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公开(公告)号：US5336420A
公开(公告)日：1994-08-09
申请号：US989861
申请日：1992-12-14
IPC分类号： C07D285/12 , C07D285/125 , C10L1/14 , C10L1/18 , C10L1/24 , C10M135/36
CPC分类号： C10L1/143 , C07D285/125 , C10L1/2456 , C10L1/2475 , C10L10/04 , C10L10/08 , C10M135/36 , C10L1/1828 , C10L1/1963 , C10L1/2437 , C10L1/2493 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106
摘要： An aromatic functional fluid, specifically a monoalkylated tetradecyl diphenyl oxide synthetic lubricant, contains a polymer-supported reaction product of an organic quaternary ammonium salt, derived from a mercapto-heterocycle and a quaternary ammonium salt. To produce the polymer-supported organic quaternary ammonium salt, the salt is reacted with a dicarboxylic acid or anhydride, specifically 2-dodecen-1-ylsuccinic anhydride. An arylamine antioxidant, such as alkylated phenyl naphthylamine, can be added to the polymer supported organic quaternary ammonium salt-treated functional fluid to impart extra antioxidant and stability properties.
摘要翻译： 芳族官能流体，特别是单烷基化十四烷基二苯醚合成润滑剂，含有衍生自巯基杂环的有机季铵盐和季铵盐的聚合物负载的反应产物。 为了制备聚合物负载的有机季铵盐，该盐与二羧酸或酸酐，特别是2-十二碳烯-1-基琥珀酸酐反应。 可以将芳基胺抗氧化剂如烷基化苯基萘胺加入到经支持聚合物的有机季铵盐处理的功能流体中以赋予额外的抗氧化和稳定性。
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公开(公告)号：US4943383A
公开(公告)日：1990-07-24
申请号：US210453
申请日：1988-06-23
IPC分类号： C10L1/18 , C08F8/08 , C10L10/08 , C10M105/18 , C10M107/10 , C10M107/18 , C10M107/22 , C10M111/04 , C10M143/08 , C10M143/18 , C10N30/02 , C10N30/06 , C10N40/25 , C10N60/04 , C10N60/06
CPC分类号： C10M143/18 , C08F8/08 , C10M107/10 , C10M107/18 , C10M111/04 , C10M143/08 , C10M2205/00 , C10M2205/028 , C10M2205/0285 , C10M2205/123 , C10M2207/021 , C10M2207/022 , C10M2207/042 , C10M2219/084 , C10M2221/041 , C10M2223/04 , C10M2223/042 , C10M2223/047 , C10M2225/00 , C10M2225/02 , C10M2227/061 , C10N2220/02 , C10N2230/12 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： Epoxy functionalized polyalpha-olefin lubricants compositions are prepared with superior properties by epoxidizing the olefinic bond of oligomers prepare by oligomerizing C.sub.6 -C.sub.20 alpha-olefins with reduced valence state chromium catalyst on silica support. The invention encompasses a product of reaction made by epoxidizing C.sub.30 + polyalpha-olefin oligomeric hydrocarbon lubricant having a branch ratio of less than 0.19 and pour point below -15.degree. C. in the presence of an epoxidizing amount of an epoxidizing agent wherein said product comprises a mixture of 2-dialkyl oxirane and 1,2-dialkyl oxirane having between an average of C.sub.30 and C.sub.1000 carbon atoms, said mixture having a branch ratio of less than 0.19 and pour point below -15.degree. C. The invention further encompasses blends and additive compositions of the novel epoxidizing polyalpha-olefins.
