摘要:
A process for producing oxygen-containing compounds containing at least one oxygen atom bonded to two distinct carbon atoms which are not bonded together and not comprising a multiple bond comprises a step a) for hydroformylation of a feed comprising at least one olefin containing four to seven carbon atoms to at least one aldehyde, in the presence of a catalyst and a synthesis gas under hydroformylation conditions, a step b) for hydrogenation of this aldehyde to at least one corresponding alcohol, and a step c) for transforming at least one alcohol obtained from step b) in the presence of a catalyst under conditions for producing a mixture containing at least one ether or at least one acetal.
摘要:
Heavy crude transportation optimization method wherein at least one solvent is added to said crude. According to the method, a predetermined amount of dimethyl ether (DME) is added under pressure so as to adjust the viscosity of the crude.
摘要:
An enhanced ether production process from an olefinic cut containing at least one iso-olefin and from an alcohol comprises a stage of removal of the acetonitrile present in the hydrocarbon feed by liquid-liquid extraction, the extraction solvent being a non-aqueous ionic liquid of general formula Q+A−, wherein Q+ is an ammonium, phosphonium and/or sulfonium cation, and A− an anion likely to form a liquid salt with said cation. Advantageously, the method according to the invention generally allows the amount of water at the etherification reactor inlet to be divided by at least two and thus the purity of the ether produced to be improved.
摘要:
The invention describes materials comprising organic groups containing sulphur and phosphorous bonded together by a hydrocarbon chain and bonded via phosphorous and oxygen atoms to a mineral oxide of an element M, said materials being characterized in that they comprise M-O-M′ bonds, M′representing an element of a mineral oxide identical to or different from M, in that the ratio of the element M to the phosphorous is about 0.5: 1 to about 500:1 and in that each phosphorous atom of the phosphorous-containing groups forms at least one P—O-M bond and/or P—O-M′ bond. The invention also describes a process for preparing such materials.
摘要:
The present invention relates to a composition including an organic phosphorous-containing group bonded via an oxygen atom to a metal oxide of at least one element M. Generally, the composition is essentially amorphous, and includes an essentially monomolecular layer of an organic group directly bonded to the phosphorous atom. In addition, the composition is generally essentially free of any phosphate, phosphonate or phosphinate phase of the element M. Moreover, the composition has a ratio of the element M to phosphorous of about 15:1-200:1.
摘要:
Alkyl esters of fatty acids, and high purity glycerin, are produced using a process comprising a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol employing a heterogeneous catalyst, for example based on zinc aluminate, the water content in the reaction medium being controlled to a value that is below a given limiting value.
摘要:
A process for carrying out a reaction on an organic feed, for example dimerization, co-dimerization, oligomerization or metathesis of olefins, as described in which the catalyst is a catalytic metal compound dissolved in a non-aqueous ionic medium which is not or is only slightly miscible with hydrocarbons. The reaction is carried out in a system comprising at least two treatment loops each comprising at least one reaction zone and at least one zone for separating the organic and polar phases between which the polar medium containing the catalytic metal compound, and the organic phase circulate. Fresh polar phase is injected into the second loop and used polar phase is eliminated from the first loop. The hydrocarbon to be transformed is injected into the first loop and the products are withdrawn from the second loop. The invention also concerns a unit for carrying out the process.
摘要:
Synthetic oil that contains wholly or partly of dialkylbenzenes and/or partially or totally hydrogenated dialkylbenzenes. The synthetic oil according to the invention can also be used as an oil base or oil base additive and comprises at least one dialkylbenzene and/or at least one partially or totally hydrogenated dialkylbenzene and meets the general chemical formula: R1—A—R2 in which R1 and R2 represent alkyl groups and A is a benzene core and/or a cyclohexane core and/or a cyclohexene core and/or a cyclohexadiene core and is characterized in that it contains between 1 and 20% by weight or ortho isomers and in that at least one of the alkyl groups is attached for the most part to group A by carbon 2 of the aliphatic chain. The two alkyl groups are preferably attached for the most part to group A by carbon 2 of the aliphatic chain.
摘要:
A process for oligomerising olefins in an organic feed containing at least one olefin comprises two steps with different types of catalysis. The cut to be treated containing at least one olefin (Cn) is introduced via line 1 into a reaction zone R1 where in a first step it undergoes catalytic oligomerisation, either of a liquid phase homogeneous type, or heterogeneous with a solid support. The effluent produced is sent via line 2 to a heat exchanger E1 traversed by a cold liquid. The effluent is thus cooled before being sent via line 3 to a second reaction zone R2 where it undergoes catalytic oligomerisation in a liquid-liquid two-phase medium. After reaction, the effluent is fed via line 4 to a zone L1 where it is washed. After washing, the hydrocarbon fraction is sent via line 5 to separator S1. The fraction containing the unreacted olefins (Cn) is separated from the oligomer product fraction produced, this fraction Cn is evacuated from the apparatus via line 6, and the fraction containing the oligomer products is evacuated via line 7.
摘要:
A process for producing a tertiary olefin by decomposing a tertiary alkyl ether comprises a) decomposing at least one ether to a product containing an alcohol and a tertiary olefin, b) fractionating at least a portion of the product from a) in a fractionation zone (C1) to obtain the tertiary olefin and the alcohol, c) purifying at least a portion of the tertiary olefin obtained from step b) wherein said portion is sent to a water washing extraction zone (L1) from which a fraction (D) containing the tertiary olefin is recovered, and d) a step in which at least a portion of the fraction (D) from c) is sent to a separation zone (Co) from which a liquid aqueous fraction (Le) and a liquid hydrocarbon fraction (Lc) containing the major portion of the tertiary olefin are recovered.