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公开(公告)号：US20070104399A1
公开(公告)日：2007-05-10
申请号：US11584205
申请日：2006-10-20
申请人： Alex Hamza , Juergen Biener , Christoph Wild , Eckhard Woerner
发明人： Alex Hamza , Juergen Biener , Christoph Wild , Eckhard Woerner
CPC分类号： C23C16/458 , B22F2998/00 , B43K1/082 , C04B35/52 , C04B2235/427 , C04B2235/6028 , C04B2235/94 , C04B2235/95 , C04B2235/963 , C04B2235/9661 , C23C16/01 , C23C16/271 , C23C16/272 , C23C16/274 , C23C16/4417 , C30B25/12 , C30B25/18 , C30B29/04 , C30B29/607 , C30B35/00 , G02B1/02 , G21B1/19 , Y02E30/16 , B22F1/0051 , B22F1/02 , B22F9/28
摘要： A novel method for fabricating diamond shells is introduced. The fabrication of such shells is a multi-step process, which involves diamond chemical vapor deposition on predetermined mandrels followed by polishing, microfabrication of holes, and removal of the mandrel by an etch process. The resultant shells of the present invention can be configured with a surface roughness at the nanometer level (e.g., on the order of down to about 10 nm RMS) on a mm length scale, and exhibit excellent hardness/strength, and good transparency in the both the infra-red and visible. Specifically, a novel process is disclosed herein, which allows coating of spherical substrates with optical-quality diamond films or nanocrystalline diamond films.
摘要翻译： 介绍了一种制作金刚石壳的新方法。 这种壳的制造是多步骤方法，其包括在预定心轴上进行金刚石化学气相沉积，随后抛光，微孔加工，以及通过蚀刻工艺去除心轴。 本发明的所得壳可以以毫米长度尺度配置在纳米级的表面粗糙度（例如，大约低达10nm RMS），并且表现出优异的硬度/强度，并且在 红外和可见。 具体地，本文公开了一种新颖的方法，其允许用光学质量金刚石膜或纳米晶体金刚石膜涂覆球形基底。
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公开(公告)号：US09481930B2
公开(公告)日：2016-11-01
申请号：US11584205
申请日：2006-10-20
申请人： Alex V. Hamza , Juergen Biener , Christoph Wild , Eckhard Woerner
发明人： Alex V. Hamza , Juergen Biener , Christoph Wild , Eckhard Woerner
IPC分类号： F16C33/00 , C23C16/458 , B43K1/08 , C04B35/52 , C23C16/01 , C23C16/27 , C23C16/44 , C30B25/12 , C30B25/18 , C30B29/04 , C30B35/00 , C30B29/60 , G21B1/19 , G02B1/02
CPC分类号： C23C16/458 , B22F2998/00 , B43K1/082 , C04B35/52 , C04B2235/427 , C04B2235/6028 , C04B2235/94 , C04B2235/95 , C04B2235/963 , C04B2235/9661 , C23C16/01 , C23C16/271 , C23C16/272 , C23C16/274 , C23C16/4417 , C30B25/12 , C30B25/18 , C30B29/04 , C30B29/607 , C30B35/00 , G02B1/02 , G21B1/19 , Y02E30/16 , B22F1/0051 , B22F1/02 , B22F9/28
摘要： A novel method for fabricating diamond shells is introduced. The fabrication of such shells is a multi-step process, which involves diamond chemical vapor deposition on predetermined mandrels followed by polishing, microfabrication of holes, and removal of the mandrel by an etch process. The resultant shells of the present invention can be configured with a surface roughness at the nanometer level (e.g., on the order of down to about 10 nm RMS) on a mm length scale, and exhibit excellent hardness/strength, and good transparency in the both the infra-red and visible. Specifically, a novel process is disclosed herein, which allows coating of spherical substrates with optical-quality diamond films or nanocrystalline diamond films.
