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    Preparation of low-density ethylene copolymers in fluid bed reactor
    1.
    发明授权
    Preparation of low-density ethylene copolymers in fluid bed reactor 失效
    在流化床反应器中制备低密度乙烯共聚物

    公开(公告)号：US4482687A

    公开(公告)日：1984-11-13

    申请号：US506772

    申请日：1983-06-24

    申请人： Allen Noshay ,  Frederick J. Karol ,  Robert J. Jorgensen

    发明人： Allen Noshay ,  Frederick J. Karol ,  Robert J. Jorgensen

    IPC分类号： C08F2/34 ,  C08F210/16 ,  C08F10/02

    CPC分类号： C08F210/16 ,  Y10S526/901 ,  Y10S526/904

    摘要： Ethylene copolymers having a density of about 0.91 to 0.94 and a melt flow ratio of about .gtoreq.26 to .ltoreq.40 are readily produced in a low pressure gas phase process at a productivity of .gtoreq.500,000 pounds of polymer per pound of Ti with a catalyst formed from selected organo aluminum compounds and a composition prepared by copulverizing magnesium dihalide with a complex obtained by contacting a titanium compound of the structure Ti(OR).sub.a X.sub.b with an ether, ester, ketone or amine,wherein R is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, or COR' where R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical,X is Cl, Br, I or mixtures thereof, a is 0 or 1, b is 2 to 4 inclusive and a+b=3 or 4.

    摘要翻译： 密度为约0.91至0.94，熔体流动比约> = = 26至<= 40的乙烯共聚物在低压气相法中容易产生，生产率≥500,000磅聚合物/磅 Ti与由选择的有机铝化合物形成的催化剂组成的组合物，以及通过使二卤化镁与通过使Ti（OR）a Xb结构的钛化合物与醚，酯，酮或胺接触而获得的络合物制备的组合物，其中R是C1 C 14脂族或芳族烃基，或COR'，其中R'为C 1至C 14脂族或芳族烃基，X为Cl，Br，I或其混合物，a为0或1，b为2至4， + b = 3或4。

    Catalyst composition for copolymerizing ethylene
    5.
    发明授权
    Catalyst composition for copolymerizing ethylene 失效
    乙烯共聚用催化剂组合物

    公开(公告)号：US4349648A

    公开(公告)日：1982-09-14

    申请号：US288806

    申请日：1981-07-31

    申请人： Robert J. Jorgensen ,  George L. Goeke ,  Frederick J. Karol

    发明人： Robert J. Jorgensen ,  George L. Goeke ,  Frederick J. Karol

    IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F110/02 ,  C08F210/00 ,  C08F210/16 ,  C08F10/02

    CPC分类号： C08F210/16 ,  C08F110/02 ,  Y10S526/901

    摘要： Ethylene copolymers having improved optical properties in film form are prepared by continuously copolymerizing ethylene with one or more higher alpha olefin monomers in a low pressure gas phase reaction with a catalyst composition prepared by forming a precursor composition from a magnesium compound, titanium compound, and electron donor compound; diluting said precursor composition with an inert carrier material; optionally partially activating the diluted precursor composition with an organo aluminum compound prior to introducing said diluted precursor composition into the polymerization reactor; and completely activating the diluted (and optionally partially activated) precursor composition in the polymerization reactor with a mixture of a dihydrocarbyl aluminum halide compound and a trihydrocarbyl aluminum compound.

    摘要翻译： 通过在低压气相反应中将乙烯与一种或多种较高级α-烯烃单体连续共聚而制备的膜形式的光学性能的乙烯共聚物是通过由镁化合物，钛化合物和电子形成前体组合物制备的催化剂组合物 供体化合物; 用惰性载体材料稀释所述前体组合物; 在将所述稀释的前体组合物引入聚合反应器之前，任选地用有机铝化合物部分活化稀释的前体组合物; 并用二烃基卤化铝化合物和三烃基铝化合物的混合物在聚合反应器中完全活化稀释（和任选地部分活化的）前体组合物。

    Preparation of ethylene copolymers in fluid bed reactor
    6.
    发明授权
    Preparation of ethylene copolymers in fluid bed reactor 失效
    在流化床反应器中制备乙烯共聚物

    公开(公告)号：US4302566A

    公开(公告)日：1981-11-24

    申请号：US14414

    申请日：1979-02-27

    申请人： Frederick J. Karol ,  George L. Goeke ,  Burkhard E. Wagner ,  William A. Fraser ,  Robert J. Jorgensen ,  Nils Friis

    发明人： Frederick J. Karol ,  George L. Goeke ,  Burkhard E. Wagner ,  William A. Fraser ,  Robert J. Jorgensen ,  Nils Friis

    IPC分类号： C08F2/34 ,  C08F210/16 ,  C08F4/64

    CPC分类号： C08F210/16

    摘要： Ethylene copolymers having a density of .gtoreq.0.91 to .ltoreq.0.96 and a melt flow ratio of .gtoreq.22 to .ltoreq.32 are readily produced in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti with a particulate catalyst diluted with an inert carrier material and formed from selected organo aluminum compounds and a precursor composition of the formula:Mg.sub.m Ti.sub.1 (OR).sub.n X.sub.p [ED].sub.qwherein ED is a selected electron donor compound.m is .gtoreq.0.5 to .ltoreq.56n is 0 or 1p is .gtoreq.6 to .ltoreq.116q is .gtoreq.2 to .ltoreq.85R is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting of Cl, Br, I, or mixtures thereof.

