摘要:
An inorganic material is described, which consists of at least two elementary spherical particles, each one of said spherical particles comprising metallic nanoparticles of size ranging between 1 and 300 nm and a mesostructured matrix based on an oxide of at least one element X selected from the group made up of silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium, and the mixture of at least two of these elements, said mesostructured matrix having a pore diameter ranging between 1.5 and 30 nm and having amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 μm and less than or equal to 100 μm. Said material can also contain zeolite nanocrystals trapped within said mesostructured matrix.
摘要:
An inorganic material is described, which consists of at least two elementary spherical particles, each one of said spherical particles comprising metallic nanoparticles of size ranging between 1 and 300 nm and a mesostructured matrix based on an oxide of at least one element X selected from the group made up of silicon, aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium, and the mixture of at least two of these elements, said mesostructured matrix having a pore diameter ranging between 1.5 and 30 nm and having amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 μm and less than or equal to 100 μm. Said material can also contain zeolite nanocrystals trapped within said mesostructured matrix.
摘要:
A material with a hierarchical porosity is described, constituted by at least two spherical elementary particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. the matrix based on silicon oxide may contain aluminium. The preparation of said material is also described.
摘要:
A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminum oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译:描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料,每个所述球形颗粒由基于氧化硅和氧化铝的基体构成,孔径在1.5至30nm的范围内,Si / Al 摩尔比至少为1,具有厚度在1至20nm范围内的非晶壁,所述球形基本粒子的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。
摘要:
A process for depositing a layer on at least part of the surface of a substrate by at least partially submerging the substrate in a solution having a solvent and at least one compound intended to form the layer, then drying the substrate, the drying being at least partially carried out in an atmosphere that is isolated from the solution. The submersion in the solution and the drying of the substrate are carried out in the same controlled-atmosphere enclosure.
摘要:
A process for depositing a layer on at least part of the surface of a substrate by at least partially submerging the substrate in a solution comprising a solvent and at least one compound intended to form the layer, then drying the substrate, this drying being at least partially carried out in an atmosphere that is isolated from the solution. The submersion in the solution and the drying of the substrate are carried out in the same controlled-atmosphere enclosure.
摘要:
The invention relates to a nanostructured porous oxyfluoride film deposited onto a substrate, to a method for its production, and also to various applications.The oxyfluoride has a porous semicrystalline structure and a refractive index of 1.08 to 1.25, measured in the visible range for a relative humidity level below 80%. Its chemical composition corresponds to the formula (Mg(1−x)Cax)(1−y)MyF(2+(n−2)y−2z−t)Oz(OH)tM′w in which n is the valency of M, n being 1 to 4, M represents at least one element chosen from Al, Si, Ge and Ga, M′ represents at least one element chosen from the group composed of Co, Cr, Ni, Fe, Cu, Sb, Ag, Pd, Cd, Au, Sn, Pb, Ce, Nd, Pr, Eu, Yb, Tb, Dy, Er and Gd, and 0≦w 0 and t
摘要翻译:本发明涉及沉积在基底上的纳米结构多孔氟氧化物膜,其生产方法以及各种应用。 氟氧化物具有多孔半晶体结构,折射率为1.08至1.25,在相对湿度低于80%的可见范围内测量。 其化学成分对应于式(Mg(1-x)Cax)(1-y)MyF(2+(n-2)y-2z-t)Oz(OH)tM'w,其中n为 M,n为1至4,M表示选自Al,Si,Ge和Ga中的至少一种元素,M'表示选自Co,Cr,Ni,Fe,Cu,Sb,Ag ,Pd,Cd,Au,Sn,Pb,Ce,Nd,Pr,Eu,Yb,Tb,Dy,Er和Gd,0&nlE; w <0.1; 0&nlE; x&nlE; 1; 0&nlE; y&nlE; 0.5; z <1; z + t> 0和t <2。