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9 条记录 (耗时 0.04 秒)

    Process for producing negative copies
    4.
    发明授权
    Process for producing negative copies 失效
    生产负面副本的方法

    公开(公告)号：US5227281A

    公开(公告)日：1993-07-13

    申请号：US625542

    申请日：1990-12-11

    申请人： Otfried Gaschler ,  Andreas Elsaesser ,  Dieter Mohr ,  Hans W. Frass

    发明人： Otfried Gaschler ,  Andreas Elsaesser ,  Dieter Mohr ,  Hans W. Frass

    IPC分类号： G03F7/004 ,  G03F7/022 ,  G03F7/20 ,  G03F7/38

    CPC分类号： G03F7/38 ,  G03F7/2022

    摘要： A process for producing negative copies is disclosed in which a light-sensitive or radiation-sensitive recording material comprising a layer support and a normally positive-working light-sensitive or radiation-sensitive layer applied thereto is irradiated imagewise, thermally treated, irradiated overall and then developed with an alkaline developer. Thermal treatment is carried out with water or with an aqueous solution, at temperatures in the range from about 50.degree. to 100.degree. C., preferably from 60.degree. to 90.degree. C., within a period of time varying between about 1 second and 5 minutes, preferably between 5 seconds and 1 minute, overall irradiation is performed on the optionally still hot recording material and development is thereafter carried out within a period of time varying between about 10 seconds and 2 minutes, preferably between 15 seconds and 1 minute. The process can be carried out according to the customary procedure known in the practice of positive processing, and results in perfect printing stencils.

    摘要翻译： 公开了一种用于制造负片的方法，其中对包含层支撑体和施加于其上的正常正光敏感或辐射敏感层的感光或辐射敏感记录材料进行成像照射，热处理，整体辐射照射 然后用碱性显影剂显影。 热处理在水中或水溶液中进行，温度范围为约50℃至100℃，优选60℃至90℃，时间间隔约1秒至5秒 分钟，优选在5秒至1分钟之间，对任意热的记录材料进行总体照射，然后在约10秒至2分钟之间，优选15秒至1分钟之间的时间内进行显影。 该过程可以根据正面加工实践中已知的常规程序进行，并产生完美的印刷模版。

    Matted, radiation-sensitive recording material and printing plate
    5.
    发明授权
    Matted, radiation-sensitive recording material and printing plate 失效
    有光泽，辐射敏感的记录材料和印版

    公开(公告)号：US5576137A

    公开(公告)日：1996-11-19

    申请号：US305647

    申请日：1994-09-14

    申请人： Werner Frass ,  Otfried Gaschler ,  Klaus Joerg ,  Guenter Hultzsch ,  Andreas Elsaesser

    发明人： Werner Frass ,  Otfried Gaschler ,  Klaus Joerg ,  Guenter Hultzsch ,  Andreas Elsaesser

    IPC分类号： G03F7/00 ,  G03F7/115 ,  G03F7/11 ,  B41N1/00 ,  G03F7/023

    CPC分类号： G03F7/115 ,  Y10S430/151

    摘要： The invention relates to a non-continuous matte layer that can be used with a recording material having a substrate and a radiation-sensitive layer which contains a 1,2-naphthoquinone-2-diazide and an organic, polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions. This matte layer comprises 100 to 10,000 particles per square centimeter which have a mean diameter of less than 40 .mu.m and a maximum diameter of less than 80 .mu.m and a mean height of 2 to 6 .mu.m and a maximum height of 10 .mu.m, and contains a resin which has up to 0.80 mmol of acid groups and/or salt groups per gram. The matte layer is obtained by spraying on and drying an aqueous, anionically or anionically/nonionically stabilized dispersion of the resin.