摘要翻译： 环氧官能化聚α-烯烃润滑剂组合物通过环氧化通过在二氧化硅载体上降低的价态铬催化剂的C 6 -C 20α-烯烃制备的低聚物的烯键来制备具有优异性能。 本发明包括在环氧化量的环氧化剂存在下，使分支比小于0.19且倾点低于-15℃的C30 +聚α-烯烃低聚烃润滑剂进行反应制得的反应产物，其中所述产物包含 平均C30至C1000个碳原子的2-二烷基环氧乙烷和1,2-二烷基环氧乙烷的混合物，所述混合物的分支比小于0.19，倾点低于-15℃。本发明还包括共混物和添加剂 新型环氧化聚α-烯烃的组成。
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公开(公告)号：US5288937A
公开(公告)日：1994-02-22
申请号：US992341
申请日：1992-12-17
IPC分类号： C07C15/40 , C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F297/02 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/24 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C07C2/40
CPC分类号： C08F297/02 , C07C15/40 , C08F236/04 , C08F8/00 , C08F8/04 , C08F8/08 , C10L1/1658 , C10L1/195 , C10L1/1955 , C10L1/196 , C10L1/198 , C10L1/207 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C10L1/1963 , C10L1/1966 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/2383 , C10L1/2387 , C10M2205/04 , C10M2205/06 , C10M2215/04 , C10M2215/26 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06
摘要： Block and random straight chain and star-branched liquid copolymers of two different conjugated dienes, the residual ethylenic unsaturation of the polymerized units of one of which, e.g. isoprene, is less readily hydrogenated than that of the other diene, e.g., butadiene. In the case of block copolymers, the terminal blocks of a straight chain copolymer or the blocks of the free ends of the branches of a star-branched copolymer are composed of the less readily hydrogenated diene polymer while the more readily hydrogenated diene polymer is in the form of central blocks of a straight chain copolymer or interior blocks of the branches of a star-branched copolymer. These copolymers may be selectively hydrogenated so that substantially all of the residual ethylenic unsaturation of the more readily hydrogenated polymerized diene units are hydrogenated while enough residual ethylenic unsaturation of the less readily hydrogenated polymerized diene units remains unhydrogenated to provide sufficient sites for subsequent vulcanization or chemical modification. The combination of elastomeric properties and oxidative stability possessed by the polymers of this invention makes them suitable for many and uses such as sealants, caulks and adhesives.
摘要翻译： 两种不同的共轭二烯的嵌段和无规直链和星形支链液体共聚物，其中一种的聚合单元的残余烯属不饱和键。 异戊二烯不如其它二烯例如丁二烯那样氢化。 在嵌段共聚物的情况下，直链共聚物的末端嵌段或星形支链共聚物的支链的自由端的嵌段由不太容易氢化的二烯聚合物组成，而较容易氢化的二烯聚合物在 直链共聚物的中心嵌段的形式或星形支链共聚物的支链的内部嵌段。 可以选择性地氢化这些共聚物，使得更容易氢化的聚合二烯单元的基本上所有的残余烯属不饱和基团都被氢化，而不易氢化的聚合二烯单元的足够的残留烯属不饱和基团保持未氢化以提供足够的用于后续硫化或化学改性的位点 。 本发明的聚合物具有的弹性体性质和氧化稳定性的组合使得它们适用于许多用途，例如密封剂，填缝剂和粘合剂。
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4.发明授权Measurement of vanadium content in a refinery stream by electron spin resonance spectroscopy 失效通过电子自旋共振光谱法测定炼厂流中的钒含量
公开(公告)号：US4777140A
公开(公告)日：1988-10-11
申请号：US054048
申请日：1987-05-26
申请人： Leslie R. Rudnick
发明人： Leslie R. Rudnick
CPC分类号： G01R33/60 , G01R33/30 , Y10T436/12 , Y10T436/24
摘要： In the control of a refinery process, vanadium content of the hydrocarbon streams is determined by measuring the intensity of the 5 isotropic and 6 anisotropic ESR spectral peaks. The ln of the sum of the intensities of these two peaks has a linear relationship to vanadium content.
