公开(公告)号：US08900347B2

公开(公告)日：2014-12-02

申请号：US13819319

申请日：2011-08-26

申请人： Andre Boulet ,  Soheil Khiavi

发明人： Andre Boulet ,  Soheil Khiavi

IPC分类号： B01D53/04 ,  B01D53/52 ,  B01D53/62 ,  C10L3/10

CPC分类号： B01D53/0462 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/116 ,  B01D2253/202 ,  B01D2253/204 ,  B01D2253/3425 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2257/60 ,  B01D2257/80 ,  B01D2258/0283 ,  C10L3/102 ,  Y02C10/04 ,  Y02C10/08 ,  Y02C20/20

摘要： A method of temperature swing adsorption allows separation of a first fluid component from a fluid mixture comprising at least the first fluid component in an adsorptive separation system having a parallel passage adsorbent contactor with parallel flow passages having cell walls which include an adsorbent material and axial thermally conductive filaments in direct contact with the adsorbent material. The method provides for transferring heat from the heat of adsorption in a countercurrent direction along at least a portion of the filaments during adsorption and transferring heat in either axial direction along the filaments to provide at least a portion of the heat of desorption during a desorption step. A carbon dioxide TSA separation process to separate carbon dioxide from flue gas also includes steps transferring heat from adsorption or for desorption along axial thermally conductive filaments.

摘要翻译： 温度变化吸附的方法允许在具有平行通道吸附剂接触器的吸附分离系统中从包含至少第一流体组分的流体混合物中分离第一流体组分，所述吸附分离系统具有平行流动通道，所述平行流动通道具有包含吸附剂材料和轴向热 导电丝与吸附材料直接接触。 该方法提供了在吸附期间沿着沿着长丝的至少一部分沿着逆流方向从吸热热传递热量，并沿着长丝沿轴向方向传递热量，以在解吸步骤期间提供至少一部分解吸热 。 从烟道气中分离二氧化碳的二氧化碳TSA分离方法还包括从吸附或沿轴向导热细丝解吸的热量的步骤。

公开(公告)号：US08940072B2

公开(公告)日：2015-01-27

申请号：US13203714

申请日：2010-02-26

申请人： Andre Boulet ,  Soheil Khiavi

发明人： Andre Boulet ,  Soheil Khiavi

IPC分类号： B01D39/06 ,  B01D39/20 ,  B01D39/14 ,  B01D24/00 ,  B01D50/00 ,  B01D53/04 ,  B01J12/00 ,  B01J19/24 ,  C04B38/00 ,  C04B111/00 ,  C04B111/94 ,  F28D9/04 ,  F28F3/02 ,  F28F7/02

CPC分类号： B01J35/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2253/1124 ,  B01D2253/116 ,  B01D2253/202 ,  B01D2253/204 ,  B01J12/007 ,  B01J19/2485 ,  B01J20/28045 ,  B01J20/3007 ,  B01J20/3291 ,  B01J37/0201 ,  B01J2219/0004 ,  B01J2219/00135 ,  C04B38/0006 ,  C04B38/0083 ,  C04B2111/00379 ,  C04B2111/0081 ,  C04B2111/94 ,  F28D9/04 ,  F28F3/025 ,  F28F7/02 ,  H05B3/50 ,  H05B2203/021 ,  H05B2203/022 ,  H05B2203/024 ,  Y10T428/24074 ,  Y10T428/24132 ,  C04B35/80 ,  C04B35/83 ,  C04B38/0016

摘要： A parallel passage fluid contactor structure for chemical reaction processes has one or more segments, where each segment has a plurality of substantially parallel fluid flow passages oriented in an axial direction; cell walls between each adjacent fluid flow passages and each cell wall has at least two opposite cell wall surfaces. The structure also includes at least one active compound in the cell walls and multiple axially continuous conductive filaments either embedded within the cell walls or situated between the cell wall surfaces. The conductive filaments are at least one of thermally and electrically conductive, are oriented in axially, and are in direct contact with the active compound, and are operable to transfer thermal energy between the active material and the conductive filaments. Heating of the conductive filaments may be used to transfer heat to the active material in the cell walls. Methods of manufacturing the structure are discussed.

