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    Branched aromatic sulfide sulfone polymer production
    2.
    发明授权
    Branched aromatic sulfide sulfone polymer production 失效
    分支芳香硫醚砜聚合物生产

    公开(公告)号：US5179193A

    公开(公告)日：1993-01-12

    申请号：US789554

    申请日：1991-11-08

    申请人： Rex L. Bobsein ,  Howard F. Efner

    发明人： Rex L. Bobsein ,  Howard F. Efner

    IPC分类号： C08G75/02 ,  C08G75/20

    CPC分类号： C08G75/20 ,  C08G75/0236

    摘要： Branched aromatic sulfide sulfone polymer is produced by contacting at least one dihalo aromatic sulfone, at least one polymerizable sulfur source other than lithium sulfide, at least one alkali metal carbonate, at least one organic amide, at least one alkali metal carboxylate, at least one polyhalodiarylsulfone having more than two halogen substituents and water including water of hydration under polymerization conditions for a period of time sufficient to form an aromatic sulfide sulfone polymer. The polymer exhibits higher melt and solution viscosity than obtained in the same process except without the use in the reaction mixture of polyhalodiarylsulfone having more than two halogen substituents and is useful in the production of coatings, films, molded objects, and fibers.

    摘要翻译： 分支芳香硫醚砜聚合物是通过使至少一种二卤代芳族砜，至少一种不同于硫化锂的可聚合硫源，至少一种碱金属碳酸盐，至少一种有机酰胺，至少一种碱金属羧酸盐，至少一种 具有多于两个卤素取代基的多卤代二芳基砜和包含水合的水在聚合条件下持续足以形成芳族硫化物砜聚合物的时间。 聚合物显示出比在相同方法中获得的熔体和溶液粘度更高的熔融和溶液粘度，除非在具有多于两个卤素取代基的多卤二芳基砜的反应混合物中使用，并且可用于制备涂料，膜，模制物体和纤维。

    Poly(arylene sulfide) polymer containing sulfone, ether and biphenyl groups
    4.
    发明授权
    Poly(arylene sulfide) polymer containing sulfone, ether and biphenyl groups 失效
    聚（亚芳基硫醚）聚合物含有砜，醚和联苯基

    公开(公告)号：US5245000A

    公开(公告)日：1993-09-14

    申请号：US724270

    申请日：1991-07-01

    申请人： Rex L. Bobsein ,  Jon F. Geibel ,  Howard F. Efner

    发明人： Rex L. Bobsein ,  Jon F. Geibel ,  Howard F. Efner

    IPC分类号： C08G75/02 ,  C08G75/23

    CPC分类号： C08G75/23 ,  C08G75/0204 ,  C08G75/0259

    摘要： Poly(arylene sulfide) polymers containing sulfone, ether and biphenyl groups are prepared by a two step process. In the first step, a diphenol is reacted with either a dihaloaromatic sulfone monomer or a bis(haloarylsulfonyl) biphenyl monomer, or both, in the presence of an alkali metal base and a polar organic compound. In the second step, the reaction mixture above is reacted with a sulfur source, and any monomer which was not employed in the first step, if any. The polymers prepared according to the invention process exhibit increased glass transition temperatures over those of known poly(arylene sulfide) polymers. The structure of repeating units of the polymer can be controlled by varying the sequence of addition of the monomers.

    摘要翻译： 含有砜，醚和联苯基的聚（亚芳基硫醚）聚合物通过两步法制备。 在第一步中，在碱金属碱和极性有机化合物的存在下，二酚与二卤代芳族砜单体或双（卤代芳基磺酰基）联苯单体或两者反应。 在第二步中，将上述反应混合物与硫源反应，以及在第一步中未使用的任何单体（如果有的话）。 根据本发明方法制备的聚合物的玻璃化转变温度高于已知的聚（亚芳基硫醚）聚合物的玻璃化转变温度。 可以通过改变单体加成顺序来控制聚合物的重复单元的结构。

    Treatment of polyarylene sulfide/sulfone polymers with zinc compound and acidic solution
    8.
    发明授权
    Treatment of polyarylene sulfide/sulfone polymers with zinc compound and acidic solution 失效
    用锌化合物和酸溶液处理聚亚烷基硫化物/磺化聚合物

    公开(公告)号：US5235034A

    公开(公告)日：1993-08-10

    申请号：US696451

    申请日：1991-05-06

    申请人： Rex L. Bobsein ,  Michael C. Yu ,  Roy F. Wright ,  David A. Soules

    发明人： Rex L. Bobsein ,  Michael C. Yu ,  Roy F. Wright ,  David A. Soules

    IPC分类号： C08G75/02 ,  C08G75/20

    CPC分类号： C08G75/02 ,  C08G75/20

    摘要： Poly(arylene sulfide/sulfone) polymers are treated in order to increase melt stability and decrease impurities by contacting the poly(arylene sulfide/sulfone) polymer with a soluble zinc compound and an acidic solution. In one embodiment, the polymer is treated first with the soluble zinc compound, followed by treatment with the acidic solution. In another embodiment, the polymer is treated in one step with a solution comprising a water soluble zinc compound in an acidic solution.

    摘要翻译： 处理聚（亚芳基硫醚/砜）聚合物以通过使聚（亚芳基硫醚/砜）聚合物与可溶性锌化合物和酸性溶液接触来提高熔体稳定性和降低杂质。 在一个实施方案中，首先用可溶性锌化合物处理聚合物，然后用酸性溶液处理。 在另一个实施方案中，聚合物在一个步骤中用在酸性溶液中的水溶性锌化合物的溶液处理。

    Water-based industrial cleaners
    9.
    发明授权
    Water-based industrial cleaners 失效
    水性工业清洁剂

    公开(公告)号：US4663082A

    公开(公告)日：1987-05-05

    申请号：US808971

    申请日：1985-12-16

    申请人： Rex L. Bobsein ,  Clarence R. Bresson

    发明人： Rex L. Bobsein ,  Clarence R. Bresson

    IPC分类号： C11D1/72 ,  C11D1/755 ,  C11D3/075

    CPC分类号： C11D1/755 ,  C11D1/72

    摘要： A stable water-based industrial cleaning composition comprising water, an additive comprising a mixture of an alkyl polyoxyalkylene sulfide and an alkyl polyoxyalkylene sulfoxide and at least one builder selected from the group consisting of alkali metal and ammonium salts of ethylenediamine tetraacetic acid, alkali metal and ammonium pyrophosphates, alkali metal and ammonium metasilicates, alkali metal hydroxides, alkaline earth metal hydroxides and alkali metal borates is disclosed. In accordance with the invention, said alkyl polyoxyalkylene sulfide may be partially oxidized to its corresponding alkyl polyoxyalkylene sulfoxide to produce said additive.

    摘要翻译： 一种稳定的基于水的工业清洁组合物，其包含水，包含烷基聚氧化烯硫化物和烷基聚氧化烯亚砜的混合物的添加剂和至少一种助洗剂，其选自乙二胺四乙酸的碱金属和铵盐，碱金属和 焦磷酸铵，偏硅酸铵，碱金属氢氧化物，碱土金属氢氧化物和碱金属硼酸盐。 根据本发明，所述烷基聚氧化烯硫化物可以部分氧化成其相应的烷基聚氧化烯亚砜，以产生所述添加剂。