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1.发明授权Nickel electrode active material; a nickel electrode and a nickel alkali storage cell using such nickel electrode active material; and production methods of such material, electrode, and cell 失效镍电极活性物质; 镍电极和使用这种镍电极活性材料的镍碱存储电池; 和这种材料，电极和电池的生产方法
公开(公告)号：US5629111A
公开(公告)日：1997-05-13
申请号：US529980
申请日：1995-09-19
CPC分类号： H01M4/52
摘要： Fine-grained nickel electrode active material, each of which contributing to electrode reaction; production method of the fine-grained nickel electrode active material; and a nickel alkali storage cell of high capacity which is excellent in over discharge characteristics. In order to produce the fine-grained nickel electrode active material, fine-grained nickel hydroxide is precipitated by adding a given amount of alkali to solution in which at least a nickel compound is dissolved while the solution is stirred. Each of the fine-grained nickel hydroxide has pores with 20 vol % or more of a combined volume of the pores being composed of pores of diameter 60 .ANG. or greater. Next, a given amount of alkali is gradually added to suspension including the fine-grained nickel hydroxide and dissolved cobalt compound so that cobalt hydroxide is precipitated on the external surface of the fine-grained nickel hydroxide. The fine-grained nickel electrode active material is produced in the above mentioned way. Each of the fine-grained nickel electrode active material comprises a nickel hydroxide and cobalt oxide having distorted crystal structure and oxidation number higher than +2. The nickel hydroxide has pores whose diameters are 60 .ANG. or greater. And the volume of such pores amounts to 20 vol % or more of the combined volume of all of the pores.
摘要翻译： 细粒镍电极活性物质，各有助于电极反应; 细粒镍电极活性物质的制备方法; 以及高放电特性优异的高容量镍碱性电池。 为了生产细粒镍电极活性材料，在搅拌溶液的过程中，向至少溶解有镍化合物的溶液中加入规定量的碱，使细粒状氢氧化镍析出。 每种细粒度氢氧化镍具有孔直径为60以上的孔的组合体积的20vol％以上的孔。 接着，向包含细粒度氢氧化镍和溶解的钴化合物的悬浮液中逐渐加入给定量的碱，使得氢氧化钴在细粒状氢氧化镍的外表面析出。 以上述方式制造细粒镍电极活性物质。 每种细粒镍电极活性材料都包含氢氧化镍和氧化钴，晶体结构变形，氧化数高于+2。 氢氧化镍具有直径为60或更大的孔。 这些孔的体积相当于所有孔的组合体积的20体积％以上。
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2.发明授权
公开(公告)号：US5672447A
公开(公告)日：1997-09-30
申请号：US670170
申请日：1996-06-27
CPC分类号： H01M4/52 , C01G53/006 , C01G53/42 , H01M4/32 , C01P2002/54 , C01P2002/72 , C01P2004/84 , C01P2006/40 , H01M10/30 , H01M10/345 , Y10T29/49108
摘要： A alkali storage cell includes a non-sintered type nickel electrode which includes a highly efficient nickel hydroxide active material and which causes no capacity decrease during an over-discharge operation. The nickel electrode contains an active material composed of nickel hydroxide, a solid solution of at least one of zinc, cadmium, magnesium, and calcium which are added to the nickel hydroxide, and cobalt compound layers which are formed over the surfaces of particles of the nickel hydroxide. The cobalt compound layers have an oxidation number of larger than 2 and a disordered crystal structure. Such an active material can be manufactured by mixing nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium with either metallic cobalt or a cobalt compound, and subjecting the mixture to heat treatment in the presence of oxygen and alkali. Another production method is to precipitate a cobalt compound over the surfaces of the nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium so as to form cobalt compound layers, before subjecting it to the heat treatment in the same conditions.