    摘要翻译： 本发明涉及一种非连续的无光泽层，其可与具有基底和含有1,2-萘醌-2-二叠氮化物的辐射敏感层和不溶于水的有机聚合物粘合剂的记录材料一起使用 但可溶于碱性水溶液。 该无光泽层包含平均直径小于40μm，平均直径小于80μm，平均高度为2〜6μm，最大高度为10μm的100〜10000个平方厘米的颗粒 ，并且含有每克最多含有0.80mmol酸基和/或盐基的树脂。 通过喷涂和干燥树脂的水性，阴离子或阴离子/非离子稳定的分散体获得无光泽层。

    Radiation-sensitive mixtures comprising IR-absorbing cyanine dyes having a betaine structure or having a betaine structure and containing an anion, and recording materials prepared therewith
    6.
    发明授权
    Radiation-sensitive mixtures comprising IR-absorbing cyanine dyes having a betaine structure or having a betaine structure and containing an anion, and recording materials prepared therewith 有权

    公开(公告)号：US06492093B2

    公开(公告)日：2002-12-10

    申请号：US09362857

    申请日：1999-07-29

    申请人： Otfried Gaschler ,  Andreas Elsaesser ,  Joerg Jung ,  Hans-Joachim Schlosser

    发明人： Otfried Gaschler ,  Andreas Elsaesser ,  Joerg Jung ,  Hans-Joachim Schlosser

    IPC分类号： G03C177

    CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/106 ,  Y10S430/127 ,  Y10S430/145

    摘要： The invention relates to a positive-working, radiation-sensitive mixture which contains an organic polymeric binder which is insoluble in water but soluble or at least swellable in aqueous alkaline solution and at least one IR-absorbing cyanine dye having a betaine structure or having a betaine structure and containing an anion and having the formula (I) in which R1 to R8 independently of one another, are a hydrogen or halogen atom, a sulfonate, carboxylate, phosphonate, hydroxyl, (C1-C4)alkoxy, nitro, amino, (C1-C4)alkylamino, di(C1-C4)alkylamino group or a (C6-C10)aryl group which in turn may be substituted by one or more halogen atoms and/or one or more sulfonate, carboxylate, phosphonate, hydroxyl, (C1-C4)alkoxy, nitro, amino, (C1-C4)alkylamino and/or di(C1-C4)alkylamnino groups, R9 and R10 independently of one another, are a straight-chain or branched (C1-C6)alkyl, a (C7-C6)aralkyl or a (C6-C10)aryl group, each of which in turn may be substituted by one or more halogen atoms and/or one or more sulfonate, carboxylate, phosphonate, hydroxyl, (C1-C4)alkoxy, nitro, amino, (C1-C4)alkylamino and/or di(C1-C4)alkylamino groups, R11 and R12 independently of one another, are (C1-C4)alkyl or (C6-C10)aryl groups which in turn may be substituted, Z1 and Z2 independently of one another, are a sulfur atom, a di(C1-C4)alkylmethylene group or an ethene-1,2-diyl group and A is a carbon atom or a chain having conjugated double bonds which results in the formation of a delocalized II-electron system between the quaternary nitrogen atom of the 3H-indolium, quinolinium or benzothiazolium radical and the enolate oxygen atom of the pyrimidine-2,4,6-trione radical. After imagewise exposure to a laser, the recording material prepared using this mixture can be readily developed with an aqueous alkaline solution without additional processing steps (such as post-bake or postexposure). The invention also relates to a process for the production of printing plates for offset printing from a recording material according to the invention.

    Photosensitive recording material containing negative working diazonium salt layer and discontinuous top layer
    7.
    发明授权
    Photosensitive recording material containing negative working diazonium salt layer and discontinuous top layer 失效
    含有负重重氮盐层和不连续顶层的感光记录材料

