公开(公告)号：US09624171B2

公开(公告)日：2017-04-18

申请号：US12995699

申请日：2009-05-27

申请人： Akira Matsumoto ,  Hisatoshi Kura ,  Katia Studer ,  Sébastien Villeneuve

发明人： Akira Matsumoto ,  Hisatoshi Kura ,  Katia Studer ,  Sébastien Villeneuve

IPC分类号： C07D209/86 ,  C07C251/66 ,  C08F2/50 ,  C09D11/101 ,  G03F7/00 ,  C07D333/38 ,  G03F7/029 ,  G03F7/031 ,  G03F7/105

CPC分类号： C07D209/86 ,  C07C251/66 ,  C07D333/38 ,  C08F2/50 ,  C09D11/101 ,  G03F7/0007 ,  G03F7/0037 ,  G03F7/029 ,  G03F7/031 ,  G03F7/105

摘要： Photoinitiator mixture comprising at least one alpha-amino ketone compound; and at least one compound of the Formula (I) or (I′) wherein R1 and R′1 for example are hydrogen, C3-C8cycloalkyl or C1-C12alkyl R2 and R2′ for example are hydrogen; unsubstituted C1-C20alkyl or substituted C1-C20alkyl; and R8 and R9 for example are hydrogen, C1-C12alkyl which optionally is substituted, or phenyl which optionally is substituted; exhibit an unexpectedly good performance in photopolymerization reactions.

公开(公告)号：US08586268B2

公开(公告)日：2013-11-19

申请号：US12086567

申请日：2006-11-09

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G02B5/20 ,  G03F7/031

CPC分类号： G03F7/031 ,  B33Y70/00 ,  C07D209/86 ,  C07D409/06 ,  C08F2/50 ,  G03F7/0007 ,  G03F7/001

摘要： Compounds of the Formula (I) and (II) wherein M1, M2 and M3 independently of one another are no bond, a direct bond, CO, O, S, SO, SO2 or NR14; provided that at least one of M1, M2 or M3 is a direct bond, CO, O, S, SO, SO2 or NR14; M4 is a direct bond, CR″3R″4, CS, O, S, SO, or SO2; Y is S or NR18; R1 for example is hydrogen, C3-C8cycloalkyl, phenyl or naphthyl, both of which are optionally substituted; R2 for example is C1-C20alkyl; R″2 has one of the meanings given for R2; R3 and R4 are for example hydrogen, halogen, C1-C20alkyl; R′3, R′4, R″3 and R″4 independently of one another have one of the meanings given for R3 and R4; and R5 is for example hydrogen, halogen, C1-C20alkyl; provided that in the compounds of the Formula (I) at least two oxime ester groups are present; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 其中M1，M2和M3彼此独立的式（I）和（II）的化合物不是键，直接键，CO，O，S，SO，SO 2或NR 14; 条件是M1，M2或M3中的至少一个是直接键，CO，O，S，SO，SO 2或NR 14; M4是直接键，CR''3R''4，CS，O，S，SO或SO2; Y为S或NR18; R 1例如是氢，C 3 -C 8环烷基，苯基或萘基，它们都是任选取代的; R 2例如是C 1 -C 20烷基; R'2具有R2中给出的含义之一; R3和R4是例如氢，卤素，C1-C20烷基; R 3，R'4，R“3和R”4彼此独立地具有R3和R4给出的含义之一; R5是例如氢，卤素，C1-C20烷基; 条件是在式（I）的化合物中存在至少两个肟酯基团; 在光聚合反应中表现出出人意料的良好性能。

公开(公告)号：US08507726B2

公开(公告)日：2013-08-13

申请号：US13127068

申请日：2009-10-23

申请人： Katia Studer ,  Sébastien Villeneuve ,  Akira Matsumoto ,  Hisatoshi Kura ,  Jan Sültemeyer

发明人： Katia Studer ,  Sébastien Villeneuve ,  Akira Matsumoto ,  Hisatoshi Kura ,  Jan Sültemeyer

IPC分类号： C07C259/00

CPC分类号： C08F2/50 ,  B33Y70/00 ,  C07D209/86 ,  C07D333/22 ,  G03F7/031

摘要： Photoinitiators mixture comprising (i) at least one compound selected from the group consisting of alpha-hydroxy ketones, monoacylphosphine oxides, bisacylphosphine oxides, ketosulfones, benzil ketals, benzoin ether, phenylglyoxylates, borates and titanocenes; and (ii) at least one compound of the formula (I) or (I′) R1, R′1, R2 and R2′ R′9 independently of each other for example are hydrogen or C1-C12alkyl R7, R8, R9, R′8 and R′9 independently of each other for example are hydrogen, C1-C12alkyl which optionally is substituted or phenyl which optionally is substituted, exhibit excellent photoinitiating properties.

