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1.发明授权Method for the production of ethene and synthesis gas in circulating fluidized bed 有权在循环流化床中生产乙烯和合成气的方法公开(公告)号：US09216902B2
公开(公告)日：2015-12-22
申请号：US12585214
申请日：2009-09-08
申请人： Andrea de Rezende Pinho , Fabio Leal Mendes , Mauro Silva , Keiji Maeshiro , Antonio Wahib Bogossian Khalil , Julio Amilcar Ramos Cabral , Luis Fernando Soares de Azevedo , Daniel Santos de Albuquerque
发明人： Andrea de Rezende Pinho , Fabio Leal Mendes , Mauro Silva , Keiji Maeshiro , Antonio Wahib Bogossian Khalil , Julio Amilcar Ramos Cabral , Luis Fernando Soares de Azevedo , Daniel Santos de Albuquerque
CPC分类号： C01B3/323 , C01B3/44 , C01B2203/0233 , C01B2203/0283 , C01B2203/0811 , C01B2203/1005 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/1076 , C01B2203/1217 , C01B2203/1229 , C01B2203/1247
摘要： The present invention relates to a method for the production of ethene, CO, and hydrogen in a reactor with a circulating fluidized bed with two independent sections, from feedstocks that contain hydrocarbons with at least 11 carbon atoms or from feedstocks with a high oxygen content, using a catalyst in particulate form. The method teaches that in one of the sections of the reactor, in the absence of oxygen, a catalyst containing a dehydrogenation metal promotes the cracking of the said feedstocks, facilitating the subsequent endothermic reactions. In the other section, the coke is burned with air and the heating of the catalyst is controlled, for the adjustment of the appropriate amount of energy that the heated catalyst will convey to the section in which the endothermic reactions take place. The total ethene yield of the process according to the present invention is approximately 20% by weight in relation to the feedstock.
摘要翻译： 本发明涉及一种在具有循环流化床的反应器中生产乙烯，CO和氢的方法，所述循环流化床具有两个独立的部分，所述循环流化床包含含有至少11个碳原子的烃的原料或具有高氧含量的原料， 使用颗粒形式的催化剂。 该方法教导了在反应器的一个部分中，在不存在氧的情况下，含有脱氢金属的催化剂促进所述原料的裂化，促进随后的吸热反应。 在另一部分中，焦炭用空气燃烧，并且控制催化剂的加热，以调节加热的催化剂将传递到发生吸热反应的部分的适当量的能量。 根据本发明的方法的总乙烯产率相对于原料为约20重量％。
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2.发明申请PROCESS FOR PRODUCING LIGHT OLEFINS FROM A FEED CONTAINING TRIGLYCERIDES 有权从含有TRIGLYCERIDER的饲料生产光油的方法公开(公告)号：US20090326293A1
公开(公告)日：2009-12-31
申请号：US12477352
申请日：2009-06-03
申请人： Jefferson Roberto GOMES , Julio Amilcar Ramos Cabral , Andrea de Rezende Pinho , Luis Fernando Soares de Azevedo
发明人： Jefferson Roberto GOMES , Julio Amilcar Ramos Cabral , Andrea de Rezende Pinho , Luis Fernando Soares de Azevedo
IPC分类号： C07C1/20
CPC分类号： C07C11/06 , C07C1/22 , C07C11/04 , C07C2521/04 , C07C2521/10 , C07C2521/12 , C07C2523/28 , C07C2523/30 , C07C2523/75 , C07C2523/755 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , C10G2300/4025 , C10G2400/20 , Y02P20/52 , Y02P30/20 , C07C9/08
摘要： The process combines hydroconversion and catalytic cracking starting from a feed containing triglycerides, at concentrations of fatty acids above 85%, which maximizes the yields of light olefins, chiefly ethylene and propylene, while reducing the yield of gasoline, with conversion greater than 80 wt. %.