    摘要翻译： 在低压气相法中容易产生密度≥0.91〜0.96，熔体流动比> 22 = 32的乙烯共聚物，生产率≥50万磅 聚合物每磅Ti与用惰性载体材料稀释并由选定的有机铝化合物和下式的前体组合物MgMTi1（OR）nXp [ED] q形成的颗粒催化剂形成，其中ED是选择的电子给体化合物。 m为≥0.5至 / = 6至 / = 2至

    Polymerization catalyst for ethylene homopolymerization
    8.
    发明授权
    Polymerization catalyst for ethylene homopolymerization 失效
    用于乙烯均聚的聚合催化剂

    公开(公告)号：US4684703A

    公开(公告)日：1987-08-04

    申请号：US471068

    申请日：1983-03-07

    申请人： Burkhard E. Wagner ,  Frederick J. Karol ,  George L. Goeke ,  Robert J. Jorgensen ,  Nils Friis

    发明人： Burkhard E. Wagner ,  Frederick J. Karol ,  George L. Goeke ,  Robert J. Jorgensen ,  Nils Friis

    IPC分类号： C08F2/34 ,  C08F4/02 ,  C08F4/642 ,  C08F4/654 ,  C08F4/655 ,  C08F110/02

    CPC分类号： C08F110/02 ,  C08F4/6425 ,  C08F4/6543 ,  C08F4/6555 ,  Y10S526/901 ,  Y10S526/904

    摘要： A catalyst formed from selected organo aluminum compounds and a precursor composition of the formulaMg.sub.m Ti.sub.l (OR).sub.n X.sub.p [ED].sub.qwhereinED is a selected electron donor compoundm is .gtoreq.0.5 to .ltoreq.56n is 0 or 1p is .gtoreq.6 to .ltoreq.116q is .gtoreq.2 to .ltoreq.85R is a C.sub.1 to C.sub.14, aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting of Cl, Br, I, or mixtures thereof, which catalyst is in particulate form and diluted with an inert carrier material; a process for preparing such catalyst; a process for using said catalyst to readily prepare ethylene homopolymer having a density of about .gtoreq.0.958 to .ltoreq.0.972 and a melt flow ratio of .gtoreq.22 to .ltoreq.32 in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti. Novel polymers and molded articles are prepared.

    摘要翻译： 由选择的有机铝化合物和式MgmTil（OR）nXp [ED] q的前体组合物形成的催化剂，其中ED是选择的电子给体化合物m，其中n = 0.5至56，n为0或1 p为 R = C1至C14，脂族或芳族烃基或COR'，其中R'为C1至C14脂族或芳族烃基， X选自Cl，Br，I或其混合物，该催化剂为颗粒形式并用惰性载体材料稀释; 制备这种催化剂的方法; 在低压气相方法中使用所述催化剂容易地制备密度为约> = = 0.958至 22 = 32的乙烯均聚物的方法 的/ = 50,000磅聚合物/磅Ti。 制备新型聚合物和模塑制品。

    Polymerization catalyst, process for preparing, and use for ethylene homopolymerization
    9.
    发明授权
    Polymerization catalyst, process for preparing, and use for ethylene homopolymerization 失效
    聚合催化剂，制备方法和用于乙烯均聚

    公开(公告)号：US4395359A

    公开(公告)日：1983-07-26

    申请号：US249447

    申请日：1981-03-31

    申请人： Burkhard E. Wagner ,  Frederick J. Karol ,  George L. Goeke ,  Robert J. Jorgensen ,  Nils Friis

    发明人： Burkhard E. Wagner ,  Frederick J. Karol ,  George L. Goeke ,  Robert J. Jorgensen ,  Nils Friis

    IPC分类号： C08F4/64 ,  C08F110/02

    CPC分类号： C08F110/02 ,  Y10S526/901

    摘要： A catalyst formed from selected organo aluminum compounds and a precursor composition of the formulaMg.sub.m Ti.sub.1 (OR).sub.n X.sub.p [ED].sub.qwhereinED is a selected electron donor compoundm is .gtoreq.0.5 to .ltoreq.56n is 0 or 1p is .gtoreq.6 to .ltoreq.116q is .gtoreq.2 to .ltoreq.85R is a C.sub.1 to C.sub.14, aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting of Cl, Br, I,or mixtures thereof, which catalyst is in particulate from and diluted with an inert carrier material; a process for preparing such catalyst; a process for using said catalyst to readily prepare ethylene homopolymer having a density of about .gtoreq.0.958 to .ltoreq.0.972 and a melt flow ratio of .gtoreq.22 to .ltoreq.32 in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti. Novel polymers and molded articles are prepared.

    摘要翻译： 由选择的有机铝化合物和式MgmTi1（OR）nXp [ED] q的前体组合物形成的催化剂，其中ED是选择的电子给体化合物m，其中η= 0〜 R = C1至C14，脂族或芳族烃基或COR'，其中R'为C1至C14脂族或芳族烃基， X选自Cl，Br，I或其混合物，该催化剂是由惰性载体材料制成的颗粒和稀释的; 制备这种催化剂的方法; 在低压气相方法中使用所述催化剂容易地制备密度为约> = = 0.958至 22 = 32/32的方法 的/ = 50,000磅聚合物/磅Ti。 制备新型聚合物和模塑制品。