    公开(公告)号：US5753404A

    公开(公告)日：1998-05-19

    申请号：US558580

    申请日：1995-10-31

    申请人： Andreas Elsaesser ,  Otfried Gaschler ,  Werner Frass ,  Klaus-Peter Konrad

    发明人： Andreas Elsaesser ,  Otfried Gaschler ,  Werner Frass ,  Klaus-Peter Konrad

    IPC分类号： G03F7/115 ,  G03F7/021 ,  G03F7/11

    CPC分类号： G03F7/115

    摘要： A photosensitive recording material is described which has a layer base, a negative-working photosensitive layer containing a diazonium salt and a water-insoluble polymeric binder which is soluble or swellable in aqueous alkaline solutions, and a discontinuous top layer which forms a rough surface and which is composed of particles of a water-insoluble polymer which is dispersible in water in the presence of anionic or anionic/nonionic dispersants and which has a content of free acid groups or acid groups neutralized by salt formation of less than 0.8 mmol/g, the mean height of the particles being 2 to 6 .mu.m, the maximum height less than 10 .mu.m, the mean horizontal diameter less than 40 .mu.m, the maximum diameter less than 80 .mu.m and the number of particles being 100 to 10,000 per cm.sup.2. The material is suitable for the production of planographic printing plates and requires only short vacuum times in a vacuum-operated copying frame. The material can be developed without residue after exposure, the rough surface remaining intact at the image areas.

    摘要翻译： 描述了一种感光记录材料，其具有层基底，含有重氮盐的负性感光层和在碱性水溶液中可溶或溶胀的水不溶性聚合物粘合剂，以及形成粗糙表面的不连续顶层和 其由在水阴离子或阴离子/非离子分散剂存在下可分散于水中的水不溶性聚合物的颗粒组成，并且其含量由少于0.8mmol / g的盐形成中和的游离酸基或酸基组成， 颗粒的平均高度为2〜6μm，最大高度小于10μm，平均水平直径小于40μm，最大直径小于80μm，颗粒数为100〜10,000 cm2。 该材料适用于生产平版印刷版，并且在真空操作的复印机架中仅需要较短的真空时间。 材料可以在曝光后无残留发育，粗糙的表面在图像区域保持完整。

    Photosensitive mixture containing an ester or amide of 1,2-naphthoquinone diazide sulfonic or carboxylic acid, a phenolic binder resin and a bis-(4-hydroxyphenyl) speed enhancing compound
    8.
    发明授权
    Photosensitive mixture containing an ester or amide of 1,2-naphthoquinone diazide sulfonic or carboxylic acid, a phenolic binder resin and a bis-(4-hydroxyphenyl) speed enhancing compound 失效
    含有1,2-萘醌二叠氮化物磺酸或羧酸的酯或酰胺的光敏性混合物，酚类粘合剂树脂和双（4-羟基苯基）速度增强化合物

    公开(公告)号：US5225310A

    公开(公告)日：1993-07-06

    申请号：US202194

    申请日：1988-06-02

    申请人： Paul Stahlhofen ,  Otfried Gaschler

    发明人： Paul Stahlhofen ,  Otfried Gaschler

    IPC分类号： G03C1/00 ,  G03C1/72 ,  G03F7/00 ,  G03F7/004 ,  G03F7/022 ,  G03F7/023

    CPC分类号： G03F7/0226

    摘要： The invention relates to a photosensitive mixture which essentially contains an ester or an amide of a 1,2-naphthoquinonediazide sulfonic or carboxylic acid as the photosensitive compound, a phenolic resin which is soluble in aqueous-alkaline solutions and insoluble in water as the binder, and an additional speed enhancer, which corresponds to the general formula ##STR1## where X denotes a single bond, CH.sub.2, SO.sub.2, S, CO, C(CH.sub.3).sub.2, CHCC1.sub.3 or ##STR2## Biphenyldiol-(4,4'), bis-(4-hydroxyphenyl)-ketone, 2,2-bis-(4-hydroxy-phenyl)-propane or bis-(4-hydroxyphenyl)-sulfone are described as suitable compounds. The mixture is employed as photosensitive layers in recording materials suitable for the production of printing forms.The invention provides for an increased photospeed, without any disadvantages occurring in respect of the copying or printing behavior.