摘要翻译： 该方法结合加氢转化和催化裂解，从含有甘油三酸酯的进料开始，脂肪酸浓度高于85％，这使得轻质烯烃（主要是乙烯和丙烯）的产率最大化，同时降低汽油产率，转化率大于80wt。 ％。
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3.发明申请Catalytic cracking process for production of diesel from seeds of oleaginous plants 有权从含油植物种子生产柴油的催化裂解过程公开(公告)号：US20080313955A1
公开(公告)日：2008-12-25
申请号：US12213296
申请日：2008-06-17
申请人： Mauro Silva , Andrea de Rezende Pinho , Wilson Kenzo Huziwara , Amilcar Pereira Da Silva Neto , Carlos Nagib Khalil , Julio Amilcar Ramos Cabral , Lucia Cristina Ferreira Leite , Luiz Carlos Casavechia , Raul de Carvalho Silva
发明人： Mauro Silva , Andrea de Rezende Pinho , Wilson Kenzo Huziwara , Amilcar Pereira Da Silva Neto , Carlos Nagib Khalil , Julio Amilcar Ramos Cabral , Lucia Cristina Ferreira Leite , Luiz Carlos Casavechia , Raul de Carvalho Silva
IPC分类号： C10L1/00
CPC分类号： C11C3/00 , C10G3/49 , C10G3/57 , C10G11/18 , C10G2300/1014 , C10G2300/1055 , C10G2300/1059 , C10G2300/307 , C10G2400/04 , Y02E50/13 , Y02P30/20
摘要： The present invention comprises a thermocatalytic cracking process for the production of diesel oil from a charge of vegetable origin made from seeds of oleaginous plants in refineries possessing at least two FCC reactors. At least -one of such reactors processes heavy gas oil or residue under conventional conditions whilst at least one of such reactors processes the charge of vegetable origin made from seeds of oleaginous plants under conditions suitable, for production of diesel oil. Said process employs the same catalyst utilised in the fluid catalytic cracking process which, simultaneously, processes a conventional charge.The diesel, or biodiesel, oil produced by means of said process is of superior quality having a cetane number exceeding 40 given that the cracking reactions occur at low temperatures and the products obtained are less oxidised and consequently purer than products obtained by means of existing technology.
摘要翻译： 本发明包括一种用于在具有至少两个FCC反应器的炼油厂中由含油植物的种子从植物来源产生柴油的热催化裂解方法。 至少有一个这样的反应器在常规条件下处理重质瓦斯油或残余物，而至少一个这样的反应器在适合用于生产柴油的条件下处理由含油植物的种子制成的植物来源。 所述方法使用与流化催化裂化方法相同的催化剂，其同时处理常规电荷。 通过所述方法生产的柴油或生物柴油具有十六烷值超过40的优异品质，因为在低温下发生裂解反应，所得产物的氧化较少，因此比通过现有技术获得的产物更纯净 。
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4.发明授权Catalytic cracking process for production of diesel from seeds of oleaginous plants 有权从含油植物种子生产柴油的催化裂解过程公开(公告)号：US08231777B2
公开(公告)日：2012-07-31
申请号：US12213296
申请日：2008-06-17
申请人： Mauro Silva , Andrea de Rezende Pinho , Wilson Kenzo Huziwara , Amilcar Pereira da Silva Neto , Carlos Nagib Khalil , Julio Amilcar Ramos Cabral , Lúcia Cristina Ferreira Leite , Luiz Carlos Casavechia , Raul de Carvalho Silva
发明人： Mauro Silva , Andrea de Rezende Pinho , Wilson Kenzo Huziwara , Amilcar Pereira da Silva Neto , Carlos Nagib Khalil , Julio Amilcar Ramos Cabral , Lúcia Cristina Ferreira Leite , Luiz Carlos Casavechia , Raul de Carvalho Silva
CPC分类号： C11C3/00 , C10G3/49 , C10G3/57 , C10G11/18 , C10G2300/1014 , C10G2300/1055 , C10G2300/1059 , C10G2300/307 , C10G2400/04 , Y02E50/13 , Y02P30/20
摘要： The present invention comprises a thermocatalytic cracking process for the production of diesel oil from a charge of vegetable origin made from seeds of oleaginous plants in refineries possessing at least two FCC reactors. At least one of such reactors processes heavy gas oil or residue under conventional conditions while at least one of such reactors processes the charge of vegetable origin made from seeds of oleaginous plants under conditions suitable, for production of diesel oil. Said process employs the same catalyst utilized in the fluid catalytic cracking process which, simultaneously, processes a conventional charge.The diesel, or biodiesel, oil produced by means of said process is of superior quality having a cetane number exceeding 40 given that the cracking reactions occur at low temperatures and the products obtained are less oxidized and consequently purer than products obtained by means of existing technology.
