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公开(公告)号：US5260354A
公开(公告)日：1993-11-09
申请号：US847966
申请日：1992-03-06
CPC分类号： C09D5/4492
摘要： An additive for cationic electrodepositable coating compositions is disclosed which improves hiding ability, stability, rheology and oil spot resistance. The additive is present in amounts of between 0.5 to 40 weight percent and is prepared by polymerizing in aqueous medium, under free radically initiated conditions, an aqueous dispersion of a polymerizable, ethylenically unsaturated monomer composition in the presence of a cationic polymeric surface active substance. The coating composition additionally has between 60 to 99.5 weight percent of a cationic salt group containing film forming polymer. Also disclosed is a method for coating which includes electrodepositing the above composition on an electrically conductive cathode.
摘要翻译： 公开了用于阳离子电沉积涂料组合物的添加剂，其改进了遮盖能力，稳定性，流变性和耐油斑性。 该添加剂以0.5至40重量％的量存在，并且通过在自由基引发的条件下在水性介质中聚合，在阳离子聚合物表面活性物质存在下将可聚合的烯属不饱和单体组合物的水分散体制备。 涂料组合物另外具有60至99.5重量％的含阳离子盐基的成膜聚合物。 还公开了一种涂覆方法，其包括在导电阴极上电沉积上述组合物。
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2.发明授权
公开(公告)号：US5286778A
公开(公告)日：1994-02-15
申请号：US951619
申请日：1992-09-28
申请人： Roy E. Dean , Edward E. McEntire
发明人： Roy E. Dean , Edward E. McEntire
IPC分类号： C09D15/00 , C09D127/06 , C09D127/08 , C08L27/08 , B32B21/08
CPC分类号： C09D127/08 , C09D127/06 , C09D15/00 , Y10T428/31989
摘要： Latex copolymers of vinyl halide and vinylidene halide reacted in the presence of a polymeric surfactant are advantageously employed as binders in waterborne stains and other coating compositions. Monomers from which the latex is polymerized may additionally include acrylates, vinyl esters, and/or unsaturated epoxies.
摘要翻译： 在聚合物表面活性剂存在下反应的乙烯基卤化物和亚乙烯基卤化物的乳胶共聚物有利地用作水性染料和其它涂料组合物中的粘合剂。 胶乳聚合的单体可另外包括丙烯酸酯，乙烯基酯和/或不饱和环氧树脂。
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公开(公告)号：US5118752A
公开(公告)日：1992-06-02
申请号：US776104
申请日：1991-10-15
IPC分类号： C08F2/24 , C08F30/08 , C08F220/10 , C08F220/18 , C08F230/08 , C08F246/00 , C08G18/62 , C08G18/67 , C08L25/00 , C08L75/04 , C08L101/00 , C08L101/02 , C09D125/06 , C09D143/04 , C09D151/00 , C09D151/08
CPC分类号： C09D151/08 , C08F2/24 , C09D125/06 , C09D143/04 , C08L75/04
摘要： An aqueous polymer emulsion latex is claimed composed of particles comprising a vinyl polymer and a surfactant containing at least one hydrophobic moiety and at least one hydrophilic moiety and also carrying silicon moieties and amido functionalities. Also claimed are coating compositions containing the aqueous polymer emulsion latex, processes for preparing the aqueous polymer emulsion latex wherein ethylenically unsaturated monomers are polymerized in the presence of a surfactant containing a silicon moiety and amido functionality, and substrates carrying a coating composition containing the aqueous polymer emulsion latex.
摘要翻译： 含水聚合物乳液胶乳由包含乙烯基聚合物和含有至少一个疏水部分和至少一个亲水部分并且还带有硅部分和酰胺官能团的表面活性剂的颗粒组成。 还要求保护的是含有聚合物水乳液胶乳的涂料组合物，制备含水聚合物乳液胶乳的方法，其中烯属不饱和单体在含有硅部分和酰胺官能团的表面活性剂存在下聚合，以及承载含有含水聚合物 乳液胶乳。
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公开(公告)号：US4483997A
公开(公告)日：1984-11-20
申请号：US462250
申请日：1983-01-31
IPC分类号： B01J23/24 , B01J27/188 , C07D301/19 , C07D303/04
CPC分类号： C07D301/19 , B01J23/24 , B01J27/188 , C07D303/04
摘要： A method for the preparation of an epoxide by reacting an olefin having 3 or more carbon atoms with a hydroperoxide in the presence of a catalyst. The catalyst includes molybdenum and/or tungsten and an inorganic metal phosphate and/or arsenate wherein at least the inorganic metal phosphate and/or arsenate is substantially insoluble in the olefin hydroperoxide reaction mixture. The metal portion of the inorganic metal phosphate and/or arsenate is one or more metals selected from the group consisting of the metals found in Groups I to III, VIIb and VIII, of the Periodic Table of Elements. Preferred metals include aluminum, iron, zinc and mixtures of these metals.