摘要翻译： 介绍了一种制作金刚石壳的新方法。 这种壳的制造是多步骤方法，其包括在预定心轴上进行金刚石化学气相沉积，随后抛光，微孔加工，以及通过蚀刻工艺去除心轴。 本发明的所得壳可以以毫米长度尺度配置在纳米级的表面粗糙度（例如，大约低达10nm RMS），并且表现出优异的硬度/强度，并且在 红外和可见。 具体地，本文公开了一种新颖的方法，其允许用光学质量金刚石膜或纳米晶体金刚石膜涂覆球形基底。
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公开(公告)号：US20070224099A1
公开(公告)日：2007-09-27
申请号：US11728939
申请日：2007-03-26
申请人： Juergen Biener , Alex Hamza , Marcus Baeumer , Christian Schulz , Birte Jurgens , Monika Biener
发明人： Juergen Biener , Alex Hamza , Marcus Baeumer , Christian Schulz , Birte Jurgens , Monika Biener
IPC分类号： B01J23/66
摘要： The invention relates to a gold-containing catalyst with porous structure that is obtainable through a process that comprises the following steps: melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum, and at least partial removal by dissolving the at least one less noble metal out of the starting alloy thus obtained. The catalyst has high activity and great long-term stability, despite the fact that it does not contain a support material or a compound that serves as a support material. The catalyst can be used to accelerate and/or to influence the product selectivity of oxidation and reduction reactions. The catalyst is suitable, for example, for the oxidization of carbon monoxide to carbon dioxide, which makes it usable, among other things, in a fuel cell, in particular a polymer electrolyte membrane fuel cell (PEM), for protection of the anode catalyst against blocking by carbon monoxide.
摘要翻译： 本发明涉及具有多孔结构的含金催化剂，其可通过包括以下步骤的方法获得：将金和至少一种少量贵金属熔合在一起，所述贵金属选自银，铜，铑，钯 和铂，并且通过将如此获得的起始合金中的至少一种较少的贵金属溶解至少部分去除。 催化剂具有高活性和长期的稳定性，尽管它不含支撑材料或用作载体材料的化合物。 催化剂可用于加速和/或影响氧化和还原反应的产物选择性。 该催化剂适用于例如将一氧化碳氧化成二氧化碳，这使得其在燃料电池，特别是聚合物电解质膜燃料电池（PEM）中可用于保护阳极催化剂 防止一氧化碳堵塞。
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公开(公告)号：US20100230298A1
公开(公告)日：2010-09-16
申请号：US12723215
申请日：2010-03-12
CPC分类号： F03G7/00 , B82Y30/00 , C01B3/0021 , H01G11/32 , H01M4/926 , H01M8/0234 , H01M8/04216 , H01M2220/00 , Y02E60/325
摘要： An electrochemically driveable actuator according to one embodiment includes a nanoporous carbon aerogel composition capable of exhibiting charge-induced reversible strain when wetted by an electrolyte and a voltage is applied thereto. An electrochemically driven actuator according to another embodiment includes a nanoporous carbon aerogel composition wetted by an electrolyte; and a mechanism for causing charge-induced reversible strain of the composition. A method for electrochemically actuating an object according to one embodiment includes causing charge-induced reversible strain of a nanoporous carbon aerogel composition wetted with an electrolyte to actuate the object by the strain.
摘要翻译： 根据一个实施方案的可电化学驱动的致动器包括纳米多孔碳气凝胶组合物，其能够在被电解质润湿时表现出电荷诱导的可逆应变，并且向其施加电压。 根据另一个实施方案的电化学致动器包括由电解质润湿的纳米孔碳气凝胶组合物; 以及用于引起组合物的电荷诱导的可逆应变的机理。 根据一个实施方案的用于电化学致动物体的方法包括使用电解质润湿的纳米多孔碳气凝胶组合物的电荷诱导的可逆应变引起该应变致动物体。
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公开(公告)号：US10266949B2
公开(公告)日：2019-04-23
申请号：US12249630
申请日：2008-10-10
申请人： Juergen Biener , Monika M. Biener , Alex V. Hamza , Marcus Baeumer , Arne Wittstock , Joerg Weissmueller , Dominik Kramer , Raghavan Nadar Viswanath
发明人： Juergen Biener , Monika M. Biener , Alex V. Hamza , Marcus Baeumer , Arne Wittstock , Joerg Weissmueller , Dominik Kramer , Raghavan Nadar Viswanath
IPC分类号： C23C8/06 , G01L1/20 , C23F1/00 , G01N27/403 , H01L41/047
摘要： A method of controlling macroscopic strain of a porous structure includes contacting a porous structure with a modifying agent which chemically adsorbs to a surface of the porous structure and modifies an existing surface stress of the porous structure. A device in one embodiment includes a porous metal structure, which when contacted with a modifying agent which chemically adsorbs to a surface of the porous metal structure, exhibits a volumetric change due to modification of an existing surface stress of the porous metal structure; and a mechanism for detecting the volumetric change. Additional methods and systems are also presented.
