公开(公告)号：US20240183494A1

公开(公告)日：2024-06-06

申请号：US18285830

申请日：2022-03-31

Applicant: ARKEMA FRANCE

Inventor： Thibaut SAVART ,  Arthur BABEAU ,  Axel SALINIER ,  Gilles HOCHSTETTER ,  Alexandre HAUCK ,  Damien BUSCA

IPC: F17C1/06 ,  F16L9/04 ,  F16L9/12

CPC classification number: F17C1/06 ,  F16L9/04 ,  F16L9/12 ,  F17C2201/0104 ,  F17C2201/0147 ,  F17C2203/012 ,  F17C2203/0621 ,  F17C2203/0624 ,  F17C2203/066 ,  F17C2203/0673 ,  F17C2209/2163 ,  F17C2209/232 ,  F17C2221/012

Abstract: A multilayer structure, intended for the transportation, for the distribution or for the storage of a gas, in particular hydrogen, including, from the inside toward the outside, N composite reinforcing layer(s), deposited on one another, and being of a fibrous material in the form of continuous fibers which is impregnated by a composition of at least one semicrystalline thermoplastic polymer P1, the M.p. of which, as measured according to ISO 11357-3:2013, is greater than or equal to 150° C., or at least one amorphous thermoplastic polymer, the Tg of which is greater than 80° C., N being of from 1 to 2000 layers, and an outer sealing layer (1) cohesive with the outermost composite reinforcing layer (2) and including a composition of the at least one thermoplastic polymer P1, the composition of the outer sealing layer (1) resulting from at least the outermost composite reinforcing layer (2) cohesive with the sealing layer.

公开(公告)号：US20220063137A1

公开(公告)日：2022-03-03

申请号：US17415073

申请日：2019-12-16

Applicant: ARKEMA FRANCE

Inventor： Gilles HOCHSTETTER ,  Thibaut SAVART ,  Arthur Pierre BABEAU ,  Axel SALINIER

IPC: B29B15/12

Abstract: Method for manufacturing a material including a fibrous material with continuous fibres and a thermoplastic polymer matrix, the material being produced as a unidirectional band, the method including a step of pre-impregnation of a strand of the fibrous material by the matrix in powdered form, the pre-impregnation step being carried out in a fluidised bed including a grooved roller component, the strand being in contact with the surface of the roller component and including up to 0.1% by weight of sizing, the matrix rate being controlled by controlling the dwell time in the powder and by constantly controlling the tension of the strand when it is introduced into the fluidised bed.

公开(公告)号：US20210016523A1

公开(公告)日：2021-01-21

申请号：US17040230

申请日：2019-03-19

Applicant: ARKEMA FRANCE

Inventor： Gilles HOCHSTETTER ,  Thibaut SAVART ,  Arthur Pierre BABEAU ,  Anthony FLORENCIE ,  Patrice GAILLARD ,  Axel SALINIER

IPC: B29C70/52 ,  C08J5/04 ,  C08J5/24

Abstract: An impregnated fibrous material including at least one fibrous material of continuous fibers and: at least one non-reactive thermoplastic polymer matrix, or at least one reactive thermoplastic prepolymer, which is a precursor of the non-reactive thermoplastic polymer, optionally mixed with a chain extender, wherein the at least one non-reactive thermoplastic polymer or the reactive prepolymer is an amorphous polymer or prepolymer having a glass transition temperature such that Tg≥80° C., or is a semi-crystalline polymer or prepolymer having a melting temperature Tf≥150° C., the fiber content in the pre-impregnated fibrous material being between 45 and 65 volume %, and the average thickness of the impregnated fibrous material being less than or equal to 100 μm, independently of the number of fibers present in the fibrous material before impregnation.

公开(公告)号：US20250027607A1

公开(公告)日：2025-01-23

申请号：US18708442

申请日：2022-11-08

Applicant: ARKEMA FRANCE ,  COVESS

Inventor： Gilles HOCHSTETTER ,  Thibaut SAVART ,  Arthur BABEAU ,  Axel SALINIER ,  Tony VANSWIJGENHOVEN ,  Johan DE CLIPPELEIR

IPC: F17C1/16 ,  B32B5/28 ,  B32B27/12 ,  B32B27/34

Abstract: A tank comprising a multi-layer structure, for storing compressed gas, including in succession from inside to outside at least the three following layers: at least one sealing layer of a composition including at least one semi-crystalline thermoplastic polyamide having a Tm of less than or equal to 280° C., at least one intermediate composite reinforcing layer of a fibrous material in the form of continuous fibres impregnated with a composition including at least one semi-crystalline thermoplastic polyamide having a Tg of less than 100° C., at least one outer composite reinforcing layer of a fibrous material in the form of continuous fibres impregnated with a composition including at least one polyphthalamide having a Tg of greater than 80° C., the outermost sealing layer being welded to the innermost intermediate composite reinforcing layer and the outermost intermediate composite reinforcing layer being welded to the innermost outer composite reinforcing layer.