摘要翻译： 碱性蓄电池包括非烧结型镍电极，其包括高效氢氧化镍活性材料，并且在过放电操作期间不引起容量减小。 镍电极含有由氢氧化镍组成的活性物质，添加到氢氧化镍中的锌，镉，镁和钙中的至少一种的固溶体，以及形成在氧化镍颗粒表面上的钴化合物层 氢氧化镍。 钴化合物层具有大于2的氧化数和无序的晶体结构。 可以通过将含有锌，镉，镁和钙中的至少一种的固溶体的氢氧化镍粉末与金属钴或钴化合物混合并在氧气存在下进行热处理来制造这种活性物质 和碱。 另一种制造方法是在含有锌，镉，镁和钙中的至少一种的固溶体的氢氧化镍粉末的表面上析出钴化合物，以形成钴化合物层，然后在其中进行热处理 条件相同。
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3.发明授权公开(公告)号：US06632568B1
公开(公告)日：2003-10-14
申请号：US08929253
申请日：1997-09-15
IPC分类号： H01M452
CPC分类号： H01M4/52 , C01G53/006 , C01G53/42 , C01P2002/54 , C01P2002/72 , C01P2004/84 , C01P2006/40 , H01M4/32 , H01M10/30 , H01M10/345 , Y10T29/49108
摘要： A alkali storage cell includes a non-sintered type nickel electrode which includes a highly efficient nickel hydroxide active material and which causes no capacity decrease during an over-discharge operation. The nickel electrode contains an active material composed of nickel hydroxide, a solid solution of at least one of zinc, cadmium, magnesium, and calcium which are added to the nickel hydroxide, and cobalt compound layers which are formed over the surfaces of particles of the nickel hydroxide. The cobalt compound layers have an oxidation number of larger than 2 and a disordered crystal structure. Such an active material can be manufactured by mixing nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium with either metallic cobalt or a cobalt compound, and subjecting the mixture to heat treatment in the presence of oxygen and alkali. Another production method is to precipitate a cobalt compound over the surfaces of the nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium so as to form cobalt compound layers, before subjecting it to the heat treatment in the same conditions.
摘要翻译： 碱性蓄电池包括非烧结型镍电极，其包括高效氢氧化镍活性材料，并且在过放电操作期间不引起容量减小。 镍电极含有由氢氧化镍组成的活性物质，添加到氢氧化镍中的锌，镉，镁和钙中的至少一种的固溶体，以及形成在氧化镍颗粒表面上的钴化合物层 氢氧化镍。 钴化合物层具有大于2的氧化数和无序的晶体结构。 可以通过将含有锌，镉，镁和钙中的至少一种的固溶体的氢氧化镍粉末与金属钴或钴化合物混合并在氧气存在下进行热处理来制造这种活性物质 和碱。 另一种制造方法是在含有锌，镉，镁和钙中的至少一种的固溶体的氢氧化镍粉末的表面上析出钴化合物，以形成钴化合物层，然后在其中进行热处理 相同的条件。
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公开(公告)号：US5688616A
公开(公告)日：1997-11-18
申请号：US671199
申请日：1996-06-27
CPC分类号： H01M4/52 , C01G53/006 , C01G53/42 , H01M4/32 , C01P2002/54 , C01P2002/72 , C01P2004/84 , C01P2006/40 , H01M10/30 , H01M10/345 , Y10T29/49108
摘要： A alkali storage cell includes a non-sintered type nickel electrode which includes a highly efficient nickel hydroxide active material and which causes no capacity decrease during an over-discharge operation. The nickel electrode contains an active material composed of nickel hydroxide, a solid solution of at least one of zinc, cadmium, magnesium, and calcium which are added to the nickel hydroxide, and cobalt compound layers which are formed over the surfaces of particles of the nickel hydroxide. The cobalt compound layers have an oxidation number of larger than 2 and a disordered crystal structure. Such an active material can be manufactured by mixing nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium with either metallic cobalt or a cobalt compound, and subjecting the mixture to heat treatment in the presence of oxygen and alkali. Another production method is to precipitate a cobalt compound over the surfaces of the nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium so as to form cobalt compound layers, before subjecting it to the heat treatment in the same conditions.
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5.发明授权Nickel active material for use in alkali storage cells and its manufactuiring method 失效用于碱性储存电池的镍活性材料及其制造方法
公开(公告)号：US5691086A
公开(公告)日：1997-11-25
申请号：US598598
申请日：1996-02-12
CPC分类号： H01M4/28 , H01M4/32 , H01M4/52 , H01M10/30 , H01M10/345 , Y02E60/124
摘要： A nickel active material for an alkali storage cell whose surface is covered with a cobalt compound, wherein the diffusion and permeation into the nickel hydroxide mother particles of cobalt compound during excessive discharging, which act to reduce the active material efficiency and the excessive discharging characteristics, are prevented. This is achieved by having a covering layer, including one or more of the following metal compounds; an aluminum compound, a magnesium compound, an indium compound and a zinc compound, in addition to a cobalt compound, formed on the surface of a mother particle of nickel hydroxide, and by heat treating the covered mother particles in the presence of alkali and oxygen so as to convert the cobalt compound into a compound of cobalt where an oxidization number of cobalt is greater than 2.