摘要翻译： 用于化学反应过程的平行通道流体接触器结构具有一个或多个段，其中每个段具有沿轴向定向的多个基本平行的流体流动通道; 每个相邻流体流动通道和每个细胞壁之间的细胞壁具有至少两个相对的细胞壁表面。 该结构还包括细胞壁中的至少一种活性化合物和嵌入细胞壁内或位于细胞壁表面之间的多个轴向连续的导电细丝。 导电细丝是热和导电中的至少一种，其轴向定向并与活性化合物直接接触，并且可操作以在活性材料和导电细丝之间传递热能。 导电丝的加热可用于将热量传递到细胞壁中的活性物质。 讨论了制造结构的方法。

公开(公告)号：US20130152787A1

公开(公告)日：2013-06-20

申请号：US13819319

申请日：2011-08-26

申请人： Andre Boulet ,  Soheil Khiavi

发明人： Andre Boulet ,  Soheil Khiavi

IPC分类号： B01D53/04

CPC分类号： B01D53/0462 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/116 ,  B01D2253/202 ,  B01D2253/204 ,  B01D2253/3425 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2257/60 ,  B01D2257/80 ,  B01D2258/0283 ,  C10L3/102 ,  Y02C10/04 ,  Y02C10/08 ,  Y02C20/20

摘要： A method of temperature swing adsorption allows separation of a first fluid component from a fluid mixture comprising at least the first fluid component in an adsorptive separation system having a parallel passage adsorbent contactor with parallel flow passages having cell walls which include an adsorbent material and axial thermally conductive filaments in direct contact with the adsorbent material. The method provides for transferring heat from the heat of adsorption in a countercurrent direction along at least a portion of the filaments during adsorption and transferring heat in either axial direction along the filaments to provide at least a portion of the heat of desorption during a desorption step. A carbon dioxide TSA separation process to separate carbon dioxide from flue gas also includes steps transferring heat from adsorption or for desorption along axial thermally conductive filaments.

摘要翻译： 温度变化吸附的方法允许在具有平行通道吸附剂接触器的吸附分离系统中从包含至少第一流体组分的流体混合物中分离第一流体组分，所述吸附分离系统具有平行流动通道，所述平行流动通道具有包含吸附剂材料和轴向热 导电丝与吸附材料直接接触。 该方法提供了在吸附期间沿着沿着长丝的至少一部分沿着逆流方向从吸热热传递热量，并沿着长丝沿轴向方向传递热量，以在解吸步骤期间提供至少一部分解吸热 。 从烟道气中分离二氧化碳的二氧化碳TSA分离方法还包括从吸附或沿轴向导热细丝解吸的热量的步骤。

公开(公告)号：US20110311761A1

公开(公告)日：2011-12-22

申请号：US13203714

申请日：2010-02-26

申请人： Andre Boulet ,  Soheil Khiavi

发明人： Andre Boulet ,  Soheil Khiavi

IPC分类号： B01J35/04 ,  B32B3/12 ,  B01D53/86 ,  B01J20/28 ,  B01J37/02 ,  B01J20/32 ,  B01D53/04 ,  B29C47/02

CPC分类号： B01J35/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2253/1124 ,  B01D2253/116 ,  B01D2253/202 ,  B01D2253/204 ,  B01J12/007 ,  B01J19/2485 ,  B01J20/28045 ,  B01J20/3007 ,  B01J20/3291 ,  B01J37/0201 ,  B01J2219/0004 ,  B01J2219/00135 ,  C04B38/0006 ,  C04B38/0083 ,  C04B2111/00379 ,  C04B2111/0081 ,  C04B2111/94 ,  F28D9/04 ,  F28F3/025 ,  F28F7/02 ,  H05B3/50 ,  H05B2203/021 ,  H05B2203/022 ,  H05B2203/024 ,  Y10T428/24074 ,  Y10T428/24132 ,  C04B35/80 ,  C04B35/83 ,  C04B38/0016

摘要： A parallel passage fluid contactor structure for chemical reaction processes has one or more segments, where each segment has a plurality of substantially parallel fluid flow passages oriented in an axial direction; cell walls between each adjacent fluid flow passages and each cell wall has at least two opposite cell wall surfaces. The structure also includes at least one active compound in the cell walls and multiple axially continuous conductive filaments either embedded within the cell walls or situated between the cell wall surfaces. The conductive filaments are at least one of thermally and electrically conductive, are oriented in axially, and are in direct contact with the active compound, and are operable to transfer thermal energy between the active material and the conductive filaments. Heating of the conductive filaments may be used to transfer heat to the active material in the cell walls. Methods of manufacturing the structure are discussed.

