摘要:
A mixture for stabilizing polyurethanes contains(a) an amine of the formula I ##STR1## (b) a mixture of the benzotriazoles II and III ##STR2## in which n is chosen so that the mean molecular weight of the mixture is greater than 600, and(c) .alpha.-tocopherol, if necessary mixed with tris-(nonylphenyl) phosphite, and polyurethanes contain from 0.005 to 5.0% by weight, based on the material to be stabilized, of this mixture.
摘要:
Benzimidazolecarboxanilides of the formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, chlorine, bromine, alkyl, alkoxy, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 independently of one another are each hydrogen, alkyl, alkyl which is interrupted by one or more oxygen atoms, alkoxy, alkoxy which is interrupted by one or more oxygen atoms, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl, phenylalkoxy, alkanoylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 0, 1, 2, 3, 4 or 5, X is oxygen, ##STR2## R.sup.5 is hydrogen, alkyl, phenylalkyl, cyanomethyl, aminoethyl, hydroxyethyl, alkylcarbonyl or benzoyl, R.sup.6 is hydrogen, alkyl, phenylalkyl or phennyl and m is from 2 to 8, and the acid addition salts and hydrates of these compounds are stabilizers for organic material, in particular for plastics, such as polyethylene, polypropylene and polyamide.
摘要:
The novel compounds of the general formula I ##STR1## where n is from 1 to 70,R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.7 -C.sub.12 -aralkyl, aryl or a carboxylic ester group, orR.sup.1 and R.sup.2 together may form a tetramethylene or pentamethylene group,R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each alkyl, the radicalsX independently of one another are each a direct bond or a bridge member,Y and Z are each oxygen, sulfur or NR.sup.8,R.sup.7 is hydrogen, chlorine, bromine, hydroxyl, alkoxy, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl and R.sup.8 is hydrogen or unsubstituted or substituted alkyl, and the ammonium salts of these compounds, are very useful as light stabilizers.
摘要:
Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.
摘要:
Heterocyclic compounds of the formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently of the others hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 - or C.sub.6 -cycloalkyl orR.sup.1 and R.sup.2 and also R.sup.3 and R.sup.4 are each pairwise trimethylene or tetramethylene,A is a direct bond, C.sub.1 - C.sub.22 -alkylene, cycloalkylene, ##STR2## where m and o are each from 1 to 20 andR.sup.6 is C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, unsubstituted or substituted phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a group of the formula ##STR3## which may be bonded to A not only via the nitrogen but also via the carbon, and whereR.sup.7, R.sup.8, and R.sup.10 are each independently of the others C.sub.1 -C.sub.4 -alkyl orR.sup.7 and R.sup.8 and/or R.sup.9 and R.sup.10 are each pairwise tetramethylene or pentamethylene andR.sup.11 is hydrogen or C.sub.1 -C.sub.4 -alkyl,B is a direct bond, C.sub.1 -C.sub.22 - alkylene, C.sub.7 -C.sub.16 -phenylalkylene or carbonyl-, carboxamido- or carboxylato-interrupted C.sub.3 -C.sub.22 -alkylene andR.sup.5 is hydrogen, cyano, hydroxyl, ##STR4## R.sup.12 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.16 -phenylalkyl, unsubstituted or substituted phenyl or 5- or 6- membered heterocyclyl or, when n is 1, M--B--R.sup.5 is a group of the formula ##STR5## R.sup.13 is C.sub.1 -C.sub.4 -alkyl, R.sup.14 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sup.15 is C.sub.1 -C.sub.12 -alkyl, have very good stabilizing properties, no self-color, good compatibility with polymers, a low vapor pressure and stability to thermal decomposition.
摘要:
Novel tetrahydrofurancarboxylic acid derivatives of the general formula I ##STR1## or polymers of these containing units of the formula II ##STR2## where the radicals R independently of one another are each C.sub.1 -C.sub.4 -alkyl, cyclohexyl or phenyl, m is from 0 to 3, n is 1 or 2, and R' is a radical of the formula ##STR3## suitable terminal groups in the polymers being chlorine or hydroxyl in the case of the CO group and hydrogen in the case of the --NR.sup.2 group, A is a bridge member, R.sup.1 is hydrogen, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.12 -alkyl which may be interrupted by up to 3 oxygen atoms, unsubstituted or substituted phenylalkyl or C.sub.5 -C.sub.7 -cycloalkyl and R.sup.2 is radical of the formula ##STR4## where R.sup.3 is hydrogen or methyl, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are each methyl or ethyl and R.sup.8 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -alkenyl, C.sub.2 -C.sub.4 -hydroxyalkyl or aralkyl, and salts of the compounds I and II, are very useful as light stabilizers for organic polymers.