摘要翻译： 光引发剂混合物，其包含（i）至少一种选自α-羟基酮，单酰基氧化膦，双酰基氧化膦，酮砜，苯偶酰缩酮，苯偶姻醚，苯基乙醛酸酯，硼酸酯和二茂钛的化合物; 和（ii）至少一种式（I）或（I'）R1，R'1，R2和R2'R'9彼此独立的化合物例如是氢或C 1 -C 12烷基R 7，R 8，R 9， R'8和R'9彼此独立地为氢，任选被取代的C 1 -C 12烷基或任选被取代的苯基表现出优异的光引发性能。

公开(公告)号：US20100188765A1

公开(公告)日：2010-07-29

申请号：US12086567

申请日：2006-11-09

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G03F7/004 ,  C07D209/58 ,  C08F2/50 ,  G03F7/20 ,  G03F7/031 ,  G02B5/22

CPC分类号： G03F7/031 ,  B33Y70/00 ,  C07D209/86 ,  C07D409/06 ,  C08F2/50 ,  G03F7/0007 ,  G03F7/001

摘要： Compounds of the Formula (I) and (II) wherein M1, M2 and M3 independently of one another are no bond, a direct bond, CO, O, S, SO, SO2 or NR14; provided that at least one of M1, M2 or M3 is a direct bond, CO, O, S, SO, SO2 or NR14; M4 is a direct bond, CR″3R″4, CS, O, S, SO, or SO2; Y is S or NR18; R1 for example is hydrogen, C3-C8cycloalkyl, phenyl or naphthyl, both of which are optionally substituted; R2 for example is C1-C20alkyl; R″2 has one of the meanings given for R2; R3 and R4 are for example hydrogen, halogen, C1-C20alkyl; R′3, R′4, R″3 and R″4 independently of one another have one of the meanings given for R3 and R4; and R5 is for example hydrogen, halogen, C1-C20alkyl; provided that in the compounds of the Formula (I) at least two oxime ester groups are present; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 其中M1，M2和M3彼此独立的式（I）和（II）的化合物不是键，直接键，CO，O，S，SO，SO 2或NR 14; 条件是M1，M2或M3中的至少一个是直接键，CO，O，S，SO，SO 2或NR 14; M4是直接键，CR“3R”4，CS，O，S，SO或SO 2; Y为S或NR18; R 1例如是氢，C 3 -C 8环烷基，苯基或萘基，它们都是任选取代的; R 2例如是C 1 -C 20烷基; R“2具有R2的含义之一; R3和R4是例如氢，卤素，C1-C20烷基; R'3，R'4，R“3和R”4彼此独立地具有R3和R4给出的含义之一; R5是例如氢，卤素，C1-C20烷基; 条件是在式（I）的化合物中存在至少两个肟酯基团; 在光聚合反应中表现出出人意料的良好性能。

公开(公告)号：US20090087759A1

公开(公告)日：2009-04-02

申请号：US12085383

申请日：2006-11-08

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G03F1/02 ,  C07D209/88 ,  C08F2/46 ,  G03F7/20

CPC分类号： C07D209/86 ,  C07D209/88 ,  C07D403/10 ,  C07D409/06 ,  C07D409/10 ,  G03F7/031

摘要： Compounds of the formula (I), (II), and wherein R1, R2, R′2 and R′″2 for example are C1-C20alkyl; R3, R4, and R5 for example independently of one another are hydrogen or a defined substituent provided that at least one of R3, R4 or R5 is other than hydrogen or C1-C20alkyl; R6, R7, R8, R′6, R′7, R′8, R″6, R″7, R′″6 and R′″7 for example independently of one another have one of the meanings as given for R3, R4, and R5; and R9 for example is C1-C20alkyl; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 式（I），（II）和其中R 1，R 2，R'2和R“2的化合物例如是C 1 -C 20烷基; R 3，R 4和R 5例如彼此独立地是氢或定义的取代基，条件是R 3，R 4或R 5中的至少一个不是氢或C 1 -C 20烷基; R6，R7，R8，R'6，R'7，R'8，R'6，R'7，R“'6和R”'7例如彼此独立地具有一个含义 如R3，R4和R5所示; 例如，R 9为C 1 -C 20烷基; 在光聚合反应中表现出出人意料的良好性能。