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公开(公告)号：US08785346B2
公开(公告)日：2014-07-22
申请号：US12480545
申请日：2009-06-08
申请人： Juergen Biener , Alex V. Hamza , Marcus Baeumer , Christian Schulz , Birte Jürgens , Monika M. Biener
发明人： Juergen Biener , Alex V. Hamza , Marcus Baeumer , Christian Schulz , Birte Jürgens , Monika M. Biener
摘要： A method for forming a gold-containing catalyst with porous structure according to one embodiment of the present invention includes producing a starting alloy by melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum; and a dealloying step comprising at least partial removal of the less noble metal by dissolving the at least one less noble metal out of the starting alloy. Additional methods and products thereof are also presented.
摘要翻译： 根据本发明的一个实施方案，形成具有多孔结构的含金催化剂的方法包括通过将金和至少一种较少的贵金属熔融在一起来制备起始合金，所述金属选自银，铜，铑 ，钯和铂; 以及脱金合步骤，其包括通过将所述至少一种较低贵重金属从所述起始合金中溶解出来至少部分去除所述较低贵金属。 还提供了附加的方法和产品。
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7.发明授权Nanoporous carbon tunable resistor/transistor and methods of production thereof 有权纳米多孔碳可调谐电阻/晶体管及其生产方法公开(公告)号：US08703523B1
公开(公告)日：2014-04-22
申请号：US13311468
申请日：2011-12-05
IPC分类号： H01L21/00
CPC分类号： H01L29/66037 , H01L29/0665 , H01L29/0673 , H01L29/16 , H01L29/1606 , H01L29/772
摘要： In one embodiment, a tunable resistor/transistor includes a porous material that is electrically coupled between a source electrode and a drain electrode, wherein the porous material acts as an active channel, an electrolyte solution saturating the active channel, the electrolyte solution being adapted for altering an electrical resistance of the active channel based on an applied electrochemical potential, wherein the active channel comprises nanoporous carbon arranged in a three-dimensional structure. In another embodiment, a method for forming the tunable resistor/transistor includes forming a source electrode, forming a drain electrode, and forming a monolithic nanoporous carbon material that acts as an active channel and selectively couples the source electrode to the drain electrode electrically. In any embodiment, the electrolyte solution saturating the nanoporous carbon active channel is adapted for altering an electrical resistance of the nanoporous carbon active channel based on an applied electrochemical potential.
摘要翻译： 在一个实施例中，可调电阻器/晶体管包括电耦合在源电极和漏电极之间的多孔材料，其中多孔材料用作有源沟道，饱和有源沟道的电解质溶液，电解质溶液适于 基于施加的电化学电位改变活性通道的电阻，其中活性通道包括以三维结构排列的纳米多孔碳。 在另一个实施例中，形成可调谐电阻/晶体管的方法包括形成源电极，形成漏电极，以及形成用作有源沟道的整体式纳米多孔碳材料，并将源极电极选择性地耦合到漏电极。 在任何实施方案中，饱和纳米多孔碳活性通道的电解质溶液适于基于所施加的电化学电位来改变纳米多孔碳活性通道的电阻。
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公开(公告)号：US20090291848A1
公开(公告)日：2009-11-26
申请号：US12480545
申请日：2009-06-08
申请人： Juergen Biener , Alex V. Hamza , Marcus Baeumer , Christian Schulz , Birte Jürgens , Monika M. Biener
发明人： Juergen Biener , Alex V. Hamza , Marcus Baeumer , Christian Schulz , Birte Jürgens , Monika M. Biener
IPC分类号： B01J23/50
摘要： The invention relates to a gold-containing catalyst with porous structure that is obtainable through a process that comprises the following steps: melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum, and at least partial removal by dissolving the at least one less noble metal out of the starting alloy thus obtained. The catalyst has high activity and great long-term stability, despite the fact that it does not contain a support material or a compound that serves as a support material. The catalyst can be used to accelerate and/or to influence the product selectivity of oxidation and reduction reactions. The catalyst is suitable, for example, for the oxidization of carbon monoxide to carbon dioxide, which makes it usable, among other things, in a fuel cell, in particular a polymer electrolyte membrane fuel cell (PEM), for protection of the anode catalyst against blocking by carbon monoxide.