摘要翻译： 在炼油过程的控制中，通过测量5个各向同性和6个各向异性ESR光谱峰的强度来确定烃流的钒含量。 这两个峰值的强度之和与钒含量呈线性关系。
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公开(公告)号：US4581131A
公开(公告)日：1986-04-08
申请号：US674433
申请日：1984-11-23
申请人： Leslie R. Rudnick
发明人： Leslie R. Rudnick
IPC分类号： C10G25/00
CPC分类号： C10G25/003
摘要： Phenolic compounds are removed from a hydrocarbon oil by contacting the oil with manganese nodules at suitable conditions of contact time, temperature, and pressure.
摘要翻译： 通过在合适的接触时间，温度和压力条件下使油与锰结核接触，从烃油中除去酚类化合物。
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公开(公告)号：US06313075B1
公开(公告)日：2001-11-06
申请号：US07752138
申请日：1991-08-29
IPC分类号： C10M10572
CPC分类号： C10L10/08 , C07D339/08 , C10L1/245 , C10M105/72 , C10M135/34 , C10M2219/102 , C10N2230/06 , C10N2230/08 , C10N2250/10 , C10N2270/00
摘要： Alkylated thianthrenes are high temperature stable lubricant fluids having excellent thermal stability, antiwear and load-carrying properties and excellent additive solubility as well as multifunctional additives for fuels.
摘要翻译： 烷基化噻吩是具有优异的热稳定性，抗磨损和承载性能以及优异的添加剂溶解性以及用于燃料的多功能添加剂的高温稳定润滑剂流体。
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公开(公告)号：US5773524A
公开(公告)日：1998-06-30
申请号：US514200
申请日：1995-08-11
IPC分类号： C07C15/40 , C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F297/02 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/24 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C08F36/14 , C08F236/14
CPC分类号： C07C15/40 , C08F236/04 , C08F297/02 , C08F8/00 , C08F8/08 , C10L1/1658 , C10L1/195 , C10L1/1955 , C10L1/196 , C10L1/198 , C10L1/207 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C08F2800/10 , C08F2800/20 , C10L1/1963 , C10L1/1966 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/2383 , C10L1/2387 , C10M2205/04 , C10M2205/06 , C10M2215/04 , C10M2215/26 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06
摘要： Epoxidized linear block, random, star-branched block or star-branched random polymers are disclosed which prior to epoxidation contain at least one conjugated diene having at least five carbon atoms of the formula (1) ##STR1## wherein R.sup.1 -R.sup.6 are each hydrogen or a hydrocarbyl group, provided that at least one of R.sup.1 -R.sup.6 is a hydrocarbyl group and the structure of the residual double bond in the polymerized diene of formula (1) has the formula (2) ##STR2## wherein R.sup.I, R.sup.II, R.sup.III and R.sup.IV are each hydrogen or a hydrocarbyl group, provided that either both R.sup.I and R.sup.II are hydrocarbyl groups or both R.sup.III and R.sup.IV are hydrocarbyl groups; and the remainder of the conjugated diene different from the diene of formula (1), has at least four carbon atoms of the formula (3) ##STR3## wherein R.sup.7 -R.sup.12 are each hydrogen or a hydrocarbyl group, provided that the structure of the residual double bond in the polymerized diene of formula (3) has the formula (4) ##STR4## wherein R.sup.a, R.sup.b, R.sup.c and R.sup.d are each hydrogen or a hydrocarbyl group, provided that one of R.sup.a or R.sup.b is hydrogen, one of R.sup.c and R.sup.d is hydrogen.
