopentadiene, vinyl cyclohexene, divinyl acetylene, divinyl benzene, trivinyl benzene and hexatriene. The products may be formed by the separate or simultaneous addition of the organic reactants to molten sulphur, or by prereacting the dithiol polysulphide with the unsaturated compound and optionally the sulphur. The products may be used for making traffic signs and, optionally mixed with sand or gravel, for covering ground. They may be used in paints and as a jointing medium. Examples describe (I) the preparation of a dithiol polysulphide by reacting sodium hydroxide, sulphur, hydrogen sulphide and epichlorohydrin; and the preparation of plastic compositions by reacting this product with sulphur and (II) polybutene, (III and VIII) polybutene and styrene, (VI) polyethylene, (IX and X) polyisobutylene and styrene, (XI) ethylene/propylene copolymer and a-methylstyrene, (XII) atactic polypropylene and (XIII) atactic polypropylene and chloroprene.
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