摘要翻译： 本发明包括一种用于在具有至少两个FCC反应器的炼油厂中由含油植物的种子从植物来源产生柴油的热催化裂解方法。 这些反应器中的至少一个在常规条件下处理重质瓦斯油或残余物，而这些反应器中的至少一个在适于生产柴油的条件下处理由含油植物的种子制成的植物来源。 所述方法使用与流化催化裂化方法相同的催化剂，其同时处理常规电荷。 通过所述方法生产的柴油或生物柴油具有十六烷值超过40的优异品质，因为裂化反应在低温下发生，所得产物的氧化较少，因此比通过现有技术获得的产物更纯 。
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5.发明授权Process for converting ethanol and hydrocarbons in a fluidized catalytic cracking unit 有权在流化催化裂化装置中转化乙醇和烃的方法公开(公告)号：US07867378B2
公开(公告)日：2011-01-11
申请号：US11958031
申请日：2007-12-17
IPC分类号： C10G51/02
CPC分类号： C10G11/05 , B01J29/06 , B01J29/084 , B01J29/40 , B01J29/80 , B01J2229/42 , C07C1/24 , C07C2521/12 , C07C2521/16 , C07C2529/80 , C10G2400/20 , Y02P20/52 , C07C11/04
摘要： A method is described for co-processing of ethanol and hydrocarbons from petroleum refining, which are introduced separately in two reaction zones of a reactor of a fluidized catalytic cracking unit. The process combines conversion of ethanol into ethene and conversion of hydrocarbons into other lighter hydrocarbon fractions, to produce ethene in quantities of 15 to 90 wt % in the fuel gas fraction obtained during the process.
摘要翻译： 描述了一种从石油精炼中共同处理乙醇和烃的方法，其分别在流化催化裂化装置的反应器的两个反应区中引入。 该方法将乙醇转化为乙烯，将烃转化为其他较轻的烃馏分，以在该方法中获得的燃料气体馏分中生产量为15至90重量％的乙烯。
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6.发明申请PROCESS FOR CONVERTING ETHANOL AND HYDROCARBONS IN A FLUIDIZED CATALYTIC CRACKING UNIT 有权在流化催化裂化装置中转化乙醇和碳氢化合物的方法公开(公告)号：US20080156692A1
公开(公告)日：2008-07-03
申请号：US11958031
申请日：2007-12-17
IPC分类号： C10G51/02
CPC分类号： C10G11/05 , B01J29/06 , B01J29/084 , B01J29/40 , B01J29/80 , B01J2229/42 , C07C1/24 , C07C2521/12 , C07C2521/16 , C07C2529/80 , C10G2400/20 , Y02P20/52 , C07C11/04
摘要： A method is described for co-processing of ethanol and hydrocarbons from petroleum refining, which are introduced separately in two reaction zones of a reactor of a fluidized catalytic cracking unit. The process combines conversion of ethanol into ethene and conversion of hydrocarbons into other lighter hydrocarbon fractions, to produce ethene in quantities of 15 to 90 wt % in the fuel gas fraction obtained during the process.
摘要翻译： 描述了一种从石油精炼中共同处理乙醇和烃的方法，其分别在流化催化裂化装置的反应器的两个反应区中引入。 该方法将乙醇转化为乙烯，将烃转化为其他较轻的烃馏分，以在该方法中获得的燃料气体馏分中生产量为15至90重量％的乙烯。
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