摘要翻译： 公开了环氧化线性嵌段，无规，星形支链嵌段或星形支链无规聚合物，其在环氧化之前含有至少一种具有式（1）至少五个碳原子的共轭二烯，其中R 1 -R 6各自为氢 或烃基，条件是R 1 -R 6中的至少一个是烃基，并且式（1）的聚合二烯中的残余双键的结构具有式（2）h氢或烃基，条件是 RI和RII都是烃基或RIII和RIV都是烃基; 和不同于式（1）的二烯的共轭二烯的其余部分具有至少四个式（3）的碳原子，其中R 7 -R 12各自为氢或烃基，条件是 式（3）的聚合二烯中的残余双键具有式（4）其中R a，R b，R c和R d各自为氢或烃基，条件是R a或R b中的一个为氢，R c Rd为氢。
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公开(公告)号：US5210359A
公开(公告)日：1993-05-11
申请号：US907959
申请日：1992-08-06
IPC分类号： C07C15/40 , C08F8/00 , C08F8/04 , C08F8/08 , C08F236/04 , C08F297/02 , C10L1/16 , C10L1/18 , C10L1/195 , C10L1/196 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/24 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10
CPC分类号： C08F297/02 , C07C15/40 , C08F236/04 , C08F8/00 , C08F8/04 , C08F8/08 , C10L1/1658 , C10L1/195 , C10L1/1955 , C10L1/196 , C10L1/198 , C10L1/207 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L10/00 , C10M143/12 , C10M149/06 , C10M149/10 , C10L1/1963 , C10L1/1966 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/2383 , C10L1/2387 , C10M2205/04 , C10M2205/06 , C10M2215/04 , C10M2215/26 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06
摘要： There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers as the linear block copolymers.
摘要翻译： 公开了包含至少一个三嵌段IBI的线性嵌段共聚物，其中I是至少一种具有至少五（5）个碳原子的聚合的共轭二烯的嵌段，例如异戊二烯，B是在 与用于聚合嵌段I的至少一种与至少四（4）个碳原子如1,3-丁二烯聚合的共轭二烯的至少一种共轭二烯。 B嵌段被选择性氢化，而每个I嵌段是未氢化的，因此保留足够量的其原始不饱和度以硫化共聚物。 还公开了另一种线性嵌段共聚物，该线性嵌段共聚物含有至少一个由少部分至少一种芳基取代的烯烃如苯乙烯制成的第一聚合物嵌段的三嵌段，以及用于聚合的至少一种共轭二烯的主要比例 嵌段I，用于聚合嵌段B的至少一种二烯的第二中间聚合物嵌段和与第一聚合物嵌段相同的第三聚合物嵌段。 还公开了由与线性嵌段共聚物相同的单体制备的随机线性和星形支链嵌段和无规共聚物。
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公开(公告)号：US4642175A
公开(公告)日：1987-02-10
申请号：US713376
申请日：1985-03-19
申请人： Leslie R. Rudnick
发明人： Leslie R. Rudnick
摘要： The coking tendencies of heavy hydrocarbon feedstocks are reduced by treatment with a free radical removing catalyst such as a transition metal naphthenate, preferably at temperatures below 350.degree. C. The treated product has improved stability as such and may be treated in subsequent processing operations such as catalytic cracking and thermal cracking, including visbreaking and coking, with improved liquid yield and reduced coke production.
摘要翻译： 重质烃原料的焦化倾向通过用自由基去除催化剂如环烷酸过渡金属处理而降低，优选在低于350℃的温度下处理。处理过的产品具有改善的稳定性，并且可以在随后的加工操作如 催化裂化和热裂解，包括减粘裂化和焦化，具有改善的液体产率和减少的焦炭产量。
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10.发明授权Process for reducing nitrogen and/or oxygen heteroatom content of a mineral oil 失效降低矿物油中氮和/或氧杂原子含量的方法
公开(公告)号：US4414102A
公开(公告)日：1983-11-08
申请号：US263820
申请日：1981-05-15
摘要： The nitrogen-containing and oxygen-containing contaminants of a mineral oil are converted to the corresponding sulfur compounds by contacting the oil with a fresh catalyst containing metals from Groups VB, VIB and VIII or a deactivated and metals contaminated hydrodesulfurization catalyst in the presence of hydrogen and hydrogen sulfide under conditions of elevated temperature and pressure.
摘要翻译： 将矿物油中的含氮和含氧污染物转化为相应的硫化合物，通过使油与含VB，VIB和VIII族金属的新鲜催化剂接触，或在氢气存在下使其失活和金属污染的加氢脱硫催化剂 和硫化氢在升高的温度和压力的条件下。
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