    摘要翻译： 本发明涉及一种感光性混合物，其基本上含有作为感光性化合物的1,2-萘醌二叠氮化物磺酸或羧酸的酯或酰胺，可溶于水溶性碱溶液且不溶于水的酚醛树脂作为粘合剂， 和其中X表示单键，CH2，SO2，S，CO，C（CH3）2，CHCC13或联苯二醇 - （4,4'）的通式为“IMAGE”的附加速度增强剂， 双（4-羟基苯基） - 酮，2,2-双 - （4-羟基 - 苯基） - 丙烷或双 - （4-羟基苯基） - 砜被描述为合适的化合物。 该混合物用作适于生产印刷形式的记录材料中的感光层。 本发明提供了增加的感光速度，在复印或打印行为方面没有出现任何缺点。

    Positive-working 1,2-quinone diazide radiation-sensitive mixture and recording material containing urethane compound to diminish developer solubility
    9.
    发明授权
    Positive-working 1,2-quinone diazide radiation-sensitive mixture and recording material containing urethane compound to diminish developer solubility 失效
    正负性1,2-醌二叠氮化合物辐射敏感性混合物和含有氨基甲酸酯化合物的记录材料以降低显影剂溶解度

    公开(公告)号：US5368975A

    公开(公告)日：1994-11-29

    申请号：US39554

    申请日：1993-03-26

    申请人： Andreas Elsaessser ,  Hans W. Frass ,  Otfried Gaschler ,  Dieter Mohr ,  Gerhard Buhr

    发明人： Andreas Elsaessser ,  Hans W. Frass ,  Otfried Gaschler ,  Dieter Mohr ,  Gerhard Buhr

    IPC分类号： G03F7/00 ,  G03F7/022 ,  G03F7/023 ,  G03F7/039

    CPC分类号： G03F7/039 ,  G03F7/0233

    摘要： The invention relates to a usually positive-working radiation-sensitive mixture which contains as essential components a binder which is insoluble in water and soluble in aqueous-alkaline solutions, a 1,2-quinone diazide and a compound which diminishes the developer solubility of the exposed regions by heat treatment, in which the compound which diminishes the developer solubility which is present is at least one urethane of the formula I: ##STR1## in which R.sub.1 is hydrogen or methyl,R.sub.2 is hydrogen, alkyl, substituted or unsubstituted aryl, or substituted or unsubstituted arylaminocarbonyl,R.sub.3 is substituted or unsubstituted arylene or arylenealkylene,Q is hydrogen, --CH.sub.4-p, or --CR.sub.5 R.sub.6 in which R.sub.5 and R.sub.6 can be identical or different and are selected from the group consisting of hydrogen, alkyl and aryl, carbonyl, oxygen, sulfur or sulfonyl,m is 1, 2 or 3,n is at least 1 and not more than 50, andis 1, 2 or 3.The mixture is suitable for producing a radiation-sensitive recording material which has a long shelf life in combination with high radiation sensitivity and has a broad image reversal range in a process for producing relief images.

    摘要翻译： 本发明涉及一种通常为正性的辐射敏感性混合物，其包含作为必需组分的粘合剂，其不溶于水并且可溶于水性 - 碱性溶液，1,2-醌二叠氮化物和降低显影剂溶解度的化合物 暴露区域，其中减少存在的显影剂溶解度的化合物是至少一种式I的氨基甲酸酯：其中R 1是氢或甲基，R 2是氢，烷基，取代或未取代的芳基 或者取代或未取代的芳基氨基羰基，R3是取代或未取代的亚芳基或亚芳基亚烷基，Q是氢，-CH4-p或-CR5R6，其中R5和R6可以相同或不同，并且选自氢，烷基和 芳基，羰基，氧，硫或磺酰基，m为1,2或3，n至少为1且不大于50，为1,2或3.该混合物适用于生产辐射敏感记录材料 其具有长的保质期和高的辐射灵敏度，并且在用于产生浮雕图像的过程中具有广泛的图像反转范围。