摘要翻译： 一种表面被钴化合物覆盖的碱性蓄电池用镍活性物质，其特征在于，在过量放电中扩散渗透到钴化合物的氢氧化镍母粒中，其作用是降低活性物质效率和过度的放电特性， 被阻止 这通过具有包括一种或多种以下金属化合物的覆盖层来实现; 铝化合物，镁化合物，铟化合物和锌化合物，除了形成在氢氧化镍母体表面上的钴化合物之外，还在碱和氧的存在下热处理被覆盖的母体颗粒 以便将钴化合物转化为钴的化合物，其中钴的氧化数大于2。
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公开(公告)号：US06653023B1
公开(公告)日：2003-11-25
申请号：US09534174
申请日：2000-03-24
申请人： Masao Inoue , Takeo Hamamatsu , Takashi Nagase , Hideyuki Asanuma
发明人： Masao Inoue , Takeo Hamamatsu , Takashi Nagase , Hideyuki Asanuma
IPC分类号： H01M402
CPC分类号： H01M10/0413 , H01M2/0207 , H01M2/162 , H01M6/46 , H01M10/0436 , H01M10/0454 , Y10T29/49115
摘要： A rectangular alkaline storage battery includes an electrode plate which can be easily prepared and has a high packing density of active material and volumetric energy density. A connected negative electrode plate with hydrogen-absorbing alloy negative electrode plates is bent into a U-shaped form at a central portion (connecting portion). A composite positive electrode plate is then sandwiched by the hydrogen-absorbing alloy negative electrode plates with a separator made of an unwoven polypropylene fabric provided interposed therebetween to prepare an electrode plate unit. Two such electrode plate units are then laminated to form a group of electrode plates.
摘要翻译： 矩形碱性蓄电池包括可以容易地制备并且具有高活性材料的堆积密度和体积能量密度的电极板。 具有吸氢合金负极板的连接的负极板在中心部分（连接部分）弯曲成U形。 然后将复合正极板用吸附合金负极板夹在由隔着聚丙烯织物的隔板制成的隔板上，制成电极板单元。 然后将两个这样的电极板单元层叠以形成一组电极板。
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公开(公告)号：US06103424A
公开(公告)日：2000-08-15
申请号：US38133
申请日：1998-03-11
申请人： Takeo Hamamatsu , Masao Inoue , Takashi Nagase , Satoru Kometani , Nobuyoshi Oi , Hirofumi Sako , Hiroshi Sato , Tadashi Ise , Yasushi Kuroda
发明人： Takeo Hamamatsu , Masao Inoue , Takashi Nagase , Satoru Kometani , Nobuyoshi Oi , Hirofumi Sako , Hiroshi Sato , Tadashi Ise , Yasushi Kuroda
CPC分类号： H01M10/0413 , H01M10/0454 , H01M10/281 , H01M10/287 , H01M10/345 , H01M2010/4292
摘要： A rectangular battery having an electrode group which is inserted in a battery case having an airtight structure. The electrode group is formed by alternately stacking positive electrodes and negative electrodes via separators. The battery case is rectangular had has a closed bottom and an open part that is airtightly sealed by a cover. The outermost electrodes, which are located on both faces of the electrode group, are coated with an active material on a surface of a core. Furthermore, the outermost electrodes have the same polarity and the cores thereof directly contact an inside surface of the outer battery case. In one embodiment, the capacity of the outermost electrodes is smaller than the capacity of the inwardly disposed electrodes of the same polarity.
