公开(公告)号：US5362778A

公开(公告)日：1994-11-08

申请号：US17932

申请日：1993-02-16

申请人： Amir Famili ,  James F. Nangeroni ,  Finn L. Marten

发明人： Amir Famili ,  James F. Nangeroni ,  Finn L. Marten

IPC分类号： C08K5/00 ,  C08L3/00 ,  C08L3/04 ,  C08L29/04 ,  C08L89/00 ,  B29C65/00 ,  D01F6/14

CPC分类号： C08L3/00 ,  C08L29/04 ,  C08L3/04

摘要： An extrudable polyvinyl alcohol composition useful for packaging and molding applications is prepared by melt blending polyvinyl alcohol and thermoplastic modified starch to provide a product which has reduced water sensitivity, improved modulus and reduced elongation at high relative humidity.A method for extruding the polyvinyl alcohol composition comprises:adding sufficient energy to the polyvinyl alcohol composition to both melt it and essentially eliminate the polyvinyl alcohol crystallinity in the melt, andsimultaneously removing energy from the melt at a rate sufficient to avoid decomposition of the polyvinyl alcohol.The thermoplastic modified starch may be added to the polyvinyl alcohol before or during the melting of the polyvinyl alcohol and elimination of its crystallinity, or the starch may be blended with the thus treated polyvinyl alcohol and then melt extruding the polyvinyl alcohol/starch blend.

摘要翻译： 通过熔融共混聚乙烯醇和热塑性改性淀粉制备可用于包装和模塑应用的可挤出聚乙烯醇组合物，以提供在高相对湿度下具有降低的水敏感性，改进的模量和降低的伸长率的产品。 用于挤出聚乙烯醇组合物的方法包括：向聚乙烯醇组合物中加入足够的能量以使其熔融并基本上消除熔融物中的聚乙烯醇结晶度，同时以足以避免聚乙烯醇分解的速率从熔体中除去能量 醇。 热塑性改性淀粉可以在聚乙烯醇熔融之前或期间加入到聚乙烯醇中并消除其结晶度，或者淀粉可以与如此处理的聚乙烯醇共混，然后熔融挤出聚乙烯醇/淀粉共混物。

公开(公告)号：US5206278A

公开(公告)日：1993-04-27

申请号：US779218

申请日：1991-10-18

申请人： Amir Famili ,  Finn L. Marten ,  James F. Nangeroni

发明人： Amir Famili ,  Finn L. Marten ,  James F. Nangeroni

IPC分类号： C08L29/04 ,  C08L71/02

CPC分类号： C08L29/04 ,  B29C47/0011 ,  B29C47/0014 ,  B29C47/0021 ,  B29C47/0066 ,  B29C47/364 ,  B29C47/8845 ,  Y02P70/263

摘要： An extrudable polyvinyl alcohol composition useful for packaging and molding applications is prepared by melt blending polyvinyl alcohol and thermoplastic polyethylene oxide to provide a product which has improved pH stability and salt solution solubility. Useful extruded articles prepared from such compositions include films and containers.A method for extruding the polyvinyl alcohol composition comprises:adding sufficient energy to the polyvinyl alcohol composition to both melt it and essentially eliminate the polyvinyl alcohol crystallinity in the melt, andsimultaneously removing energy from the melt at a rate sufficient to avoid decomposition of the polyvinyl alcohol.The thermoplastic polyethylene oxide may be added to the polyvinyl alcohol before the polyvinyl alcohol is melted and its crystallinity eliminated or blended with the thus thermally treated polyvinyl alcohol and then melt extruding the polyvinyl alcohol/polyethylene oxide blend.

公开(公告)号：US5028648A

公开(公告)日：1991-07-02

申请号：US551350

申请日：1990-07-12

申请人： Amir Famili ,  Finn L. Marten ,  James F. Nangeroni

发明人： Amir Famili ,  Finn L. Marten ,  James F. Nangeroni

IPC分类号： C08K5/05 ,  C08K5/10 ,  C08L29/04 ,  C08L75/00 ,  C08L75/04

CPC分类号： C08L29/04 ,  C08L75/04

摘要： An extruable polyvinyl alcohol composition useful for packaging and molding applications is prepared by melt blending polyvinyl alcohol and thermoplastic polyurethane to provide a product which has low water absorptivity, improved impact resistance, and improved low temperature/low humidity tensile properties. Useful extruded articles prepared from such compositions include films and bottles.A method for extruding the polyvinyl alcohol composition comprises:adding sufficient energy to the polyvinyl alcohol composition to both melt it and essentially eliminate the polyvinyl alcohol crystallinity in the melt, andsimultaneously removing energy from the melt at a rate sufficient to avoid decomposition of the polyvinyl alcohol.The thermoplastic polyurethane may be added to the polyvinyl alcohol before the polyvinyl alcohol is melted and its crystallinity eliminated or blended with the thus treated polyvinyl alcohol and then melt extruding the polyvinyl alcohol/polyurethane blend.