摘要翻译： 一种通过在催化剂存在下使具有3个或更多个碳原子的烯烃与氢过氧化物反应来制备环氧化物的方法。 催化剂包括钼和/或钨和无机金属磷酸盐和/或砷酸盐，其中至少无机金属磷酸盐和/或砷酸盐基本上不溶于烯烃氢过氧化物反应混合物。 无机金属磷酸盐和/或砷酸盐的金属部分是选自元素周期表第I至III，VIIb和VIII族中的金属的一种或多种金属。 优选的金属包括铝，铁，锌和这些金属的混合物。
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公开(公告)号：US4457371A
公开(公告)日：1984-07-03
申请号：US326455
申请日：1981-12-02
CPC分类号： E21B43/40 , B01D17/047
摘要： A process for recovering bitumen from oil-in-water (O/W) emulsions is disclosed wherein water soluble demulsifiers are used. These demulsifiers are polymers of specific quaternary ammonium monomers or co-polymers of these quaternary ammonium monomers wth other types of monomers wherein the greater portion of the co-polymer is comprised of the quaternary ammonium monomers. To resolve the bituminous petroleum emulsions, the process is carried out between 25.degree. and 160.degree. C. wherein the demulsifier of the invention is contacted with the bituminous emulsion.
摘要翻译： 公开了一种从水包油（O / W）乳液中回收沥青的方法，其中使用水溶性破乳剂。 这些破乳剂是特定季铵单体的聚合物或这些季铵单体与其它类型单体的共聚物，其中大部分共聚物由季铵单体组成。 为了解决沥青石油乳液，该方法在25℃至160℃之间进行，其中本发明的破乳剂与沥青乳液接触。
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6.发明授权Method for making rim elastomers using a catalyst system which is a polymer containing tertiary amine moieties 失效使用催化剂体系制备边缘弹性体的方法，所述催化剂体系是含有叔胺部分的聚合物
公开(公告)号：US4359540A
公开(公告)日：1982-11-16
申请号：US268220
申请日：1981-05-29
CPC分类号： C08G18/165 , C08G18/18 , C08G18/2081 , C08G2120/00
摘要： The invention is a method for making reaction injection molded polyurethane of improved properties. The method comprises injecting into a mold cavity a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality, a polyisocyanate and a catalyst comprising polymers substantially without active hydrogens containing tertiary amine moieties. This catalyst results in improved paintability when using high solids paint. Reaction injection molded elastomers are useful as molded articles of commerce including, but not limited to, vehicle body parts.
摘要翻译： 本发明是改进性能的反应注塑聚氨酯的制备方法。 该方法包括向模腔注入高分子量多羟基聚醚，含有至少两种官能团的低分子量含活性氢化合物，多异氰酸酯和包含基本上不含有叔胺部分的活性氢的聚合物的催化剂。 当使用高固含量涂料时，该催化剂可改善涂料的性能。 反应注射成型的弹性体可用作商业模制品，包括但不限于车身部件。
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公开(公告)号：US4265821A
公开(公告)日：1981-05-05
申请号：US92126
申请日：1979-11-07
IPC分类号： C07D301/02
CPC分类号： C07D301/02
摘要： Alkyl substituted ethylene carbonates are converted to substituted ethylene oxides by heating the respective carbonates in the presence of a catalyst comprising alkali metal halides or lanthanum iodide. The alkyl substituted ethylene carbonates have the general formula ##STR1## where R is alkyl, aryl, substituted alkyl, substituted aryl, alkaryl or aralkyl.