公开(公告)号：US20200216627A1

公开(公告)日：2020-07-09

申请号：US16624441

申请日：2018-06-21

Applicant: ARKEMA FRANCE

Inventor： Gilles HOCHSTETTER ,  Mathieu CAPELOT ,  Thibaut SAVART ,  Arthur Pierre BABEAU ,  Denis HUZE ,  François TANGUY ,  Patrice GAILLARD

IPC: C08J5/24

Abstract: The present invention relates to an impregnated fibrous material comprising a fibrous material made of continuous fibers and at least one reactive thermoplastic prepolymer, and optionally a chain extender, characterized in that the at least one reactive thermoplastic prepolymer is partially polymerized, optionally with the chain extender, and has a number-average molecular weight (Mn) ranging from 500 to 10,000, preferably from 4,000 to 8000, the proportion of fibers in the impregnated fibrous material being 45 to 65% by volume, preferably 50 to 60% by volume, and in particular 54 to 60%.

公开(公告)号：US20160347009A1

公开(公告)日：2016-12-01

申请号：US15117312

申请日：2015-02-11

Applicant: ARKEMA FRANCE

Inventor： Patrice GAILLARD ,  Gilles HOCHSTETTER ,  Thibaut SAVART

IPC: B29C70/50 ,  B29B15/12

CPC classification number: B29C70/504 ,  B29B15/12 ,  B29B15/125 ,  B29K2101/12 ,  B29K2105/08 ,  B29K2507/04 ,  B29L2007/007

Abstract: A method of manufacturing a pre-impregnated fibrous material produced as a plurality of unidirectional parallel tapes, said method including the following steps: i) impregnation of the fibrous material while it is in the form of several parallel rovings, said impregnation step including: ia) immersion in a bath containing an aqueous dispersion of thermoplastic polymer, said immersion being followed by ib) drying, then ii) shaping by calendering, using at least one heated calender, into the form of a plurality of unidirectional parallel tapes using said calender including a plurality of calendering grooves according to the number of said tapes and with a pressure and/or separation between the rolls of said calender regulated by a control system.

Abstract translation: 一种制造作为多个单向平行带的预浸渍纤维材料的方法，所述方法包括以下步骤：i）当纤维材料以几个平行粗纱的形式浸渍时，所述浸渍步骤包括： ）浸入含有热塑性聚合物的水性分散体的浴中，所述浸渍之后是ib）干燥，然后ii）使用所述压延机使用至少一个加热的压延机通过压延成形为多个单向平行带的形式，包括 根据所述带的数量和由控制系统调节的所述压延机的辊之间的压力和/或分离的多个压延槽。

公开(公告)号：US20160030896A1

公开(公告)日：2016-02-04

申请号：US14775239

申请日：2014-03-11

Applicant: POLYMEN ,  ARKEMA FRANCE ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE PAUL SABATIER TOULOUSE

Inventor： Olivier LORAIN ,  Jean-Michel ESPENAN ,  Jean-Christophe REMIGY ,  Jean-Francois LAHITTE ,  Jean-Christophe ROUCH ,  Thibaut SAVART ,  Pierre GERARD ,  Stephanie MAGNET

IPC: B01D71/80 ,  C08L53/00 ,  C02F1/44 ,  C08F293/00

CPC classification number: B01D71/80 ,  B01D67/0011 ,  B01D71/34 ,  B01D71/40 ,  C02F1/44 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/02 ,  C08L53/00 ,  C08F220/14 ,  C08F2220/1825 ,  C08F220/20 ,  C08L27/16

Abstract: A copolymer having amphiphilic blocks includes at least one first hydrophilic block, obtainable from n-butyl acrylate and hydroxyethyl methacrylate monomers, and a second hydrophobic block likely to be obtained from a methyl methacrylate monomer. The copolymer is found to be particularly advantageous for use as an additive for manufacturing a polymer filtration membrane, particularly a PVDF membrane, particularly via a phase inversion method.