摘要翻译： 通过熔融共混聚乙烯醇和热塑性聚氨酯制备可用于包装和模塑应用的可挤出的聚乙烯醇组合物，以提供具有低吸水性，改善的耐冲击性和改善的低温/低湿拉伸性能的产品。 由这种组合物制备的有用的挤压制品包括薄膜和瓶子。 用于挤出聚乙烯醇组合物的方法包括：向聚乙烯醇组合物中加入足够的能量以使其熔融并基本上消除熔体中的聚乙烯醇结晶度，同时以足以避免聚乙烯醇分解的速率从熔体中除去能量 醇。 在聚乙烯醇熔融之前可以将热塑性聚氨酯加入到聚乙烯醇中，并且将其结晶性消除或与如此处理的聚乙烯醇混合，然后熔融挤出聚乙烯醇/聚氨酯共混物。

公开(公告)号：US4772663A

公开(公告)日：1988-09-20

申请号：US3965

申请日：1987-01-16

申请人： Finn L. Marten ,  Amir Famili ,  Dillip K. Mohanty

发明人： Finn L. Marten ,  Amir Famili ,  Dillip K. Mohanty

IPC分类号： C08F216/06 ,  C08F8/12 ,  C08F16/02 ,  C08F220/10 ,  C08F220/18 ,  C08F16/06

CPC分类号： C08F8/12

摘要： A vinyl alcohol copolymer comprising the following general structure ##STR1## where R is hydrogen or methyl;R.sup.1 is a C.sub.6 -C.sub.18 hydrocarbyl group not containing an olefinic functionality;x is 70 to 99.5% mole %;y is 0 to 29.5 mole %; andz is 0.5 to 8 mole %.

公开(公告)号：US5350801A

公开(公告)日：1994-09-27

申请号：US89067

申请日：1993-07-07

申请人： Amir Famili ,  Lori A. Vratsanos ,  Finn L. Marten

发明人： Amir Famili ,  Lori A. Vratsanos ,  Finn L. Marten

IPC分类号： C08F8/00 ,  C08F16/02 ,  C08F16/06 ,  C08L29/04

CPC分类号： C08F8/34

摘要： A solid state process for modifying polyvinyl alcohol using a Michael-type addition wherein dry polyvinyl alcohol powder is sprayed with a solution of a monomer capable of Michael-type addition in an amount sufficient to swell the polyvinyl alcohol or maintain its swollen state, but not dissolve or form a slurry of the polyvinyl alcohol. The swollen polyvinyl alcohol is sprayed with a catalyst and the temperature is raised to initiate the reaction between the polyvinyl alcohol and the monomer.

摘要翻译： 使用迈克尔型添加剂改性聚乙烯醇的固态方法，其中干燥聚乙烯醇粉末用能够迈克尔型加成的单体溶液以足以溶胀聚乙烯醇或保持其溶胀状态的量喷雾 溶解或形成聚乙烯醇的浆液。 用催化剂喷雾膨胀的聚乙烯醇，升高温度以引发聚乙烯醇与单体之间的反应。

公开(公告)号：US4797127A

公开(公告)日：1989-01-10

申请号：US171206

申请日：1988-03-17

申请人： Finn L. Marten ,  Amir Famili

发明人： Finn L. Marten ,  Amir Famili

IPC分类号： D06M13/02 ,  D06M15/333 ,  D06M15/53 ,  C08L5/00

CPC分类号： D06M15/333 ,  D06M13/02 ,  D06M15/53 ,  Y10T428/2969 ,  Y10T442/2402

摘要： An aqueous size composition for cotton-containing textile yarn comprising in an aqueous solution(a) 100 parts polyvinyl alcohol(b) 2-15 parts hydrophobic waxy material(c) 0.2-5 parts ethylene oxide-propylene oxide surfactant which has a surface tension between about 37 and 48 dynes/cm as a 0.1% aqueous solution at 25.degree. C., and a foaming number less than about 20 (ml foam/g solution).degree. F. as a 7% aqueous polyvinyl alcohol solution containing 11.4 parts hydrogenated tallow wax and 2 parts surfactant per 100 parts polyvinyl alcohol.