摘要翻译： 一种具有插入具有气密结构的电池壳体中的电极组的矩形电池。 电极组通过隔膜交替堆叠正极和负极而形成。 电池盒是矩形的，具有封闭的底部和通过盖子气密密封的敞开部分。 位于电极组的两个表面上的最外面的电极在芯的表面上涂覆有活性材料。 此外，最外面的电极具有相同的极性，并且其核心直接接触外部电池壳体的内表面。 在一个实施例中，最外面的电极的容量小于相同极性的向内设置的电极的容量。
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公开(公告)号：US06468687B1
公开(公告)日：2002-10-22
申请号：US09531672
申请日：2000-03-20
申请人： Teruhito Nagae , Kenji Arisawa , Etsuya Fujisaka , Masao Takee , Takeo Hamamatsu , Taishi Maeda , Satoru Kometani
发明人： Teruhito Nagae , Kenji Arisawa , Etsuya Fujisaka , Masao Takee , Takeo Hamamatsu , Taishi Maeda , Satoru Kometani
IPC分类号： H01M214
CPC分类号： H01M2/1686 , H01M2/14 , H01M2/162 , H01M10/286 , H01M10/30 , H01M10/345 , Y02E60/124
摘要： An alkaline storage battery has a group of spiral electrodes composed of positive and negative electrode plates spirally wound with first and second separators respectively located at the outside of the positive electrode plate and at the inside of the positive electrode plate. The weight per unit area of the first separator is greater than that of the second separator.
摘要翻译： 碱性蓄电池具有由分别位于正极板的外部和正极板的内部的第一和第二隔板螺旋卷绕的正极板和负极板组成的一组螺旋电极。 第一分离器的每单位面积重量大于第二分离器的重量。
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公开(公告)号：US06399244B1
公开(公告)日：2002-06-04
申请号：US09537392
申请日：2000-03-29
申请人： Naoyoshi Hinotu , Takeo Hamamatsu , Hiroki Ochi
发明人： Naoyoshi Hinotu , Takeo Hamamatsu , Hiroki Ochi
IPC分类号： H01M230
CPC分类号： H01M2/06 , H01M2/30 , H01M10/345 , Y02E60/124
摘要： An object of the invention is to provide a hermetically sealed rectangular battery which is not liable to melting of gasket during laser welding causing the deterioration of the battery airtightness as well as to occurrence of electrolyte leakage and accomplish further reduction of the thickness of the hermetically sealed rectangular battery. A hermetically sealed rectangular battery comprising a group of electrode plates received in a metallic can having a pair of opposing wide sides and a pair of opposing narrow sides, the group of electrode plates having a positive electrode plate and a negative electrode plate laminated on each other with a separator provided interposed therebetween, characterized in that the metallic can is provided with a terminal which also acts as an electrode of one of the two polarities on the wide side thereof.
摘要翻译： 本发明的目的是提供一种气密密封的矩形电池，其在激光焊接期间不易于垫圈熔化，导致电池气密性的劣化以及电解液泄漏的发生，并进一步降低了密封的厚度 矩形电池 一种气密密封的矩形电池，包括容纳在具有一对相对的宽边和一对相对的窄边的金属罐中的一组电极板，所述一组电极板具有彼此层叠的正极板和负极板 其中设置有隔板，其特征在于，所述金属罐设置有在其宽侧上也用作两极性之一的电极的端子。
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公开(公告)号：US06579640B1
公开(公告)日：2003-06-17
申请号：US09670193
申请日：2000-09-26
IPC分类号： H01M200
CPC分类号： H01M2/1229 , H01M2/0217 , H01M2/06 , H01M2/30 , H01M10/287 , H01M10/345
摘要： A sealed rectangular battery has a conductive battery case including an external casing and a sealing cap. The external casing encloses a generator element and is sealed by attaching the sealing cap using heat. The battery includes an electrode terminal with an opposite polarity to the battery case, and a safety valve. The safety valve includes a cap that is charged with the same polarity as the battery case and a valving element that covers a vent hole. The electrode terminal and safety valve are provided separately at different positions on the battery case. This construction is simpler than conventional batteries where the safety valve is integrally formed with an electrode terminal, which means that the electrode terminal can be miniaturized. This battery also has improved internal resistance.
摘要翻译： 密封的矩形电池具有包括外部壳体和密封盖的导电电池壳体。 外壳包围发电机元件，并通过使用热附接密封盖来密封。 电池包括与电池壳体相反极性的电极端子和安全阀。 安全阀包括带有与电池壳体相同极性的盖和覆盖通气孔的阀元件。 电极端子和安全阀分别设置在电池盒的不同位置。 这种结构比传统的电池简单，其中安全阀与电极端子一体形成，这意味着电极端子可以小型化。 该电池也具有改善的内阻。
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