摘要翻译： 本发明涉及具有多孔结构的含金催化剂，其可通过包括以下步骤的方法获得：将金和至少一种少量贵金属熔合在一起，所述贵金属选自银，铜，铑，钯 和铂，并且通过将如此获得的起始合金中的至少一种较少的贵金属溶解至少部分去除。 催化剂具有高活性和长期的稳定性，尽管它不含支撑材料或用作载体材料的化合物。 催化剂可用于加速和/或影响氧化和还原反应的产物选择性。 该催化剂适用于例如将一氧化碳氧化成二氧化碳，这使得其在燃料电池，特别是聚合物电解质膜燃料电池（PEM）中可用于保护阳极催化剂 防止一氧化碳堵塞。
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公开(公告)号：US08231770B2
公开(公告)日：2012-07-31
申请号：US12723215
申请日：2010-03-12
IPC分类号： G01N27/403 , H01L41/047 , G01L1/20
CPC分类号： F03G7/00 , B82Y30/00 , C01B3/0021 , H01G11/32 , H01M4/926 , H01M8/0234 , H01M8/04216 , H01M2220/00 , Y02E60/325
摘要： An electrochemically driveable actuator according to one embodiment includes a nanoporous carbon aerogel composition capable of exhibiting charge-induced reversible strain when wetted by an electrolyte and a voltage is applied thereto. An electrochemically driven actuator according to another embodiment includes a nanoporous carbon aerogel composition wetted by an electrolyte; and a mechanism for causing charge-induced reversible strain of the composition. A method for electrochemically actuating an object according to one embodiment includes causing charge-induced reversible strain of a nanoporous carbon aerogel composition wetted with an electrolyte to actuate the object by the strain.
摘要翻译： 根据一个实施方案的可电化学驱动的致动器包括纳米多孔碳气凝胶组合物，其能够在被电解质润湿时表现出电荷诱导的可逆应变，并且向其施加电压。 根据另一个实施方案的电化学致动器包括由电解质润湿的纳米孔碳气凝胶组合物; 以及用于引起组合物的电荷诱导的可逆应变的机理。 根据一个实施方案的用于电化学致动物体的方法包括使用电解液润湿的纳米多孔碳气凝胶组合物的电荷诱导可逆应变引起该应变致动物体。
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公开(公告)号：US20120034442A1
公开(公告)日：2012-02-09
申请号：US13204277
申请日：2011-08-05
申请人： Peter J. PAUZAUSKIE , Marcus A. Worsley , Theodore F. Baumann , Joe H. Satcher, JR. , Juergen Biener
发明人： Peter J. PAUZAUSKIE , Marcus A. Worsley , Theodore F. Baumann , Joe H. Satcher, JR. , Juergen Biener
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/00 , C01B32/184 , C01B32/194 , C01B32/336 , C01P2006/12 , Y10S977/734 , Y10S977/842 , Y10T428/268 , Y10T428/30
摘要： Graphene aerogels with high conductivity and surface areas including a method for making a graphene aerogel, including the following steps: (1) preparing a reaction mixture comprising a graphene oxide suspension and at least one catalyst; (2) curing the reaction mixture to produce a wet gel; (3) drying the wet gel to produce a dry gel; and (4) pyrolyzing the dry gel to produce a graphene aerogel. Applications include electrical energy storage including batteries and supercapacitors.
摘要翻译： 具有高导电性和表面积的石墨烯气凝胶，包括制备石墨烯气凝胶的方法，包括以下步骤：（1）制备包含石墨烯氧化物悬浮液和至少一种催化剂的反应混合物; （2）固化反应混合物以产生湿凝胶; （3）干燥湿凝胶以产生干凝胶; 和（4）热解干凝胶以产生石墨烯气凝胶。 应用包括电能储存，包括电池和超级电容器。
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