摘要:
Useful stabilizers for organic material, in particular plastics and paints, and metal ion deactivators are amides of the formula ##STR1## where R.sup.1 and R.sup.2 are singly methyl or together tetramethylene or pentamethylene, R.sup.3 is hydrogen, alkyl, alkoxycarbonyl, alkanoyl, benzyl, hydroxyethyl, cyanomethyl or aminomethyl, n is 1, 2 or 3 and--when n is 1--R.sup.4 is hydrogen and R.sup.5 is --CO--R.sup.6 is H, alkyl, cycloalkyl, aralkyl, phenoxyalkyl, aryl, a 5- or 6-membered heterocycle, alkoxy, aryloxy, cycloalkyloxy, phenylalkoxy, carbamoyl or --SO.sub.2 --R.sup.8 where R.sup.8 is alkyl or phenyl or ##STR2## is a phthalimide group or--when n is 2--R.sup.4 is H and R.sup.5 is --CO--Z--CO-- where Z is a chemical bond, C.sub.1 -C.sub.8 -alkylene, oxaalkylene, phenylene, cyclohexylene, biphenylene, biphenylene oxide, dioxyphenylene, diaminophenylene, diaminocyclohexylene, 1-.OMEGA.-diiminoalkylene or a 2-valent heterocycle or ##STR3## is a pyromellimide group or--when n is 3--R.sup.4 is H and R.sup.5 is ##STR4## where R.sup.10 is a trivalent alkyl or 3-valent aryl, or acid addition salts and hydrates thereof.
摘要:
Polycyclic compounds of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, alkyl, cycloalkyl, unsubstituted or substituted phenyl, pyridyl or phenylalkyl, or R.sup.1 and R.sup.2 together form a trimethylene or tetramethylene group, W, X, Y and Z independently of one another are each C--R.sup.6 or nitrogen, one or more of the radicals W, X, Y or Z being C--R.sup.6, R.sup.6 is hydrogen, --CO.sub.2 R.sup.7, --CONR.sup.7 R.sup.8, cyano or hydroxymethyl and R.sup.7 and R.sup.8 are each hydrogen, alkyl, unsubstituted or substituted phenyl, cycloalkyl, a 5-membered or 6-membered heterocyclic structure or phenylalkyl, R.sup.3 and R.sup.4 are each hydrogen or R.sup.3 and R.sup.4 together form a group of the formula ##STR2## A is a chemical bond, alkylene, ##STR3## or cycloalkylene, m and o are each from 1 to 20, R.sup.9 is alkyl, cycloalkyl, phenylalkyl or unsubstituted or substituted phenyl, M is a group of the formula ##STR4## and can be bonded to A both with the nitrogen atom and with the carbon atom, and R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each alkyl, or R.sup.10 and R.sup.11 or R.sup.12 and R.sup.13 together form a tetramethylene or pentamethylene group, B is a chemical bond, alkylene or phenylalkylene or is alkylene which is interrupted by carbonyl, carboxamide or a carboxylic ester group, R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.14 is hydrogen, alkyl, cycloalkyl, phenylalkyl, phenyl or a 5-membered or 6-membered heterocyclic structure, or M--B--R.sup.5 is a group of the formula ##STR6## in which case A must not be a chemical bond and R.sup.15 is alkyl, R.sup.16 is hydrogen, alkyl or alkoxy and R.sup.17 is hydrogen or alkyl, have extremely good stabilizing properties and no natural color and are very compatible with organic polymers. They also have a low vapor pressure and are stable to thermal decomposition.
摘要:
Bislactams of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are each C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 form a tetra- or pentamethylene radical, and R.sup.5 is hydrogen, carbonyl-C.sub.1 -C.sub.8 -alkyl, benzoyl, C.sub.1 -C.sub.8 -alkyl, C.sub.7 -C.sub.10 -phenylalkyl, the phenyl nucleus being unsubstituted or substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkyoxy, fluorine, chlorine or bromine radicals, or is C.sub.1 -C.sub.3 -cyanoalkyl, C.sub.2 -C.sub.4 -hydroxyalkyl or C.sub.2 - or C.sub.3 -aminoalkyl, and the acid addition salts and hydrates of these compounds.The compounds (I) are stabilizers for organic materials.