公开(公告)号：US08940464B2

公开(公告)日：2015-01-27

申请号：US12085383

申请日：2006-11-08

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G02B5/20 ,  G03F7/031

CPC分类号： C07D209/86 ,  C07D209/88 ,  C07D403/10 ,  C07D409/06 ,  C07D409/10 ,  G03F7/031

摘要： Compounds of the formula (I), (II), and wherein R1, R2, R′2 and R′″2 for example are C1-C20alkyl; R3, R4, and R5 for example independently of one another are hydrogen or a defined substituent provided that at least one of R3, R4 or R5 is other than hydrogen or C1-C20alkyl; R6, R7, R8, R′6, R′7, R′8, R″6, R″7, R′″6 and R′″7 for example independently of one another have one of the meanings as given for R3, R4, and R5; and R9 for example is C1-C20alkyl; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 式（I），（II）和其中R 1，R 2，R'2和R'2的化合物例如是C 1 -C 20烷基; R 3，R 4和R 5例如彼此独立地是氢或定义的取代基，条件是R 3，R 4或R 5中的至少一个不是氢或C 1 -C 20烷基; R 6，R 7，R 8，R'6，R'7，R'8，R“6，R”7，R“6和R”7例如彼此独立地具有如R3所给出的含义之一 ，R4和R5; 例如，R 9为C 1 -C 20烷基; 在光聚合反应中表现出出人意料的良好性能。

公开(公告)号：US08349548B2

公开(公告)日：2013-01-08

申请号：US12598601

申请日：2008-04-28

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G03F7/20 ,  C07D209/88 ,  C07D335/08 ,  B32B27/18 ,  C09K3/00 ,  C08F2/46 ,  G02B5/20

CPC分类号： C07D401/12 ,  B33Y70/00 ,  C07D417/06 ,  C08F2/50 ,  G03F7/031 ,  Y10T428/31855

摘要： Compounds of the formula (I), wherein A1 is formula (II); A2 is formula (III); A3 is formula (IV); A4 is formula (V); w, x, y and z independently of each other are an integer from 0-4, provided that the sum of x+y+z is an integer from 2-4, corresponding to the valency of Q; M1, M2, M3 and M4 for example are a direct bond, CO or O; Y for example is a direct bond or S; Q is a (x+y)-valent linking group; R1 is for example hydrogen, C1-C20alkyl or phenyl or naphthyl; R2 and R″2 for example are is hydrogen or C1-C20alkyl; R3, R4, R′3, R′4, R″3 and R″4 for example are hydrogen, halogen, phenyl, or C1-C20alkyl; and R24 is for example a direct bond; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 式（I）化合物，其中A1为式（II）; A2是式（III）; A3是式（IV）; A4是公式（V）; w，x，y和z彼此独立地是0-4的整数，条件是x + y + z的和是2-4的整数，对应于Q的化合价; M1，M2，M3和M4例如是直接键，CO或O; Y例如是直接债券或S; Q是（x + y）价的连接基团; R1是例如氢，C1-C20烷基或苯基或萘基; R2和R“2例如是氢或C1-C20烷基; R 3，R 4，R'3，R'4，R“3和R”4例如是氢，卤素，苯基或C 1 -C 20烷基; 并且R 24例如是直接键; 在光聚合反应中表现出出人意料的良好性能。

公开(公告)号：US20110218266A1

公开(公告)日：2011-09-08

申请号：US13127068

申请日：2009-10-23

申请人： Katia Studer ,  Sébastien Villeneuve ,  Akira Matsumoto ,  Hisatoshi Kura ,  Jan Sültemeyer

发明人： Katia Studer ,  Sébastien Villeneuve ,  Akira Matsumoto ,  Hisatoshi Kura ,  Jan Sültemeyer

IPC分类号： C08F2/46 ,  C09K3/00

CPC分类号： C08F2/50 ,  B33Y70/00 ,  C07D209/86 ,  C07D333/22 ,  G03F7/031

摘要： Photoinitiators mixture comprising (i) at least one compound selected from the group consisting of alpha-hydroxy ketones, monoacylphosphine oxides, bisacylphosphine oxides, ketosulfones, benzil ketals, benzoin ether, phenylglyoxylates, borates and titanocenes; and (ii) at least one compound of the formula (I) or (I′) R1, R′1, R2 and R2′ R′9 independently of each other for example are hydrogen or C1-C12alkyl R7, R8, R9, R′8 and R′9 independently of each other for example are hydrogen, C1-C12alkyl which optionally is substituted or phenyl which optionally is substituted, exhibit excellent photoinitiating properties.