Abstract translation: 具有两亲性嵌段的共聚物包括至少一种可从丙烯酸正丁酯和甲基丙烯酸羟乙酯单体获得的第一亲水嵌段和可能由甲基丙烯酸甲酯单体获得的第二疏水嵌段。 发现该共聚物特别有利于用作制备聚合物过滤膜，特别是PVDF膜的添加剂，特别是通过相转化法。

公开(公告)号：US20250003530A1

公开(公告)日：2025-01-02

申请号：US18292805

申请日：2022-07-27

Applicant: ARKEMA FRANCE

Inventor： Gilles HOCHSTETTER ,  Thibaut SAVART ,  Arthur BABEAU ,  Axel SALINIER

IPC: F16L9/12 ,  B29D23/00 ,  B29K77/00 ,  B29K105/08 ,  B29K309/08

Abstract: A tube including at least one cylindrical element made of a pultruded fibrous material impregnated with a thermoplastic matrix, at least one additional fibrous reinforcement, partially or completely surrounding the cylindrical element(s), the fibers contained in the additional fibrous reinforcement being positioned along an axis different from the longitudinal axis of the cylindrical element, the total content of fibers of the tube being of between 40% and 70% by volume, with respect to the volume of the matrix and of the fibers contained in the tube.

公开(公告)号：US20240376264A1

公开(公告)日：2024-11-14

申请号：US18286048

申请日：2022-03-31

Applicant: ARKEMA FRANCE

Inventor： Thibaut SAVART ,  Lise DEVES ,  Jean-Jacques FLAT ,  Florent ABGRALL

IPC: C08G69/26 ,  C08G69/28 ,  C08G69/36 ,  C08J5/24

Abstract: A composition for a thermoplastic composite material including: a) from 65% to 95% by weight of at least one reactive semicrystalline polyamide prepolymer with an average molar mass Mn of less than 5000 g/mol and having a volume-mean diameter D50 of the reactive semicrystalline polyamide prepolymer powder particles ranging from 10 to 300 μm, b) from 5% to 35% by weight of at least one flame retardant chosen from an at least partially meltable flame retardant in powder form and having a volume-mean diameter D50 of from 10 to 300 μm, and a non-meltable flame retardant in premilled powder form with a volume-mean diameter D50 of from 1 to 50 μm, and c) from 0 to 2% by weight of at least one additive, and said reactive polyamide prepolymer comprising or consisting of at least one Z/BACT/XT copolyamide.

公开(公告)号：US20240344661A1

公开(公告)日：2024-10-17

申请号：US18292690

申请日：2022-07-27

Applicant: ARKEMA FRANCE

Inventor： Gilles HOCHSTETTER ,  Thibaut SAVART ,  Arthur BABEAU ,  Axel SALINIER

IPC: F17C1/06 ,  B29C70/08 ,  B29C70/34 ,  B29C70/52 ,  B29K77/00 ,  B29K105/08 ,  B29K307/04 ,  B29K309/08 ,  B29K705/02 ,  B29L31/00

CPC classification number: F17C1/06 ,  B29C70/08 ,  B29C70/347 ,  B29C70/521 ,  B29K2077/10 ,  B29K2105/08 ,  B29K2307/04 ,  B29K2309/08 ,  B29K2705/02 ,  B29L2031/7156 ,  F17C2201/0104 ,  F17C2203/012 ,  F17C2203/0604 ,  F17C2203/0629 ,  F17C2203/067 ,  F17C2203/0673 ,  F17C2205/0311 ,  F17C2209/2154 ,  F17C2209/232 ,  F17C2221/011 ,  F17C2221/012 ,  F17C2221/014 ,  F17C2221/031 ,  F17C2221/033 ,  F17C2221/035 ,  F17C2223/0161

Abstract: A tank for containing a pressurized fluid, including at least one cylindrical element made of a pultruded fibrous material impregnated with a thermoplastic matrix, a first cap placed at one end of at least one cylindrical element closing it, a second cap placed at the other end of at least one cylindrical element, fitted with an orifice intended to make possible the entry and the exit of the fluid, and at least one additional fibrous reinforcement, partially or completely surrounding the cylindrical element(s) and optionally the caps, the fibers contained in the additional fibrous reinforcement being positioned along a different axis from the longitudinal axis of the cylindrical element, the total content of fibers of the tank being of between 40% and 70% by volume, with respect to the volume of the matrix and of the fibers contained in the tank.