摘要翻译： 一种含棉纺织纱线的水性组合物，其包含水溶液（a）100份聚乙烯醇（b）2-15份疏水性蜡质材料（c）0.2-5份环氧乙烷 - 环氧丙烷表面活性剂，其具有表面张力 在25℃下为约37至48达因/厘米，0.1％水溶液，发泡数小于约20（ml泡沫/克溶液）DEG，作为含有11.4份氢化的7％聚乙烯醇水溶液 牛脂蜡和每100份聚乙烯醇2份表面活性剂。

公开(公告)号：US5340874A

公开(公告)日：1994-08-23

申请号：US88991

申请日：1993-07-07

申请人： Amir Famili ,  Lori A. Vratsanos ,  Finn L. Marten

发明人： Amir Famili ,  Lori A. Vratsanos ,  Finn L. Marten

IPC分类号： C08F8/00 ,  C08F16/06 ,  C08F261/04 ,  C08L29/02 ,  C08L29/04

CPC分类号： C08F261/04

摘要： A modified polyvinyl alcohol and a solid state process for producing modified polyvinyl alcohol wherein polyvinyl alcohol powder is sprayed with a sufficient amount of a solution of a polymerizable monomer to swell the polyvinyl alcohol powder but not dissolve it or form a slurry. The swollen polyvinyl alcohol powder is sprayed with a free radical source (an initiator) and the temperature is raised to initiate a reaction between polyvinyl alcohol and the polymerizable monomer.

摘要翻译： 改性聚乙烯醇和固化方法制备改性聚乙烯醇，其中聚乙烯醇粉末用足够量的可聚合单体溶液喷雾以溶胀聚乙烯醇粉末但不溶解或形成浆料。 用自由基源（引发剂）喷雾膨胀的聚乙烯醇粉末，升高温度以引发聚乙烯醇与可聚合单体之间的反应。

公开(公告)号：US4948857A

公开(公告)日：1990-08-14

申请号：US184728

申请日：1988-04-22

申请人： Finn L. Marten ,  Amir Famili ,  Dillip K. Mohanty

发明人： Finn L. Marten ,  Amir Famili ,  Dillip K. Mohanty

IPC分类号： C08F8/12 ,  C08F218/08

CPC分类号： C08F218/08 ,  C08F8/12

摘要： A vinyl acetate copolymer comprising the following general structure ##STR1## where R is hydrogen or methyl;R.sup.1 is a C.sub.6 -C.sub.18 hydrocarbyl group not containing an olefinic functionality;y is 92 to 99.5 mole %; andz is 0.5 to 8 mole %.The vinyl acetate copolymer is hydrolyzed to provide a vinyl alcohol copolymer that can be thermoplastically processed into shaped articles possessing good oxygen gas barrier properties.

摘要翻译： 乙酸乙烯酯共聚物，其包含以下通式结构，其中R是氢或甲基; R1是不含烯属官能团的C6-C18烃基; y为92〜99.5摩尔％。 z为0.5〜8摩尔％。 将乙酸乙烯酯共聚物水解以提供可以热塑性加工成具有良好氧气阻隔性的成型制品的乙烯醇共聚物。

公开(公告)号：US4851472A

公开(公告)日：1989-07-25

申请号：US68867

申请日：1987-07-01

申请人： Amir Famili ,  Finn L. Marten ,  Dillip K. Mohanty

发明人： Amir Famili ,  Finn L. Marten ,  Dillip K. Mohanty

IPC分类号： C08F216/06 ,  C08F8/12 ,  C08F16/02 ,  C08F20/22 ,  C08F20/38 ,  C08F218/02 ,  C08F218/08 ,  C08F220/22 ,  C08F220/38

CPC分类号： C08F8/12

摘要： A vinyl alcohol copolymer comprising the following general structure: ##STR1## wherein R is hydrogen or methyl;X is an organic linking group such as ##STR2## R.sup.1 is C.sub.1 -C.sub.4 alkyl; R.sub.f is a perfluoronated alkyl or poly(alkyleneoxy) group;m is 0 or 1;x is 50-99.9 mole %;y is 0-50 mole %; andz is 0.001-50 mole %.The vinyl alcohol copolymer has excellent solvent barrier properties.

公开(公告)号：US4618648A

公开(公告)日：1986-10-21

申请号：US727638

申请日：1985-04-26

申请人： Finn L. Marten

发明人： Finn L. Marten

IPC分类号： C08F8/12 ,  C08F16/06

CPC分类号： C08F8/12

摘要： A vinyl alcohol copolymer comprising the following general structure: ##STR1## wherein R is hydrogen or methyl;R.sup.1 is hydrogen or methyl;R.sup.2 is hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.20 aryl or C.sub.7 -C.sub.30 alkylaryl;n is a number from 1-1,000;x is 50-99.9 mole %;y is 0-50 mole %; and z is 0.001-50 mole %.

摘要翻译： 包含以下一般结构的乙烯醇共聚物：其中R是氢或甲基; R1是氢或甲基; R2是氢，C1-C20烷基，C6-C20芳基或C7-C30烷基芳基; n是1-1000的数字; x为50-99.9摩尔％; y为0-50摩尔％; z为0.001-50摩尔％。