摘要翻译： 光引发剂混合物，其包含（i）至少一种选自α-羟基酮，单酰基氧化膦，双酰基氧化膦，酮砜，苯偶酰缩酮，苯偶姻醚，苯基乙醛酸酯，硼酸酯和二茂钛的化合物; 和（ii）至少一种式（I）或（I'）R1，R'1，R2和R2'R'9彼此独立的化合物例如是氢或C 1 -C 12烷基R 7，R 8，R 9， R'8和R'9彼此独立地为氢，任选被取代的C 1 -C 12烷基或任选被取代的苯基表现出优异的光引发性能。

公开(公告)号：US20100136491A1

公开(公告)日：2010-06-03

申请号：US12598477

申请日：2008-04-24

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G03F7/20 ,  C07D209/88 ,  C07D209/80 ,  C07D417/12 ,  C08F2/46 ,  G02B5/22

CPC分类号： G03F7/027 ,  C07D209/80 ,  C07D209/86 ,  C07D209/88 ,  C07D403/10 ,  C07D409/06 ,  C07D409/14 ,  G02B5/20 ,  G03F7/2002 ,  G03F7/2037 ,  G03F7/2039 ,  G03F7/30

摘要： Compounds of formula (I), (II), and (III), wherein R1, R2, R′2 and R′″2 for example are C1-C20alkyl, provided that at least one of R1, R2, R′2 and R′″2 carries a specified substituent; R3, R4, and R5 for example independently of one another are hydrogen or a defined substituent provided that at least one of R3, R4 or R5 is other than hydrogen or C1-C20alkyl; R6, R7, R8, R′7, RV, R′8, R″6, R″7, R′″6 and R′″7 for example independently of one another have one of the meanings as given for R3, R4, and R5; and R9 for example is C1-C20alkyl; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 式（I），（II）和（III）的化合物，其中R 1，R 2，R'2和R'2例如是C 1 -C 20烷基，条件是R 1，R 2，R'2和 R“2携带指定的取代基; R 3，R 4和R 5例如彼此独立地是氢或定义的取代基，条件是R 3，R 4或R 5中的至少一个不是氢或C 1 -C 20烷基; R6，R7，R8，R'7，RV，R'8，R“6，R”7，R“”6“和”7“，例如彼此独立地具有R 3，R 4 ，和R5; 例如，R 9为C 1 -C 20烷基; 在光聚合反应中表现出出人意料的良好性能。

公开(公告)号：US20100136467A1

公开(公告)日：2010-06-03

申请号：US12598481

申请日：2008-04-28

申请人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

发明人： Akira Matsumoto ,  Junichi Tanabe ,  Hisatoshi Kura ,  Masaki Ohwa

IPC分类号： G03F1/00 ,  C07D409/06 ,  C07D335/08 ,  C07D417/12 ,  C07D409/14 ,  G03F7/20

CPC分类号： C07D409/06 ,  B33Y70/00 ,  C07D209/86 ,  C07D335/16 ,  C07D405/12 ,  C07D409/14 ,  C07D417/12

摘要： Compounds of the formula (I) and (II) M1, M2 and M3 independently of one another are no bond, a direct bond, CO, O, S, SO, SO2or NR14; provided that at least one of M1, M2 or M3 is a direct bond, CO, O, S, SO, SO2 or NR14; M4 is a direct bond, CR″3R″4, CS, O, S, SO, or SO2; Y is S or NR18; R1 for example is hydrogen, C3-C8cycloalkyl, phenyl or napthyl, both of which are optionally substituted; R2 for example is C1-C20alkyl; R″2 has one of the meanings given for R2; R3 and R4 are for example hydrogen, halogen, C1-C20alkyl; R′3, R′4, R″3 and R″4 indepedently of one another have one of the meanings given for R3 and R4; and R5 is for example hydrogen, halogen, C1-C20alkyl; provided that in the compounds of the formula (I) at least two oxime ester groups are present and provided that at least one specified substituent R2 or R″2 is present; exhibit an unexpectedly good performance in photopolymerization reactions.

摘要翻译： 式（I）和（II）中的M1，M2和M3彼此独立的化合物不是键，直接键，CO，O，S，SO，SO 2或NR 14; 条件是M1，M2或M3中的至少一个是直接键，CO，O，S，SO，SO 2或NR 14; M4是直接键，CR“3R”4，CS，O，S，SO或SO 2; Y为S或NR18; R 1例如是氢，C 3 -C 8环烷基，苯基或萘基，它们都是任选被取代的; R 2例如是C 1 -C 20烷基; R“2具有R2的含义之一; R3和R4是例如氢，卤素，C1-C20烷基; R'3，R'4，R“3和R”4彼此独立地具有R3和R4给出的含义之一; R5是例如氢，卤素，C1-C20烷基; 条件是在式（I）的化合物中存在至少两个肟酯基团，条件是存在至少一个特定的取代基R 2或R“2; 在光聚合反应中表现出出人意料的良好性能。