摘要翻译： 用于化学反应过程的平行通道流体接触器结构具有一个或多个段，其中每个段具有沿轴向定向的多个基本平行的流体流动通道; 每个相邻流体流动通道和每个细胞壁之间的细胞壁具有至少两个相对的细胞壁表面。 该结构还包括细胞壁中的至少一种活性化合物和嵌入细胞壁内或位于细胞壁表面之间的多个轴向连续的导电细丝。 导电细丝是热和导电中的至少一种，其轴向定向并与活性化合物直接接触，并且可操作以在活性材料和导电细丝之间传递热能。 导电丝的加热可用于将热量传递到细胞壁中的活性物质。 讨论了制造结构的方法。

公开(公告)号：US20120144803A1

公开(公告)日：2012-06-14

申请号：US13214046

申请日：2011-08-19

申请人： Xuantian Li ,  William Allison Logan ,  Christopher Gordon Stoner ,  Andre Boulet ,  Erik Paul Johannes ,  Paul Sebright Towgood ,  Jacobus Neels

发明人： Xuantian Li ,  William Allison Logan ,  Christopher Gordon Stoner ,  Andre Boulet ,  Erik Paul Johannes ,  Paul Sebright Towgood ,  Jacobus Neels

IPC分类号： F01N3/00 ,  C10L3/00

CPC分类号： F01N3/2073 ,  C01B3/36 ,  F01N2240/30 ,  F02D19/022 ,  F02M21/0206 ,  F02M21/0215 ,  F02M21/0227 ,  F02M25/12 ,  Y02T10/121 ,  Y02T10/32

摘要： In situations where the demand for syngas is intermittent, a fuel processor is operated to provide a high absolute hydrogen and carbon monoxide production, rather than to give a high fuel-specific hydrogen and carbon monoxide production. When a syngas generator is operated to intermittently produce syngas, a heating process can be performed between periods of syngas demand in order to keep the fuel processor within a desired temperature range. The heating process can comprise various steps or events including performing a heating event, allowing a standby period, and/or performing a carbon conversion event. Carbon formed during the process of converting fuel to syngas can be advantageously converted to maintain the temperature of the fuel processor within a desired range in between periods of syngas demand. A predictive method can be employed to control at least a portion of the heating process.

摘要翻译： 在对合成气的需求是间歇性的情况下，燃料处理器被运行以提供高的绝对氢气和一氧化碳的产生，而不是提供高燃料特定的氢气和一氧化碳的生产。 当操作合成气发生器以间歇地产生合成气时，可以在合成气需求期间进行加热过程，以便将燃料处理器保持在期望的温度范围内。 加热过程可以包括各种步骤或事件，包括执行加热事件，允许待机时间段和/或执行碳转化事件。 在将燃料转化为合成气的过程中形成的碳可以有利地转化为将燃料处理器的温度维持在合成气需求期间的期望范围内。 可以采用预测方法来控制加热过程的至少一部分。

公开(公告)号：US07828877B2

公开(公告)日：2010-11-09

申请号：US11667041

申请日：2005-11-07

申请人： James A. Sawada ,  Matthew L. Babicki ,  Amy Chiu ,  Andre Boulet ,  Surajit Roy ,  Edward J. Rode

发明人： James A. Sawada ,  Matthew L. Babicki ,  Amy Chiu ,  Andre Boulet ,  Surajit Roy ,  Edward J. Rode

IPC分类号： B01D53/02

CPC分类号： C07C7/12 ,  C07C7/13 ,  Y02C10/08 ,  C07C9/04

摘要： An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.