摘要翻译： 在包含碱金属卤化物或碘化镧的催化剂存在下，通过加热相应的碳酸酯将烷基取代的亚乙基碳酸酯转化成取代的环氧乙烷。 烷基取代的碳酸亚乙酯具有通式：其中R是烷基，芳基，取代的烷基，取代的芳基，烷芳基或芳烷基。
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8.发明授权
公开(公告)号：US4251637A
公开(公告)日：1981-02-17
申请号：US75437
申请日：1979-09-13
IPC分类号： C07D263/02 , C08G18/00 , C08G18/02 , C08G18/20 , C08G18/58
CPC分类号： C08G18/2081 , C08G18/2018 , C08G2105/02
摘要： The use of tertiary amino substituted oxazolidines as polyisocyanurate catalysts is disclosed. Said catalysts are useful in promoting the reaction between a polyol and an aromatic polyisocyanate to prepare a polymer containing recurring isocyanurate and urethane linkages.
摘要翻译： 公开了使用叔氨基取代的恶唑烷作为聚异氰脲酸酯催化剂。 所述催化剂可用于促进多元醇和芳族多异氰酸酯之间的反应以制备含有重复异氰脲酸酯和氨基甲酸酯键的聚合物。
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公开(公告)号：US4026836A
公开(公告)日：1977-05-31
申请号：US644494
申请日：1975-12-29
CPC分类号： C08G18/2009 , C08G18/1866 , C08G18/225 , C08G2101/0008 , C08G2101/0016 , C08G2101/0025 , C08G2105/02 , Y10S521/902
摘要： New catalysts for isocyanurate foams are those comprising aminomethacrylate salts. The foams are obtained by the polymerization of an aromatic polyisocyanate, and a polyether or polyester polyol in the presence of a blowing agent and said amino methacrylate salts falling within the following structural formula: ##STR1## where the radicals represented by R when taken singly are lower alkyl, and hydroxy lower alkyl, and when taken together with the adjacent nitrogen atom are selected from the group consisting of morpholino, C-substituted morpholino, N-alkylpiperazino and C-substituted N-alkylpiperazino, and M is selected from the group consisting of sodium, potassium, cesium, lithium and rubidium. The novel foams are useful in preparing rigid, flexible, semi-rigid, or semi-flexible materials such as panels, slabs or sprayed foam surfaces.
摘要翻译： 用于异氰脲酸酯泡沫的新催化剂是包含氨基甲基丙烯酸盐的那些。 通过在发泡剂存在下聚合芳族多异氰酸酯和聚醚或聚酯多元醇而获得泡沫，所述氨基甲基丙烯酸盐属于以下结构式：其中由单独表示的基团由R表示的基团为 低级烷基和羟基低级烷基，当与相邻的氮原子一起选自吗啉代，C取代的吗啉代，N-烷基哌嗪基和C-取代的N-烷基哌嗪基，M选自 的钠，钾，铯，锂和铷。 新型泡沫可用于制备刚性，柔性，半刚性或半柔性材料，例如面板，板坯或喷涂的泡沫表面。
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公开(公告)号：US5750770A
公开(公告)日：1998-05-12
申请号：US541748
申请日：1995-10-10
IPC分类号： C07C69/593 , C07C69/60 , C08F222/10 , C08G18/62 , C09D135/02 , C07C67/26
CPC分类号： C08G18/622 , C07C69/593 , C07C69/60 , C08F222/1006 , C09D135/02
摘要： Hydroxy functional, unsaturated diesters are disclosed that comprise the esterification reaction products of unsaturated anhydrides with secondary alcohols to form monoesters, followed by oxyalkylation of the monoester with epoxy compounds, whereby a diester is formed with hydroxy functionality. Use of secondary alcohol yields monoesters less prone to disproportionation. The unsaturated diesters may be copolymerized with vinyl monomers to form hydroxy functional copolymers useful in coating applications, wherein they may be included in compositions along with a curing agent that is reactive with hydroxy groups.
摘要翻译： 公开了羟基官能的不饱和二酯，其包含不饱和酸酐与仲醇的酯化反应产物以形成单酯，随后用环氧化合物烷氧基化单酯，由此形成具有羟基官能度的二酯。 使用仲醇会使单酯不容易发生歧化。 不饱和二酯可以与乙烯基单体共聚以形成可用于涂料应用的羟基官能共聚物，其中它们可以与可与羟基反应的固化剂一起包含在组合物中。
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