摘要翻译： 提供了本发明的吸附气体分离方法，其能够从至少包含甲烷的进料气体混合物和二氧化碳中产生作为轻质非吸附产物气体的纯化的甲烷产物气体，而不是重质解吸的废气组分。 在本发明的一个实施方案中，进料气体混合物可以包含至少约10％的二氧化碳，并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。 在本发明的另一个实施方案中，进料气体混合物可以包含至少约50％的二氧化碳，并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。

公开(公告)号：US20070261551A1

公开(公告)日：2007-11-15

申请号：US11667041

申请日：2005-11-07

申请人： James Sawada ,  Matthew Babicki ,  Amy Chiu ,  Andre Boulet ,  Surajit Roy ,  Edward Rode

发明人： James Sawada ,  Matthew Babicki ,  Amy Chiu ,  Andre Boulet ,  Surajit Roy ,  Edward Rode

IPC分类号： B01D53/02

CPC分类号： C07C7/12 ,  C07C7/13 ,  Y02C10/08 ,  C07C9/04

摘要： An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.

摘要翻译： 提供了本发明的吸附气体分离方法，其能够从至少包含甲烷的进料气体混合物和二氧化碳中产生作为轻质非吸附产物气体的纯化的甲烷产物气体，而不是重质解吸的废气组分。 在本发明的一个实施方案中，进料气体混合物可以包含至少约10％的二氧化碳，并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。 在本发明的另一个实施方案中，进料气体混合物可以包含至少约50％的二氧化碳，并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。

公开(公告)号：US09146035B2

公开(公告)日：2015-09-29

申请号：US14128595

申请日：2012-06-29

申请人： Andre Boulet

发明人： Andre Boulet

IPC分类号： B01D53/04 ,  B01D53/62 ,  F23C9/08 ,  B01D53/047 ,  F01K17/04 ,  F01K23/10 ,  F23J15/02 ,  B01D53/06

CPC分类号： B01D53/0462 ,  B01D53/047 ,  B01D53/06 ,  B01D53/62 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1124 ,  B01D2253/1126 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/40001 ,  B01D2259/45 ,  F01K17/04 ,  F01K23/10 ,  F23C9/08 ,  F23J15/02 ,  F23J2215/50 ,  F23J2219/60 ,  Y02C10/04 ,  Y02C10/08 ,  Y02E20/16 ,  Y02E20/326

摘要： An integrated fuel combustion system with adsorptive gas separation separates a portion of carbon dioxide from a combustion gas mixture and provides for recycle of separated carbon dioxide to the intake of the fuel combustor for combustion. A process for carbon dioxide separation and recycle includes: admitting combustion gas to an adsorptive gas separation system contactor containing adsorbent material; adsorbing a portion of carbon dioxide; recovering a first product gas depleted in carbon dioxide for release or use; desorbing carbon dioxide from the adsorbent material and recovering a desorbed second product gas enriched in carbon dioxide for sequestration or use; admitting a conditioning fluid into the contactor and desorbing a second portion of carbon dioxide to recover a carbon dioxide enriched conditioning stream; and recycling a portion of the carbon dioxide enriched conditioning stream to an inlet of fuel combustor to pass through the fuel combustor for combustion.

摘要翻译： 具有吸附气体分离的综合燃料燃烧系统将一部分二氧化碳与燃烧气体混合物分离，并提供分离的二氧化碳再循环到燃料燃烧器的进气口进行燃烧。 二氧化碳分离和再循环的方法包括：将燃烧气体导入含有吸附材料的吸附气体分离系统接触器; 吸附一部分二氧化碳; 回收用于释放或使用的二氧化碳消耗的第一产品气体; 从吸附剂材料中解吸二氧化碳并回收富含二氧化碳的解吸附的第二产物气体用于封存或使用; 将调理流体接纳到接触器中并解吸第二部分二氧化碳以回收富含二氧化碳的调理流; 以及将一部分富含二氧化碳的调理流循环到燃料燃烧器的入口以通过燃料燃烧器进行燃烧。

公开(公告)号：US20080274021A1

公开(公告)日：2008-11-06

申请号：US12112784

申请日：2008-04-30

申请人： Jacobus Neels ,  Xuantian Li ,  Richard Allan Sederquist ,  Andre Boulet ,  William Allison Logan

发明人： Jacobus Neels ,  Xuantian Li ,  Richard Allan Sederquist ,  Andre Boulet ,  William Allison Logan

IPC分类号： B01J19/00 ,  C01B3/02

CPC分类号： B01F5/0268 ,  B01F2005/0022 ,  C01B3/36 ,  C01B2203/0255 ,  C01B2203/1276 ,  C01B2203/1288 ,  C01B2203/1604 ,  F01N3/2073 ,  F01N2240/30 ,  F02D19/022 ,  F02D41/0027 ,  F02D41/062 ,  F02M21/0206 ,  F02M21/0227 ,  F02M25/12 ,  F02M27/02 ,  Y02T10/121 ,  Y02T10/32

摘要： A fuel processor for producing a hydrogen-containing product stream from a fuel stream and an oxidant stream, comprises a mixing tube from which the combined fuel and oxidant stream is directed substantially axially into a reaction chamber. The reaction chamber comprises a turn-around chamber and a turn-around wall at one end for re-directing the combined reactant stream, so that in the turn-around chamber the re-directed stream surrounds and is in contact with the combined reactant stream flowing substantially axially in the opposite direction. This design and opposing flow configuration creates a low velocity zone which stabilizes the location of a flame in the fuel processor and offers other advantages.

摘要翻译： 用于从燃料流和氧化剂流产生含氢产物流的燃料处理器包括混合管，所述混合燃料和氧化剂流从该混合管基本轴向地引导到反应室中。 反应室包括翻转室和在一端的转向壁，用于重新引导组合的反应物流，使得在转向室中，重新引导的流包围并与组合的反应物流接触 在相反方向基本轴向流动。 这种设计和相对的流动构造产生了一个低速度区域，其使得燃料处理器中的火焰的位置稳定并提供其他优点。

公开(公告)号：US09157357B2

公开(公告)日：2015-10-13

申请号：US13214046

申请日：2011-08-19

申请人： Xuantian Li ,  William Allison Logan ,  Christopher Gordon Stoner ,  Andre Boulet ,  Erik Paul Johannes ,  Paul Sebright Towgood ,  Jacobus Neels

发明人： Xuantian Li ,  William Allison Logan ,  Christopher Gordon Stoner ,  Andre Boulet ,  Erik Paul Johannes ,  Paul Sebright Towgood ,  Jacobus Neels

IPC分类号： C01B3/36 ,  F01N3/20 ,  F02M25/12 ,  F02M21/02 ,  F02D19/02

CPC分类号： F01N3/2073 ,  C01B3/36 ,  F01N2240/30 ,  F02D19/022 ,  F02M21/0206 ,  F02M21/0215 ,  F02M21/0227 ,  F02M25/12 ,  Y02T10/121 ,  Y02T10/32

摘要： In situations where the demand for syngas is intermittent, a fuel processor is operated to provide a high absolute hydrogen and carbon monoxide production, rather than to give a high fuel-specific hydrogen and carbon monoxide production. When a syngas generator is operated to intermittently produce syngas, a heating process can be performed between periods of syngas demand in order to keep the fuel processor within a desired temperature range. The heating process can comprise various steps or events including performing a heating event, allowing a standby period, and/or performing a carbon conversion event. Carbon formed during the process of converting fuel to syngas can be advantageously converted to maintain the temperature of the fuel processor within a desired range in between periods of syngas demand. A predictive method can be employed to control at least a portion of the heating process.

摘要翻译： 在对合成气的需求是间歇性的情况下，燃料处理器被运行以提供高的绝对氢气和一氧化碳的产生，而不是提供高燃料特定的氢气和一氧化碳的生产。 当操作合成气发生器以间歇地产生合成气时，可以在合成气需求期间进行加热过程，以便将燃料处理器保持在期望的温度范围内。 加热过程可以包括各种步骤或事件，包括执行加热事件，允许待机时间段和/或执行碳转化事件。 在将燃料转化为合成气的过程中形成的碳可以有利地转化为将燃料处理器的温度维持在合成气需求期间的期望范围内。 可以采用预测方法来控制加热过程的至少一部分。